Reaction of iron carbonyls with amides and thionamides

1968 ◽  
Vol 46 (19) ◽  
pp. 3112-3115 ◽  
Author(s):  
Howard Alper ◽  
John T. Edward
Keyword(s):  
Iron Pentacarbonyl ◽  
Butyl Ether ◽  
Iron Carbonyls

Iron pentacarbonyl in boiling butyl ether converts primary amides or thionamides to nitriles, and benzanilide or thionbenzanilide to N-benzylideneaniline. Diiron nonacarbonyl reacts with p-methoxy-thionbenzamide to form a complex C22H16N2S2O8Fe2; a possible structure is proposed.

scholarly journals On a new Iron carbonyl, and on the action of light and of heat on the Iron carbonyls

1907 ◽  
Vol 79 (527) ◽  
pp. 66-80 ◽  
Keyword(s):  
Liquid Iron ◽  
Carbonyl Iron ◽  
Chemical Properties ◽  
Iron Pentacarbonyl ◽  
Iron Carbonyl ◽  
Physical And Chemical Properties ◽  
Solid Compound ◽  
Iron Carbonyls ◽  
Physical And Chemical ◽  
And Chemical Properties

This paper contains an account of the results of the continuation of the experiments on the action of light on the liquid iron carbonyl (iron penta-carbonyl) and the action of heat on the resulting solid compound, diferro-nonacarbonyl, Fe 2 (CO) 9 , which were described in a paper on “The Physical and Chemical Properties of Iron Carbonyl,” communicated to the Society in 1905. The experiments on the action of light on iron pentacarbonyl under varied conditions have resulted in new and interesting observations, and approximate measurements of the velocity of the reaction induced by light have been made and compared with that of other reactions induced by light.

Reactions of iron pentacarbonyl with compounds containing the N—O linkage

1970 ◽  
Vol 48 (10) ◽  
pp. 1543-1549 ◽  
Author(s):  
Howard Alper ◽  
J. T. Edward
Keyword(s):  
Iron Pentacarbonyl ◽  
Butyl Ether ◽  
Amine Oxides ◽  
Amino Compounds

Amine oxides, azoxybenzenes, and nitrones are deoxygenated in good yields by iron pentacarbonyl in hot butyl ether. Substituted nitro- and nitrosobenzenes are reduced under these conditions to azo and/or amino compounds, depending on the nature and location of the substituents; some evidence for nitrene or nitrene-like intermediates in these reactions is presented.

scholarly journals Non-volatile iron carbonyls as versatile precursors for the synthesis of iron-containing nanoparticles

Nanoscale ◽  
2017 ◽  
Vol 9 (20) ◽  
pp. 6632-6637 ◽  
Author(s):  
John Watt ◽  
Grant C. Bleier ◽  
Mariah J. Austin ◽  
Sergei A. Ivanov ◽  
Dale L. Huber
Keyword(s):  
Iron Pentacarbonyl ◽  
Iron Carbonyls ◽  
Alkyl Amines ◽  
Triiron Dodecacarbonyl ◽  
Low Toxicity

Though a largely insoluble solid, when gently heated with alkyl amines, triiron dodecacarbonyl readily converts to a highly soluble, non-volatile, low-toxicity precursor for the synthesis of iron-containing nanoparticles. We show that this precursor is a convenient replacement for the volatile and highly toxic iron pentacarbonyl.

Cyclobutadiene–metal complexes. X. Reactions of tetramethylcyclobutadienenickel chloride with iron carbonyls

1967 ◽  
Vol 45 (18) ◽  
pp. 2011-2016 ◽  
Author(s):  
R. Bruce ◽  
K. Moseley ◽  
P. M. Maitlis
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Metal Complexes ◽  
Infrared Spectra ◽  
Iron Pentacarbonyl ◽  
Iron Carbonyls ◽  
Triiron Dodecacarbonyl ◽  
Nuclear Magnetic

Tetramethylcyclobutadieneiron tricarbonyl has been obtained in 25–37% yield from the reaction of triiron dodecacarbonyl with either 3,4-dichlorotetramethylcyclobutene or tetramethylcyclobutadienenickel chloride dimer. The latter reaction also gave small amounts of another complex, Me8C8NiFe(CO)3. The reaction of [Me4C4NiCl2]2 with iron pentacarbonyl gave Me4C4Fe(CO)3 together with two other complexes. The structures of these new complexes are discussed in the light of their nuclear magnetic resonance, mass, and infrared spectra.

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