Toward an understanding of rates of crystal nucleation from solution with a variable driving force

1977 ◽  
Vol 55 (8) ◽  
pp. 1285-1293 ◽  
Author(s):  
Ronald E. Massey ◽  
O. E. Hileman Jr
Keyword(s):  
Driving Force ◽  
Crystal Nucleation ◽  
Time Data ◽  
Large Spread ◽  
Steady State Rate ◽  
State Rate ◽  
Lag Times ◽  
A New Technique ◽  
Individual Droplet

'Number-time' data obtained during studies on the nucleation from aqueous solution of CaSO4•2H2O (gypsum) using the droplet technique and a variable driving force are reported. Sulfate ion was generated, in situ, by the reaction between S2O82− and S2O32− in the presence of Ca2+. The rate of the reaction was determined from polarographic data. The stoichiometry and solubility of the precipitate in the aqueous matrix were determined.Problems which arise during analysis of 'number-time' data obtained from droplet experiments with a large spread in individual droplet volumes and a variable driving force using techniques suggested in the literature are commented upon. A new technique was developed and applied to the analysis of our data. The effects of a non-steady state rate of nucleation, variable lag times and a decreasing cation: anion ratio on the derived results are discussed.

Kinetic Study Of Crystallisation In Amorphous Thin Lpcvd Si Films

1993 ◽  
Vol 321 ◽  
Author(s):  
B. Pieraggi ◽  
J. P. Guillemet ◽  
B. de Mauduit
Keyword(s):  
Experimental Data ◽  
Steady State ◽  
Isothermal Annealing ◽  
Nucleation Kinetics ◽  
Crystallisation Kinetics ◽  
Crystallisation Behaviour ◽  
Steady State Rate ◽  
State Rate ◽  
Si Films

ABSTRACTThe crystallisation behaviour of LPCVD silicon films has been investigated by TEM from in situ isothermal annealing of undoped a-Si films deposited from disilane (Si2H6) at temperatures 450,465 and 480 °C and at gas pressure of 200 MTorr. Nucleation kinetics, grain growth rates and crystallisation kinetics were determined for temperatures ranging from 600 to 675 °C. Nucleation kinetics have been experimentally determined in the early first stages of annealing : they do not show any steady-state rate and are fitted according to a power law. Experimental data for crystallisation kinetics are fitted by an Avrami law without introducing any incubation time.

In situ TEM Studies of agglomeration of sub-nanometer Ru layers in Ru/C multilayers

1992 ◽  
Vol 50 (1) ◽  
pp. 256-257
Author(s):  
Tai D. Nguyen ◽  
Ronald Gronsky ◽  
Jeffrey B. Kortright
Keyword(s):  
Layered Structure ◽  
Driving Force ◽  
High Energy ◽  
Superior Performance ◽  
In Situ Tem ◽  
Rayleigh Instability ◽  
Practical Applications ◽  
Transmission Electron ◽  
Diffraction Patterns

Nanometer period Ru/C multilayers are one of the prime candidates for normal incident reflecting mirrors at wavelengths < 10 nm. Superior performance, which requires uniform layers and smooth interfaces, and high stability of the layered structure under thermal loadings are some of the demands in practical applications. Previous studies however show that the Ru layers in the 2 nm period Ru/C multilayer agglomerate upon moderate annealing, and the layered structure is no longer retained. This agglomeration and crystallization of the Ru layers upon annealing to form almost spherical crystallites is a result of the reduction of surface or interfacial energy from die amorphous high energy non-equilibrium state of the as-prepared sample dirough diffusive arrangements of the atoms. Proposed models for mechanism of thin film agglomeration include one analogous to Rayleigh instability, and grain boundary grooving in polycrystalline films. These models however are not necessarily appropriate to explain for the agglomeration in the sub-nanometer amorphous Ru layers in Ru/C multilayers. The Ru-C phase diagram shows a wide miscible gap, which indicates the preference of phase separation between these two materials and provides an additional driving force for agglomeration. In this paper, we study the evolution of the microstructures and layered structure via in-situ Transmission Electron Microscopy (TEM), and attempt to determine the order of occurence of agglomeration and crystallization in the Ru layers by observing the diffraction patterns.

scholarly journals Amplification characteristics in active tapered segmented cladding fiber with large mode area

