Some routes to C2-alkoxymethyl hex-2-enopyranosides

1994 ◽  
Vol 72 (1) ◽  
pp. 69-74 ◽  
Author(s):  
Gordon Wong ◽  
Bert Fraser-Reid
Keyword(s):  
Thionyl Chloride ◽  
Large Scale ◽  
Alkoxy Group ◽  
Large Scale Preparation ◽  
Scale Preparation ◽  
The One ◽  
Allylic Chloride ◽  
Methylene Derivative

Several procedures for installing a C2 alkoxy group at C2 of a hex-2-enopyranoside have been investigated. The one that is most convenient for large-scale preparation begins with a 2-keto pyranoside, which is converted into the corresponding exo methylene derivative. An SN2′ rearrangement is effected with thionyl chloride, and the resulting primary allylic chloride is displaced with sodium benzylate.

Purification of the Antihemophilic Factor by Gel Filtration on Agarose

1969 ◽  
Vol 22 (03) ◽  
pp. 577-583 ◽  
Author(s):  
M.M.P Paulssen ◽  
A.C.M.G.B Wouterlood ◽  
H.L.M.A Scheffers
Keyword(s):  
Factor Viii ◽  
Plasma Proteins ◽  
Large Scale ◽  
Gel Filtration ◽  
Large Scale Preparation ◽  
Scale Preparation ◽  
Antihemophilic Factor

SummaryFactor VIII can be isolated from plasma proteins, including fibrinogen by chromatography on agarose. The best results were obtained with Sepharose 6B. Large scale preparation is also possible when cryoprecipitate is separated by chromatography. In most fractions containing factor VIII a turbidity is observed which may be due to the presence of chylomicrons.The purified factor VIII was active in vivo as well as in vitro.

The occurrence of long chain polyprenols in leaves of plants of Rosaceae family and their isolation by time-extended liquid chromatography

1992 ◽  
Vol 70 (6) ◽  
pp. 448-454 ◽  
Author(s):  
Ewa Świeżewska ◽  
T. Chojnacki ◽  
W. J. Jankowski ◽  
K. Singh ◽  
J. Olsson
Keyword(s):  
Liquid Chromatography ◽  
Fatty Acid ◽  
Large Scale ◽  
Fatty Acid Esters ◽  
Large Scale Preparation ◽  
Scale Preparation ◽  
Wet Weight ◽  
Rosaceae Family ◽  
Acid Esters ◽  
Long Chain

The long chain polyprenols composed of 30 and more isoprene units from leaves of plants belonging to the genera Potentilla and Rosa have been described. They occur in the form of fatty acid esters. The composition of polyprenol mixture was species dependent and its content reached ca. 0.5% wet weight. Large scale preparation of individual polyprenols from a natural polyprenol mixture was performed using time-extended liquid chromatography on the hydrophobic gel Lipidex-5000.Key words: long chain polyprenols, Rosaceae.

Large-scale preparation of a 3D patchy surface with dissimilar dendritic amphiphiles

Soft Matter ◽  
2018 ◽  
Vol 14 (6) ◽  
pp. 1043-1049 ◽  
Author(s):  
Yanyan Feng ◽  
Yujia Wan ◽  
Ming Jin ◽  
Decheng Wan
Keyword(s):  
Large Scale ◽  
Large Scale Preparation ◽  
Porous Monolith ◽  
Scale Preparation ◽  
Surface Decoration ◽  
Scale Surface

We show here the first example of the large-scale surface decoration of a macroscopic and porous monolith with dissimilar micropatches.

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