Temperature dependence of the electron resonance spectrum of the hydrazine positive ion

1968 ◽  
Vol 46 (10) ◽  
pp. 1703-1706 ◽  
Author(s):  
H. R. Falle
Keyword(s):  
Temperature Dependence ◽  
Torsional Vibration ◽  
Hyperfine Splitting ◽  
Resonance Spectrum ◽  
Electron Resonance ◽  
Temperature Study ◽  
Temperature Range ◽  
Increasing Temperature ◽  
Positive Ion

A temperature study of the hydrazine positive ion, N2H4+, showed that the ratio of the nitrogen hyperfine splitting to the proton hyperfine splitting, |aN/aH| increased with increasing temperature. The increase in |aN/aH| was approximately 3%, while the increase in aN itself was less than 1% over the 50 °C temperature range. This effect is attributed to torsional vibration about the N—N bond and is assessed on this basis.

The flow of liquids with a temperature anomaly of viscosity

2003 ◽  
Vol 3 ◽  
pp. 232-245
Author(s):  
V.N. Kireev ◽  
S.F. Urmancheev
Keyword(s):  
Fluid Flow ◽  
Temperature Dependence ◽  
Temperature Anomaly ◽  
Numerical Study ◽  
Liquid Sulfur ◽  
Temperature Range ◽  
External Conditions ◽  
Increasing Temperature ◽  
Viscosity Dependence

For the vast majority of liquids, viscosity is a function that decreases monotonically with increasing temperature. However, a number of substances in which processes of polymerization and depolymerization can occur in a certain temperature range have a viscosity with a nonmonotonic temperature dependence. This dependence, for example, is characteristic of liquid sulfur. In this paper we present the results of a numerical study of the features of the flow of a liquid with a certain model nonmonotonic viscosity dependence on the temperature. The formation of a ”viscous barrier“ that determines the nature of the fluid flow in the channel is established. The main regularities of the flow are determined depending on the parameters of the viscous anomaly and external conditions.

g-Values for γ-irradiated water as a function of temperature

1990 ◽  
Vol 68 (5) ◽  
pp. 712-719 ◽  
Author(s):  
A. John Elliot ◽  
Monique P. Chenier ◽  
Denis C. Ouellette
Keyword(s):  
Experimental Data ◽  
Hydrogen Peroxide ◽  
Hydroxyl Radical ◽  
Temperature Dependence ◽  
Atomic Hydrogen ◽  
Molecular Hydrogen ◽  
Hydrated Electron ◽  
Temperature Range ◽  
Increasing Temperature

The g-values of primary species formed in the γ-radiolysis of water have been estimated for the temperature range 25–300 °C. The g-values for the hydrated electron, the hydroxyl radical, and molecular hydrogen all increase approximately 50% over this temperature range. The g-values for the minor products, hydrogen peroxide and atomic hydrogen, probably also increase with temperature; however, there is evidence from some of the experimental data which suggests that these g-values may slightly decrease with increasing temperature. Keywords: radiolysis, g-values, temperature dependence.

Temperature dependence of the shape of the cellodextrins in aqueous solution

1967 ◽  
Vol 45 (20) ◽  
pp. 2363-2367 ◽  
Author(s):  
M. Ihnat ◽  
D. A. I. Goring
Keyword(s):  
Aqueous Solution ◽  
Temperature Dependence ◽  
Computational Methods ◽  
Negative Temperature ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Increasing Temperature

Intrinsic viscosities of the cellodextrins, cellobiose to cellohexaose, were measured in aqueous solution at temperatures from 25 to 70 °C. Axial ratios were determined using the Einstein–Simha viscosity relation and the computational methods developed previously. The results showed that the oligomers are fully extended over this temperature range and that the negative temperature coefficients of the intrinsic viscosities are caused by the dehydration of the molecules with increasing temperature.

scholarly journals WETTING ANGLE POLYTERMES FOR LEAD-SODIUM MELTS ON REFRACTORY METALS

2020 ◽  
pp. 113-119
Author(s):  
Барасби Сулейманович Карамурзов ◽  
Руслан Азаевич Кутуев ◽  
Мурат Хажисмелович Понежев ◽  
Виктор Адыгеевич Созаев ◽  
Астемир Хусенович Шерметов ◽  
...  
Keyword(s):  
Contact Angle ◽  
Stainless Steel ◽  
Temperature Dependence ◽  
Refractory Metals ◽  
Wetting Angle ◽  
Temperature Range ◽  
Drop Method ◽  
Pure Helium ◽  
Increasing Temperature

Методом лежащей капли изучена температурная зависимость краевого угла смачивания сплавов Pb - Na разной концентрации на подложках из Co - Cr, Ni - Cr, нержавеющей стали 251892. Измерения проводились методом лежащей капли в широком интервале температур от 359°С до 800 °С в атмосфере чистого марки А. Показано, что значение угла смачивания уменьшается с увеличением температуры, наблюдаются пороги смачивания. The temperature dependence of the contact angle for Pb - Na melts of different concentrations on Co - Cr , Ni - Cr and stainless steel 25X18H9C2 substrate was studied by the method of a lying drop. Measurements were carried out by a lying drop method in the temperature range from 359 to 800 °C in an atmosphere of pure helium grade A. It is shown that the value of the wetting angle decreases with increasing temperature, wetting thresholds are observed.