2021 ◽  
Vol 9 ◽  
Author(s):  
Caijian Xie ◽  
Tigang Ning ◽  
Jingjing Zheng ◽  
Li Pei ◽  
Jianshuai Wang ◽  
...  
Keyword(s):  
High Power ◽  
Heat Load ◽  
Nonlinear Effects ◽  
Single Mode ◽  
Large Mode Area ◽  
High Loss ◽  
Effective Mode Area ◽  
Steady State Rate ◽  
State Rate ◽  
Mode Area

Abstract A kind of tapered segmented cladding fiber (T-SCF) with large mode area (LMA) is proposed, and the mode and amplification characteristics of T-SCFs with concave, linear, and convex tapered structures are investigated based on finite-element method (FEM) and few-mode steady-state rate equation. Simulation results indicate that the concave tapered structure can introduce high loss for high-order modes (HOMs) that is advantageous to achieve single-mode operation, whereas the convex tapered structure provides large effective mode area that can help to mitigate nonlinear effects. Meanwhile, the small-to-large amplification scheme shows further advantages on stripping off HOMs, and the large-to-small amplification scheme decreases the heat load density induced by the high-power pump. Moreover, single-mode propagation performance, effective mode area, and heat load density of the T-SCF are superior to those of tapered step index fiber (T-SIF). These theoretical model and numerical results can provide instructive suggestions for designing high-power fiber lasers and amplifiers.

CHARACTERIZING ANOMALIES IN DISTRIBUTED STRAIN MEASUREMENTS OF CAST-IN-SITU BORED PILES

2016 ◽  
Vol 78 (8-5) ◽  
Author(s):  
Hisham Mohamad ◽  
Bun Pin Tee ◽  
Koh An Ang ◽  
Mun Fai Chong
Keyword(s):  
Load Transfer ◽  
Load Test ◽  
Strain Sensing ◽  
Strain Profile ◽  
A New Technique ◽  
Optical Time ◽  
Distributed Optical Fiber ◽  
Non Destructive ◽  
Distributed Strain

This paper describes the method of identifying typical defects of bored cast-in-situ piles when instrumenting using Distributed Optical Fiber Strain Sensing (DOFSS). The DOFSS technology is based on Brillouin Optical Time Domain Analyses (BOTDA), which has the advantage of recording continuous strain profile as opposed to the conventional discrete based sensors such as Vibrating Wire strain gauges. In pile instrumentation particularly, obtaining distributed strain profile is important when analysing the load-transfer and shaft friction of a pile, as well as detecting any anomalies in the strain regime. Features such as defective pile shaft necking, discontinuity of concrete, intrusion of foreign matter and improper toe formation due to contamination of concrete at base with soil particles, among others, may cause the pile to fail. In this study, a new technique of detecting such defects is proposed using DOFSS technology which can potentially supplement the existing non-destructive test (NDT) methods. Discussion on the performance of instrumented piles by means of maintained load test are also presented

Corticosterone secretion in rats as a function of ACTH input and adrenal blood flow

1965 ◽  
Vol 209 (4) ◽  
pp. 811-814 ◽  
Author(s):  
John C. Porter ◽  
M. S. Klaiber
Keyword(s):  
Blood Flow ◽  
Steady State ◽  
Steady Increase ◽  
Constant Input ◽  
Corticosterone Secretion ◽  
Steady State Rate ◽  
State Rate

The rate of secretion of corticosterone from the left adrenal of rats receiving a constant input of ACTH was determined for different flows of blood through the adrenal during the 2- to 3-hr interval following hypophysectomy. Two hours after hypophysectomy the secretion of corticosterone was low in all groups regardless of flow. An input of 0.26 mU ACTH/min caused a steady increase in secretion for 30–40 min before a steady-state rate was attained. The average steady-state rate of secretion was 1.1, 2.4, 3.5, 6.2, 7.2, 6.2, and 6.2 µg/5 min for flows of 0.005, 0.012, 0.023, 0.034, 0.039, 0.051, and 0.058 ml/min, respectively. Under the conditions of these experiments where the input of ACTH was 0.26 mU/min the secretion of corticosterone increased significantly with time of input of ACTH and with flow of blood through the adrenal.

