α-Aminophosphonates. III. Cycloaddition anionique-1,3 des esters α,β-insaturés: Préparation et transformations des Δ1-pyrrolines

1988 ◽  
Vol 66 (2) ◽  
pp. 310-318 ◽  
Author(s):  
André Dehnel ◽  
Jolanta M. Kanabus-Kaminska ◽  
Gilbert Lavielle
Keyword(s):  
Atmospheric Oxygen ◽  
The Other ◽  
Phenyl Substituent ◽  
Experimental Conditions ◽  
Unsaturated Esters ◽  
Protic Media

The anions of the 2-azaallylphosphonates 1 react with the α,β-unsaturated esters 2 to yield the intermediates 4′. These intermediates form the 2-diethoxyphosphonyl-4-ethoxycarbonylpyrrolidines 4 following a protonation while an elimination of the anion of the diethylphosphonate leads to the 4-ethoxycarbonyl-Δ1-pyrrolines 5. The proportions of these two products vary with the experimental conditions and the bulkiness of the substrates. The formation of the cyclic products has been studied for numerous substrates and in the presence of a number of bases. The reaction is regioselective and stereospecific and on the basis of the formation of the kinetically more strained diastereoisomer it is possible to conclude that the cycloaddition is a concerted one. The thermodynamically less strained diastereoisomers 6 and 7 are obtained from the compounds 4 and 5 respectively when they are subjected to the action of a base in a protic media. The other epimers of 4, the compounds 8 and 9, have been obtained by the addition of diethylphosphite to the pyrrolines 5 and 7. The pyrrolines 5 have been reduced to the 3-ethoxycarbonylpyrrolidines 12. The isomerization of the pyrrolines 5 with a phenyl substituent in position 5 leads to the formation of the 3-ethoxycarbonyl-2-phenyl-Δ1-pyrrolines 10. The latter spontaneously oxidize with atmospheric oxygen to yield the 3-ethoxycarbonyl-3-hydroxy-2-phenyl-Δ1-pyrrolines 11. [Journal translation]

Intercalation Processes in Cobalt Substituted Nickel Oxyhydroxides

1990 ◽  
Vol 210 ◽  
Author(s):  
Claude Delmas
Keyword(s):  
Ir Spectroscopy ◽  
Mechanical Treatment ◽  
Positive Charge ◽  
Van Der Waals ◽  
The Other ◽  
Hydrolysis Reaction ◽  
Water Molecules ◽  
Layered Oxides ◽  
Experimental Conditions ◽  
Cobalt Ions

AbstractChimie douce reactions (hydrolysis and reduction) from layered oxides : NaNiO2, NaxCoO2 and NaNil-xCoxO2 lead to numerous oxyhydroxides and hydroxides which differ by the composition of the intersheet space.According to the experimental conditions of the hydrolysis reaction, the oxyhydroxides can be unhydrated or intercalated with one or two layers of water molecules. From the most hydrated phases, the other ones can be obtained by chemical, thermal and even mechanical treatment.The reduction of Co-substituted nickel oxyhydroxides leads to hydroxides in which nickel and cobalt ions are respectively divalent and trivalent. In order to compensate the excess of positive charge in the (Ni, Co)O2 sheet, anions (OH-, CO32-, SO42-, NO3-) are inserted in the Van der Waals gap.For the highest anion amounts, well ordered α*-type materials are obtained. Water molecules are simultaneously inserted in the interslab space. Their structure is strongly related to the hydrotalcite one. When the amouit of anions in the intersheet space is not sufficient, interstratified materials are obtained. In this case the (Ni,Co)(OH)2 slabs are separated by a layer of CO32- anions and water molecules (α*-type) or by an empty Van der Waals gap (β(II)-type). The amount of α*-type planes in the structure increases with the cobalt amount. All these materials have been characterized by IR spectroscopy which allows to detect the existence of two types of O-H bonds (free in α*-type plane or hydrogen bonded in ²(II)-type plane).