Temperature dependence of the NH–proton hyperfine splitting in ButNHO•

1984 ◽  
Vol 62 (1) ◽  
pp. 139-140 ◽  
Author(s):  
Roberto Henriquez ◽  
M. John Perkins ◽  
David Griller
Keyword(s):  
Hyperfine Interaction ◽  
Temperature Dependence ◽  
Hyperfine Splitting ◽  
Out Of Plane ◽  
Plane Bending ◽  
Increasing Temperature

Hyperfine splitting by the NH proton in ButNHO• decreases markedly with increasing temperature, whilst the nitrogen hyperfine interaction shows a small increase. These observations are consistent with an increase in the out-of-plane bending as the temperature is raised.

Specific features of the temperature dependence of tryptophan fluorescence lifetime in the temperature range of −170–20 °C

2020 ◽  
Vol 393 ◽  
pp. 112435
Author(s):  
Peter P. Knox ◽  
Vladimir V. Gorokhov ◽  
Boris N. Korvatovsky ◽  
Nadezhda P. Grishanova ◽  
Sergey N. Goryachev ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Fluorescence Lifetime ◽  
Tryptophan Fluorescence ◽  
Temperature Range

scholarly journals Cell mechanical properties of human breast carcinoma cells depend on temperature

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Christian Aermes ◽  
Alexander Hayn ◽  
Tony Fischer ◽  
Claudia Tanja Mierke
Keyword(s):  
Mechanical Properties ◽  
Power Law ◽  
Cell Mechanics ◽  
Cell Types ◽  
Creep Response ◽  
Temperature Range ◽  
Myosin Filaments ◽  
Cell Mechanical Properties ◽  
Increasing Temperature ◽  
Mcf 7

AbstractThe knowledge of cell mechanics is required to understand cellular processes and functions, such as the movement of cells, and the development of tissue engineering in cancer therapy. Cell mechanical properties depend on a variety of factors, such as cellular environments, and may also rely on external factors, such as the ambient temperature. The impact of temperature on cell mechanics is not clearly understood. To explore the effect of temperature on cell mechanics, we employed magnetic tweezers to apply a force of 1 nN to 4.5 µm superparamagnetic beads. The beads were coated with fibronectin and coupled to human epithelial breast cancer cells, in particular MCF-7 and MDA-MB-231 cells. Cells were measured in a temperature range between 25 and 45 °C. The creep response of both cell types followed a weak power law. At all temperatures, the MDA-MB-231 cells were pronouncedly softer compared to the MCF-7 cells, whereas their fluidity was increased. However, with increasing temperature, the cells became significantly softer and more fluid. Since mechanical properties are manifested in the cell’s cytoskeletal structure and the paramagnetic beads are coupled through cell surface receptors linked to cytoskeletal structures, such as actin and myosin filaments as well as microtubules, the cells were probed with pharmacological drugs impacting the actin filament polymerization, such as Latrunculin A, the myosin filaments, such as Blebbistatin, and the microtubules, such as Demecolcine, during the magnetic tweezer measurements in the specific temperature range. Irrespective of pharmacological interventions, the creep response of cells followed a weak power law at all temperatures. Inhibition of the actin polymerization resulted in increased softness in both cell types and decreased fluidity exclusively in MDA-MB-231 cells. Blebbistatin had an effect on the compliance of MDA-MB-231 cells at lower temperatures, which was minor on the compliance MCF-7 cells. Microtubule inhibition affected the fluidity of MCF-7 cells but did not have a significant effect on the compliance of MCF-7 and MDA-MB-231 cells. In summary, with increasing temperature, the cells became significant softer with specific differences between the investigated drugs and cell lines.

Temperature dependence of chlorine-35 N.Q.R. in 2,6-Dichlorophenol

1978 ◽  
Vol 31 (4) ◽  
pp. 791 ◽  
Author(s):  
R Chandramani ◽  
SP Basavaraju ◽  
N Devaraj
Keyword(s):  
Temperature Dependence ◽  
Room Temperature ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Brown's Method

Chlorine n.q.r, in 2,6-dichlorophenol has been investigated at temperatures from 77 K to room temperature. Two resonance lines due to chemically inequivalent sites have been observed throughout this temperature range. Torsional frequencies of the molecule have been calculated at temperatures from 77 to 300 K according to Bayer's theory and Brown's method. Also the temperature coefficients of the torsional frequencies have been calculated.

scholarly journals PSEUDO-GAP FEATURES OF INTRINSIC TUNNELING IN (HgBr2)-Bi2212 SINGLE CRYSTALS

1999 ◽  
Vol 13 (29n31) ◽  
pp. 3758-3763 ◽  
Author(s):  
AUGUST YURGENS ◽  
DAG WINKLER ◽  
TORD CLAESON ◽  
SEONG-JU HWANG ◽  
JIN-HO CHOY
Keyword(s):  
Temperature Dependence ◽  
Single Crystals ◽  
Room Temperature ◽  
Unit Cell ◽  
Superconducting Gap ◽  
Axis Direction ◽  
Temperature Range ◽  
Dynamic Conductance

The c-axis tunneling properties of both pristine Bi2212 and its HgBr 2 intercalate have been measured in the temperature range 4.2-250 K. Lithographically patterned 7-10 unit-cell heigh mesa structures on the surfaces of these single crystals were investigated. Clear SIS-like tunneling curves for current applied in the c-axis direction have been observed. The dynamic conductance d I/ d V(V) shows both sharp peaks corresponding to a superconducting gap edge and a dip feature beyond the gap, followed by a wide maximum, which persists up to a room temperature. Shape of the temperature dependence of the c-axis resistance does not change after the intercalation suggesting that a coupling between CuO 2-bilayers has little effect on the pseudogap.

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