Ions and Aggregates of Tetra-n-butylammonium Picrate in Nonaqueous Solvents at 25 °C: A Solvent Extraction Study
Keyword(s):
The values of ΔG0 at 25 °C were determined for the ionization, dimerization, and trimerization of tetra-n-butylammonium picrate (1) in benzene, chlorobenzene, and o-dichlorobenzene by a solvent extraction method. Corrections were applied for the presence of hydrates in the organic phase, in order to report ΔG0 values for the anhydrous solvents. In chlorobenzene, hexamers of 1 were also indicated in measurable concentrations. The various values of ΔG0 are related in a simple way to the bulk dielectric constant of the solvent.
Keyword(s):
2004 ◽
Vol 374
(1-2)
◽
pp. 431-433
◽
Keyword(s):
1972 ◽
Vol 20
(7)
◽
pp. 1412-1416
◽
2018 ◽
Vol 12
(2)
◽
pp. 173-187
◽
2021 ◽
Vol 25
(8)
◽
pp. 1461-1463