THE IMMATURE STAGES OF PTYCHOPTERA LENIS LENIS (DIPTERA: PTYCHOPTERIDAE) WITH NOTES ON THEIR BIOLOGY

1973 ◽  
Vol 105 (8) ◽  
pp. 1091-1099 ◽  
Author(s):  
I. D. Hodkinson
Keyword(s):  
Life Cycle ◽  
Water Depth ◽  
Adult Stage ◽  
Atmospheric Oxygen ◽  
Adult Emergence ◽  
Fourth Instar ◽  
Immature Stages ◽  
Experimental Conditions ◽  
Marginal Areas ◽  
Pharate Adult

AbstractThe four larval instars and the pupa of Ptychoptera lenis lenis Osten Sacken are described. Instars 2 to 4 are very similar morphologically but instar 1 is markedly different. Both a pharate pupal and a pharate adult stage were observed. Larvae are found in stagnant marginal areas of ponds where water depth does not exceed 4 cm and where benthic deposits of plant detritus exceed 8 cm. Fourth instar larvae, under experimental conditions, survived up to 45 days without contact with atmospheric oxygen but development was arrested. P. lenis has a 1 year life cycle with an extended adult emergence season from late May to the end of July.

In Vitro Binding of Zearalenone to Different Adsorbents

2005 ◽  
Vol 68 (3) ◽  
pp. 613-615 ◽  
Author(s):  
DANTE J. BUENO ◽  
LILIANA DI MARCO ◽  
GUILLERMO OLIVER ◽  
ALICIA BARDÓN
Keyword(s):  
Activated Carbon ◽  
Calcium Sulfate ◽  
Fusarium Species ◽  
The Other ◽  
Experimental Conditions ◽  
In Vitro Binding ◽  
Other Hand ◽  
Vitro Binding ◽  
Dose Levels

Zearalenone (ZEA) is a potent estrogenic metabolite produced by some Fusarium species. No treatment has been successfully employed to get rid of the ZEA contained in foods. This study was conducted to evaluate the ability (adsorptive power) of five adsorbents—activated carbon, bentonite, talc, sandstone, and calcium sulfate—to trap ZEA in vitro. Activated carbon was the best adsorbent, binding 100% ZEA (pH 3 and 7.3) at 0.1, 0.25, 0.5, and 1% dose levels. Bentonite, talc, and calcium sulfate were less efficient than activated carbon but still could bind ZEA to some extent. On the other hand, sandstone was inactive in the experimental conditions employed. Our results indicate that activated carbon could be a good candidate for detoxification of ZEA present in foods.

The Effects of Adverse Environmental Conditions on Workload

1975 ◽  
Vol 19 (3) ◽  
pp. 301-304
Author(s):  
Ann E. Martin
Keyword(s):  
Environmental Conditions ◽  
Environmental Variables ◽  
Secondary Task ◽  
The Other ◽  
Random Numbers ◽  
Performance Decrement ◽  
Experimental Conditions ◽  
Continuous Noise ◽  
Adverse Environmental Conditions ◽  
Intermittent Noise

The present study was conducted to investigate the effects of environmental conditions on visual workload. The environmental variables used were temperature, studied at levels of 45°F., WBGT, and 95°F., WBGT; and noise, studied at 83 dBA intermittent noise and 93 dBA continuous noise. Workload was defined as the amount of attention demanded from an operator as measured by performance decrement on a secondary task while performing a primary and secondary task simultaneously. The secondary task was reading random numbers, and the primary task was reading word lists. Significant differences (p<.05) were found between the control condition and all experimental conditions. The low temperature and high temperature-continuous noise conditions were significantly different from the other conditions. Noise and temperature were found to significantly increase workload (p<05).

scholarly journals Cultivation of Milky Mushroom (Calocybeindica) in Greenhouse

2021 ◽  
pp. 63-69
Author(s):  
P. Indraja ◽  
M. Madhava ◽  
S. Satyam ◽  
P. R. Chandra ◽  
S. Joy Prince
Keyword(s):  
Relative Humidity ◽  
Traditional Method ◽  
Large Scale ◽  
Nutritive Value ◽  
Edible Mushroom ◽  
Atmospheric Temperature ◽  
The Other ◽  
Controlled Environment ◽  
Mushroom Cultivation ◽  
Experimental Conditions

