Nucleophilic addition of o-tolyllithium compounds to di-tert-butyl ketone. Thermal and organolithium-catalyzed isomerization of o-tolyldi-tert-butylcarbinol rotamers

1977 ◽  
Vol 42 (21) ◽  
pp. 3394-3399 ◽  
Author(s):  
John S. Lomas ◽  
Pham Kim Luong ◽  
Jacques Emile Dubois
Keyword(s):  
Nucleophilic Addition ◽  
Tert Butyl ◽  
Butyl Ketone

Photochemistry of di-tert-butyl ketone and structural effects on the rate and efficiency of intersystem crossing of aliphatic ketones

1970 ◽  
Vol 92 (23) ◽  
pp. 6974-6976 ◽  
Author(s):  
Nien-Chu. Yang ◽  
Eugene D. Feit ◽  
Man Him. Hui ◽  
Nicholas J. Turro ◽  
J. Christopher. Dalton
Keyword(s):  
Intersystem Crossing ◽  
Structural Effects ◽  
Tert Butyl ◽  
Aliphatic Ketones ◽  
Butyl Ketone

ChemInform Abstract: Nucleophilic Addition of Phosphine to 1-(tert-Butyl)-4-vinylbenzene: A Short-Cut to Bulky Secondary and Tertiary Phosphines and Their Chalcogenides.

ChemInform ◽  
2009 ◽  
Vol 40 (13) ◽  
Author(s):  
Nina K. Gusarova ◽  
Svetlana F. Malysheva ◽  
Vladimir A. Kuimov ◽  
Nataliya A. Belogorlova ◽  
Valentina L. Mikhailenko ◽  
...  
Keyword(s):  
Nucleophilic Addition ◽  
Tert Butyl ◽  
Tertiary Phosphines

Stereochemistry of nucleophilic addition reactions. Addition of thiophenol and of hydrogen chloride to 4-tert-butyl-1-cyanocyclohexene

1972 ◽  
Vol 37 (23) ◽  
pp. 3577-3584 ◽  
Author(s):  
R. A. Abramovitch ◽  
Milorad M. Rogic ◽  
Sandra S. Singer ◽  
N. Venkateswaran
Keyword(s):  
Hydrogen Chloride ◽  
Nucleophilic Addition ◽  
Addition Reactions ◽  
Tert Butyl

A Photoelectron Investigation of Acyl Silanes: The Photoelectron Spectra of Trimethylsilyl Phenyl Ketone and Phenyl tert-Butyl Ketone

1975 ◽  
Vol 53 (16) ◽  
pp. 2446-2449 ◽  
Author(s):  
R. S. Brown
Keyword(s):  
Energy Level ◽  
Low Energy ◽  
Ionization Potentials ◽  
Photoelectron Spectra ◽  
Energy Level Diagram ◽  
Tert Butyl ◽  
Partial Energy ◽  
Phenyl Ketone ◽  
Butyl Ketone

The photoelectron spectra of trimethylsilyl phenyl ketone and phenyl tert-butyl ketone are presented and analyzed in terms of their constituent orbitals. A hyperconjugative interpretation for the low energy ionization potentials of the acyl silanes is postulated. A combination of p.e. spectroscopy and u.v. data are used to infer the level of the LUMO in these systems and to construct a partial energy level diagram.

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