A photoelectron investigation of acyl silanes: the photoelectron spectra of trimethylsilyl phenyl ketone and phenyl tert-butyl ketone

1976 ◽  
Vol 54 (1) ◽  
pp. 188-188
Author(s):  
R. S. Brown
Keyword(s):  
Photoelectron Spectra ◽  
Tert Butyl ◽  
Phenyl Ketone ◽  
Butyl Ketone

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A Photoelectron Investigation of Acyl Silanes: The Photoelectron Spectra of Trimethylsilyl Phenyl Ketone and Phenyl tert-Butyl Ketone

1975 ◽  
Vol 53 (16) ◽  
pp. 2446-2449 ◽  
Author(s):  
R. S. Brown
Keyword(s):  
Energy Level ◽  
Low Energy ◽  
Ionization Potentials ◽  
Photoelectron Spectra ◽  
Energy Level Diagram ◽  
Tert Butyl ◽  
Partial Energy ◽  
Phenyl Ketone ◽  
Butyl Ketone

The photoelectron spectra of trimethylsilyl phenyl ketone and phenyl tert-butyl ketone are presented and analyzed in terms of their constituent orbitals. A hyperconjugative interpretation for the low energy ionization potentials of the acyl silanes is postulated. A combination of p.e. spectroscopy and u.v. data are used to infer the level of the LUMO in these systems and to construct a partial energy level diagram.

Photochemistry of di-tert-butyl ketone and structural effects on the rate and efficiency of intersystem crossing of aliphatic ketones

1970 ◽  
Vol 92 (23) ◽  
pp. 6974-6976 ◽  
Author(s):  
Nien-Chu. Yang ◽  
Eugene D. Feit ◽  
Man Him. Hui ◽  
Nicholas J. Turro ◽  
J. Christopher. Dalton
Keyword(s):  
Intersystem Crossing ◽  
Structural Effects ◽  
Tert Butyl ◽  
Aliphatic Ketones ◽  
Butyl Ketone
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