Mushroom cultivation is one of the most important steps in diversification of agriculture. Milky mushroom (Calocybeindica) is a tropical edible mushroom, popular because of its good nutritive value and it can be cultivated commercially on large scale. Generally, by creating controlled environment in rooms mushroom cultivation is taken up, In traditional method  it is typical to manage the atmospheric temperature and humidity in desired range, which can be maintained easily in greenhouse by automatic control system.Cultivation of milky mushroom in greenhouse was taken up in controlled environment under three different conditions of controlled temperature and relative humidity (RH). The experimental conditions are 28°C and 79% RH, 24°C and 84% RH and 32°C and 72%RH. The yield obtained was found maximum at 24°C temperature and 84% relative humidity when compared with the other two greenhouse environment conditions. The yield from the mushroom cultivation under controlled environmental conditions in greenhouse was found to be high when compared with the conventional practice. It was concluded that, the mushroom cultivation yields high under controlled greenhouse conditions and also economical compared to the conventional method.

scholarly journals Effect of ceramic thicknesses and opacities on water sorption and solubility of a light-curing resin cement by different units

2021 ◽  
Vol 20 ◽  
pp. e211656
Author(s):  
Gabriela Alves de Cerqueira ◽  
Lais Sampaio Souza ◽  
Rafael Soares Gomes ◽  
Giselle Maria Marchi ◽  
Paula Mathias
Keyword(s):  
Water Sorption ◽  
Light Emitting Diode ◽  
Lithium Disilicate ◽  
Resin Cement ◽  
The Other ◽  
Experimental Conditions ◽  
Light Emitting ◽  
Light Curing

Aim: This study evaluated the water sorption and solubility of a light-cured resin cement, under four thicknesses and four opacities of a lithium disilicate ceramic, also considering three light-emitting diode (LED) units. Methods: A total of 288 specimens of a resin cement (AllCem Veneer Trans – FGM) were prepared, 96 samples were light-cured by each of the three light curing units (Valo – Ultradent / Radii-Cal – SDI / Bluephase II – Ivoclar Vivadent), divided into 16 experimental conditions, according to the opacities of the ceramic: High Opacity (HO), Medium Opacity (MO), Low Translucency (LT), High Translucency (HT), and thicknesses (0.3, 0.8, 1.5, and 2.0 mm) (n = 6). The specimens were weighed at three different times: Mass M1 (after making the specimens), M2 (after 7 days of storage in water), and M3 (after dissection cycle), for calculating water sorption and solubility. Results: The higher thickness of the ceramic (2.0 mm) significantly increased the values of water sorption (44.0± 4.0) and solubility (7.8±0.6), compared to lower thicknesses. Also, the ceramic of higher opacity (HO) generated the highest values of sorption and solubility when compared to the other opacities, regardless of the thickness tested (ANOVA-3 factors / Tukey’s test, α = 0.05). There was no influence of light curing units. Conclusion: Higher thicknesses and opacities of the ceramic increased the water sorption and solubility of the tested light-cured resin cement.

scholarly journals Relations and evolution in Cheilanthes (Sinopteridaceae, Pteridophita) in Macaronesia and Mediterranean area, deduced from genome analysis of their hybrids

1983 ◽  
Vol 8 ◽  
pp. 101-126 ◽  
Author(s):  
G. Vida ◽  
A. Major ◽  
T. Reichstein
Keyword(s):  
Chromosome Number ◽  
Genome Analysis ◽  
Chromosome Doubling ◽  
Diploid Species ◽  
Mediterranean Area ◽  
Basic Chromosome Number ◽  
The Other ◽  
Experimental Conditions ◽  
Natural Group ◽  
Basic Chromosome

Nine species of "Cheilantoid ferns" are known to grow in Macaronesia and the Mediterranean basin. Two of them (lacking a pseudo-indusium and having the basic chromosome number X = 29), both aggregate species which we prefer to retain in Notholaena, are not included in this study. The other seven species (with distinct pseudo-indusium and the basic chromosome number X = 30), which we accept as members of the genus Cheilanthes Sw. sensu stricto, were subjected to detailed genome analysis of their natural and experimentally produced hybrids and shown to represent an aggregate of four very distinct ancestral diploids and three allotetraploids. The latter must have once been formed by chromosome doubling in the three diploid hybrids of C. maderensis Lowe with the other three diploid species. Theoretically three more allotetraploids would be possible but their formation has obviously been prevented by the geographical separation of the three respective diploids. The most widely distributed of the tetraploids, i.e. C. pteridioides (Reich.) C.Chr. has also been resynthesized from its ancestors (still sympatric) under experimental conditions. The intermediate morphology of the allotetraploids (as compared with their diploid ancestors) is obviously the reason why their status and existence has so long escaped recognition in Europe. These seven species form a natural group and, in our opinion, should not be divided into sections.

