Temperature dependence of the NH–proton hyperfine splitting in ButNHO•

1984 ◽  
Vol 62 (1) ◽  
pp. 139-140 ◽  
Author(s):  
Roberto Henriquez ◽  
M. John Perkins ◽  
David Griller
Keyword(s):  
Hyperfine Interaction ◽  
Temperature Dependence ◽  
Hyperfine Splitting ◽  
Out Of Plane ◽  
Plane Bending ◽  
Increasing Temperature

Hyperfine splitting by the NH proton in ButNHO• decreases markedly with increasing temperature, whilst the nitrogen hyperfine interaction shows a small increase. These observations are consistent with an increase in the out-of-plane bending as the temperature is raised.

Temperature dependence of the electron resonance spectrum of the hydrazine positive ion

1968 ◽  
Vol 46 (10) ◽  
pp. 1703-1706 ◽  
Author(s):  
H. R. Falle
Keyword(s):  
Temperature Dependence ◽  
Torsional Vibration ◽  
Hyperfine Splitting ◽  
Resonance Spectrum ◽  
Electron Resonance ◽  
Temperature Study ◽  
Temperature Range ◽  
Increasing Temperature ◽  
Positive Ion

A temperature study of the hydrazine positive ion, N2H4+, showed that the ratio of the nitrogen hyperfine splitting to the proton hyperfine splitting, |aN/aH| increased with increasing temperature. The increase in |aN/aH| was approximately 3%, while the increase in aN itself was less than 1% over the 50 °C temperature range. This effect is attributed to torsional vibration about the N—N bond and is assessed on this basis.

Comparison of Failure Modes of Piping Systems With Wall Thinning Subjected to In-Plane, Out-of-Plane, and Mixed Mode Bending Under Seismic Load: An Experimental Approach

2010 ◽  
Vol 132 (3) ◽  
Author(s):  
Izumi Nakamura ◽  
Akihito Otani ◽  
Masaki Shiratori
Keyword(s):  
Dynamic Behavior ◽  
Failure Modes ◽  
Seismic Load ◽  
Piping System ◽  
Shake Table ◽  
Shake Table Tests ◽  
Wall Thinning ◽  
Piping Systems ◽  
Out Of Plane ◽  
Plane Bending

Pressurized piping systems used for an extended period may develop degradations such as wall thinning or cracks due to aging. It is important to estimate the effects of degradation on the dynamic behavior and to ascertain the failure modes and remaining strength of the piping systems with degradation through experiments and analyses to ensure the seismic safety of degraded piping systems under destructive seismic events. In order to investigate the influence of degradation on the dynamic behavior and failure modes of piping systems with local wall thinning, shake table tests using 3D piping system models were conducted. About 50% full circumferential wall thinning at elbows was considered in the test. Three types of models were used in the shake table tests. The difference of the models was the applied bending direction to the thinned-wall elbow. The bending direction considered in the tests was either of the in-plane bending, out-of-plane bending, or mixed bending of the in-plane and out-of-plane. These models were excited under the same input acceleration until failure occurred. Through these tests, the vibration characteristic and failure modes of the piping models with wall thinning under seismic load were obtained. The test results showed that the out-of-plane bending is not significant for a sound elbow, but should be considered for a thinned-wall elbow, because the life of the piping models with wall thinning subjected to out-of-plane bending may reduce significantly.

Stresses in Curved, Circular Thin-Wall Tubes

1963 ◽  
Vol 30 (1) ◽  
pp. 134-135
Author(s):  
E. A. Utecht
Keyword(s):  
Thin Wall ◽  
Bending Moments ◽  
Circular Tubes ◽  
Out Of Plane ◽  
Thin Walled ◽  
Plane Bending

Curves are presented which give stress intensification factors for curved, thin-walled circular tubes under various combinations of in-plane and out-of-plane bending moments.

Article

1998 ◽  
Vol 76 (4) ◽  
pp. 411-413
Author(s):  
Yixing Zhao ◽  
Gordon R Freeman
Keyword(s):  
Absorption Spectrum ◽  
Optical Absorption ◽  
Temperature Dependence ◽  
Optical Absorption Spectrum ◽  
Infrared Light ◽  
Solvated Electron ◽  
Solvated Electrons ◽  
Tert Butanol ◽  
Solvent Dependence ◽  
Increasing Temperature

The energy and asymmetry of the optical absorption spectrum of solvated electrons, es- , change in a nonlinear fashion on changing the solvent through the series HOH, CH3OH, CH3CH3OH, (CH3)2CHOH, (CH3)3COH. The ultimate, quantum-statistical mechanical, interpretation of solvated electron spectra is needed to describe the solvent dependence. The previously reported optical spectrum of es- in tert-butanol was somewhat inaccurate, due to a small amount of water in the alcohol and to limitations of the infrared light detector. The present note records the remeasured spectrum and its temperature dependence. The value of the energy at the absorption maximum (EAmax) is 155 zJ (0.97 eV) at 299 K and 112 zJ (0.70 eV) at 338 K; the corresponding values of G epsilon max (10-22 m2 aJ-1) are 1.06 and 0.74. These unusually large changes are attributed to the abnormally rapid decrease of dielectric permittivity of tert-butanol with increasing temperature. The band asymmetry at 299 K is Wb/Wr = 1.8.Key words: optical absorption spectrum, solvated electron, solvent effects, tert-butanol, temperature dependence.

Out-of-Plane Bending (Opb) Test of Large Diameter Mooring Chains

2021 ◽  
Author(s):  
m.r. Karimi ◽  
J. Braun ◽  
E. Gooijer ◽  
P. Barros ◽  
E. Carlberg ◽  
...  
Keyword(s):  
Large Diameter ◽  
Out Of Plane ◽  
Plane Bending

scholarly journals Temperature-Driven Spin Reorientation Transition in CoPt/AlN Multilayer Films

2012 ◽  
Vol 2012 ◽  
pp. 1-7
Author(s):  
Wupeng Cai ◽  
Shinji Muraishi ◽  
Ji Shi ◽  
Yoshio Nakamura ◽  
Wei Liu ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Mean Field ◽  
Multilayer Films ◽  
Spin Reorientation ◽  
Strong Temperature Dependence ◽  
Mean Field Model ◽  
Spin Reorientation Transition ◽  
Magnetoelastic Effect ◽  
Out Of Plane ◽  
Interface Anisotropy

Spin reorientation transition phenomena from out-of-plane to in-plane direction with increasing temperature are observed for the 500°C annealed CoPt/AlN multilayer films with different CoPt layer thicknesses. CoPt-AlN interface and volume anisotropy contributions, favoring out-of-plane and in-plane magnetization, respectively, are separately determined at various temperatures. Interface anisotropy exhibits much stronger temperature dependence than volume contribution, hence the temperature-driven spin reorientation transition occurs. Interface anisotropy in this work consists of Néel interface anisotropy and magnetoelastic effect. Magnetoelastic effect degrades rapidly and changes its sign from positive to negative above 200°C, because of the involvement of stress state in CoPt films with temperature. By contrast, Néel interface anisotropy decays slowly, estimated from a Néel mean field model. Thus, the strong temperature dependence of CoPt-AlN interface anisotropy is dominated by the change of magnetoelastic effect.

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