Secondary ion mass spectroscopy (SIMS) and kinetics of the catalysis of bisulphite oxidation by aqueous iron
Keyword(s):
The catalytic activity of Fe(II) and Fe(III) in the aqueous oxidation of bisulphite by molecular oxygen at bisulphite concentrations similar to those in cloud water has been studied. Secondary Ion Mass Spectroscopy (SIMS) of insoluble sulphates derived from bisulphite after oxidation by 18O2 gives different 18O/32S ratios for Fe(II) and Fe(III), indicating that the oxidation mechanism is different in these two species. Key words: oxidation, bisulphite, iron, secondary ion mass spectroscopy.
2008 ◽
Vol 266
(10)
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pp. 2450-2452
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2011 ◽
Vol 82
(3)
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pp. 033101
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2015 ◽
Vol 648
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pp. 412-417
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2001 ◽
Vol 148
(5)
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pp. F92
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1998 ◽
Vol 80
(1-4)
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pp. 147-152
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2009 ◽
pp. 86-86-15