Battery Capacity Estimation From Partial-Charging Data Using Gaussian Process Regression

2017 ◽  
Author(s):  
Robert R. Richardson ◽  
Christoph R. Birkl ◽  
Michael A. Osborne ◽  
David A. Howey
Keyword(s):  
Gaussian Process ◽  
Gaussian Process Regression ◽  
Diagnostic Technique ◽  
Lithium Ion ◽  
Constant Current ◽  
Time Data ◽  
Capacity Estimation ◽  
Voltage Range ◽  
Battery Capacity

Accurate on-board capacity estimation is of critical importance in lithium-ion battery applications. Battery charging/discharging often occurs under a constant current load, and hence voltage vs. time measurements under this condition may be accessible in practice. This paper presents a novel diagnostic technique, Gaussian Process regression for In-situ Capacity Estimation (GP-ICE), which is capable of estimating the battery capacity using voltage vs. time measurements over short periods of galvanostatic operation. The approach uses Gaussian process regression to map from voltage values at a selection of uniformly distributed times, to cell capacity. Unlike previous works, GP-ICE does not rely on interpreting the voltage-time data through the lens of Incremental Capacity (IC) or Differential Voltage (DV) analysis. This overcomes both the need to differentiate the voltage-time data (a process which amplifies measurement noise), and the requirement that the range of voltage measurements encompasses the peaks in the IC/DV curves. Rather, GP-ICE gives insight into which portions of the voltage range are most informative about the capacity for a particular cell. We apply GP-ICE to a dataset of 8 cells, which were aged by repeated application of an ARTEMIS urban drive cycle. Within certain voltage ranges, as little as 10 seconds of charge data is sufficient to enable capacity estimates with ∼ 2% RMSE.

scholarly journals The Natural Rate of Interest and the Optimal Rate of Interest in the Steady State

2021 ◽  
pp. 17-41
Author(s):  
Carl Christian von Weizsäcker ◽  
Hagen M. Krämer
Keyword(s):  
Steady State ◽  
Public Debt ◽  
Fundamental Equation ◽  
Optimal Rate ◽  
Natural Rate ◽  
Real Rate ◽  
Capital Theory ◽  
Steady State Rate ◽  
Natural Rate Of Interest ◽  
State Rate

AbstractThe “natural rate of interest” is the hypothetical, risk-free real rate of interest that would obtain in a closed economy, if net public debt were zero. It is considerably less than the optimal steady-state rate of interest, which is equal to the system’s growth rate. This holds for a very general “meta-model.” The fundamental equation of capital theory holds on the optimal steady-state path: T = Z − D, where T is the overall economic period of production, Z is the representative private “waiting period” of consumers and D is the public debt ratio. Prosperity is at least 30% lower at the natural rate of interest than at the optimal rate.

scholarly journals In-situ measurement of reactive hydrocarbons at Hohenpeissenberg with comprehensive gas chromatography (GCxGC-FID): use in estimating HO and NO<sub>3</sub>

2006 ◽  
Vol 6 (4) ◽  
pp. 8155-8188
Author(s):  
S. Bartenbach ◽  
J. Williams ◽  
C. Plass-Dülmer ◽  
H. Berresheim ◽  
J. Lelieveld
Keyword(s):  
Mean Value ◽  
Time Data ◽  
Night Time ◽  
Radical Species ◽  
Diurnal Cycles ◽  
Meteorological Observatory ◽  
Variate Analysis ◽  
The Relationship ◽  
Good Agreement

Abstract. During a field campaign at the Meteorological Observatory Hohenpeissenberg (MOHp) in July 2004, VOCs were measured using GCxGC-FID. Comparison to routinely made GC-MS measurements showed good agreement for a variety of anthropogenic and biogenic ambient VOCs ranging in concentration from below the detection limit (0.1 pmol mol−1) to 180 pmol mol−1. Pronounced diurnal cycles were found for both the biogenic and anthropogenic compounds, driven for the most part by the daily rise and fall of the boundary layer over the station. For the reactive compounds (lifetimes <2 days), a significant, non-zero dependency of the variability on lifetime was found, indicating that chemistry (as opposed to transport alone) was playing a role in determining the ambient VOC concentrations. The relationship was exploited using a single-variate analysis to derive a daytime mean value of HO (5.3±1.4×106 molecules cm−3), which compares well to that measured at the site, 3.2±2.3×106 molecules cm−3. The analysis was extended to the night time data to estimate concentrations for NO3 (1.47±0.2×108 molecules cm−3), which is not measured at the site. The feasibility of this approach for environments dominated by emissions of short-lived VOCs to estimate ambient levels of radical species is discussed.

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