Priming Effects of Violence on Infrahumanization

2009 ◽  
Vol 12 (6) ◽  
pp. 699-714 ◽  
Author(s):  
Naira Delgado ◽  
Armando Rodríguez-Pérez ◽  
Jeroen Vaes ◽  
Jacques-Philippe Leyens ◽  
Verónica Betancor
Keyword(s):  
Lexical Decision ◽  
Lexical Decision Task ◽  
The Other ◽  
Decision Task ◽  
Human Suffering ◽  
Experimental Conditions ◽  
Priming Effects ◽  
Contextual Dependency ◽  
Underlying Mechanisms ◽  
Effects Of Violence

Two experiments examine whether exposure to generic violence can display infrahumanization towards out-groups. In Study 1, participants had to solve a lexical decision task after viewing animal or human violent scenes. In Study 2, participants were exposed to either human violent or human suffering pictures before doing a lexical decision task. In both studies, the infrahumanization bias appeared after viewing the human violent pictures but not in the other experimental conditions. These two experiments support the idea of contextual dependency of infrahumanization, and suggest that violence can prime an infrahuman perception of the out-group. Theoretical implications for infrahumanization and potential underlying mechanisms are discussed.

scholarly journals Well-Being and Throwing Speed of Women Handball Players Affected by Feedback

2020 ◽  
Vol 17 (17) ◽  
pp. 6064
Author(s):  
Diego Soto ◽  
Juan Antonio García-Herrero ◽  
Rodrigo J. Carcedo
Keyword(s):  
Positive Affect ◽  
Training Programs ◽  
Well Being ◽  
The Other ◽  
Positive And Negative Affect ◽  
Experimental Conditions ◽  
Feedback Group ◽  
Competence Motivation ◽  
And Performance ◽  
Speed And Accuracy

This research aims at studying the effect of feedback on well-being (vitality, and positive and negative affect), competence valuation, perceived competence, motivation, and performance (throwing speed and accuracy) in a throwing task. Thirty nine expert women handball players, with experience in international handball competitions, participated in this study. They were indiscriminately ascribed to one of three different experimental conditions measuring feedback: (positive, negative, and none). Significant differences in well-being (positive affect) and throwing speed were found among the three feedback groups. More concretely, higher levels of positive affect and throwing speed were found in the negative feedback group in comparison with the other two groups (positive and no-feedback). These results have important implications for athletes’ well-being and performance, and for coaches’ training programs.

scholarly journals Copper Complexes of Benzoylacetone Bis-Thiosemicarbazones: Metal and Ligand Based Redox Reactivity

2021 ◽  
Vol 74 (1) ◽  
pp. 34 ◽  
Author(s):  
Jessica K. Bilyj ◽  
Jeffrey R. Harmer ◽  
Paul V. Bernhardt
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Cyclic Voltammetry ◽  
Copper Complexes ◽  
Atmospheric Oxygen ◽  
The Other ◽  
Oxidation Reactions ◽  
Paramagnetic Resonance ◽  
Time Resolved ◽  
Vis Spectroscopy ◽  
Electron Paramagnetic

Bis-thiosemicarbazones derived from the β-diketone benzoylacetone (H3banR, R=Me, Et, Ph) are potentially tetradentate N2S2 ligands whose coordination chemistry with copper is reported. In the absence of oxygen and in the presence of base they form anionic CuII complexes of the fully deprotonated ligands [CuII(banR)]–. Upon exposure to atmospheric oxygen they undergo a complex series of reactions leading to two types of products; one a ligand oxidised ketone complex [CuII(banRO)] and the other an unprecedented dimeric di-CuIII complex [(CuIII(banR))2] depending on the R substituent. Time-resolved UV-vis spectroscopy, cyclic voltammetry, spectroelectrochemistry, and electron paramagnetic resonance (EPR) spectroscopy have been used to identify intermediates on the way to stable products formed under both anaerobic and aerobic conditions. It is found that both ligand-centred and Cu-centred oxidation reactions are occurring in parallel leading to this unusually complicated mixture of products.

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