VISIBLE AND ULTRAVIOLET ABSORPTION SPECTRA OF RHODIUM(III) IN FUSED ALKALI CHLORIDES AND NITRATES

1966 ◽  
Vol 44 (4) ◽  
pp. 447-450 ◽  
Author(s):  
Fredrick B. Ogilvie ◽  
Owen G. Holmes
Keyword(s):  
Absorption Spectra ◽  
Ultraviolet Absorption ◽  
Spectral Changes ◽  
Alkali Chlorides

The spectrum of RhCl3 in fused LiCl–KCl at 440 °C is sufficiently different from that of RhCl63− to suggest the existence of some other species such as dimeric or polymeric bridge-complexes, or, less likely, tetrahedral RhCl4−. The spectra of RhCl3 and K3Rh(NO2)6 in fused NaNO3–KNO3 at 300 °C indicate the occurrence of nitro coordination in both systems, probably completely in the latter case, but in competition with chloro coordination in the former. Addition of KCl to a solution of RhCl3 in NaNO3–KNO3 causes spectral changes which suggest that RhCl63− is the principal rhodium species present.

LIGHT ABSORPTION STUDIES: PART XVII. THE ULTRAVIOLET ABSORPTION SPECTRA OF CHLOROBENZENES

1960 ◽  
Vol 38 (7) ◽  
pp. 1104-1112 ◽  
Author(s):  
W. F. Forbes
Keyword(s):  
Absorption Spectra ◽  
Chlorine Atom ◽  
Light Absorption ◽  
Fluorine Atom ◽  
Ultraviolet Absorption ◽  
Electronic Interaction ◽  
Mesomeric Effect ◽  
Spectral Changes ◽  
Absorption Studies ◽  
Solute Interactions

The ultraviolet absorption spectra of a series of chlorobenzenes are determined. The spectral data suggest that the apparent mesomeric effect of the chlorine atom is greater than that of the fluorine atom, that solvent–solute interactions are generally less important in chlorobenzenes than in fluorobenzenes, and that, as expected, the effective interference radius of the chlorine atom is large. Moreover, spectral changes in o-substituted chlorobenzenes are consistent with the assumption that maximum electronic interaction requires the chlorine atom to be in the same plane as the benzene ring. The conformations of o-chloroacetophenone and o-chlorophenol are briefly discussed.

The Ultraviolet Absorption Spectra of the Acridone Alkaloids. I. Compounds containing the Acridone Nucleus

1950 ◽  
Vol 3 (4) ◽  
pp. 593 ◽  
Author(s):  
RD Brown ◽  
FN Lahey
Keyword(s):  
Electron Density ◽  
Absorption Spectra ◽  
Ultraviolet Absorption ◽  
Absorption Bands ◽  
Ultraviolet Spectra ◽  
Spectral Changes ◽  
Acridone Alkaloids

The ultraviolet spectra of the acridone alkaloids and some derivatives have been studied. The various bands in the spectra of these compounds are interpreted by starting with theoretical treatments of the spectrum of anthracene and tracing spectral changes through acridine and phenazine to acridone. An interesting relation between the π-electron density of a given position in the acridone ring and the shift in wavelength of absorption bands due to an alkoxyl derivative is noted and the spectra of the alkaloids are shown to comply with this relationship. Compounds containing a 4-hydroxy-10-methylacridone structure are found to have unusual spectra and a possible explanation of this is proposed.

FAR ULTRAVIOLET ABSORPTION SPECTRA OF N3AND N2+GENERATED BY ELECTRONS IMPACTING GASEOUS N2

2013 ◽  
Vol 779 (1) ◽  
pp. 40 ◽  
Author(s):  
Yu-Jong Wu ◽  
Hui-Fen Chen ◽  
Shiang-Jiun Chuang ◽  
Tzu-Ping Huang
Keyword(s):  
Absorption Spectra ◽  
Ultraviolet Absorption ◽  
Far Ultraviolet

scholarly journals ULTRAVIOLET ABSORPTION SPECTRA AT REDUCED TEMPERATURES

1950 ◽  
Vol 187 (1) ◽  
pp. 299-312
Author(s):  
R.L. Sinsheimer ◽  
J.F. Scott ◽  
J.R. Loofbourow
Keyword(s):  
Absorption Spectra ◽  
Ultraviolet Absorption

ULTRAVIOLET ABSORPTION SPECTRA AND ACIDITIES OF ISOMERIC THIATRIAZOLE AND TETRAZOLE DERIVATIVES

1959 ◽  
Vol 37 (3) ◽  
pp. 563-574 ◽  
Author(s):  
Eugene Lieber ◽  
J. Ramachandran ◽  
C. N. R. Rao ◽  
C. N. Pillai
Keyword(s):  
Absorption Spectra ◽  
Absorption Maximum ◽  
Dipole Moments ◽  
Ring System ◽  
Ultraviolet Absorption ◽  
Characteristic Absorption ◽  
Tetrazole Derivatives

The ultraviolet absorption spectra of 5-(substituted)amino-1,2,3,4-thiatriazoles and the corresponding isomeric 1-substituted-tetrazoline-5-thiones have been studied. The spectra and the dipole moments of the 5-(substituted)amino-1,2,3,4-thiatriazoles eliminate the possibility of meso-ionic structures for these compounds. The dipole moments of 5-amino-, 5-methylamino-, and 5-dimethylamino-1,2,3,4-thiatriazole were all high but approximately of the same value (5.77 to 5.84 D). This suggests that the amino thiatriazoles are best represented by conventional covalent structures with significant ionic resonance contributions. The thiatriazole ring system exhibits a characteristic absorption maximum at 250–255 mμ and an electron-withdrawing effect approximately equal to the tetrazolyl ring system. The tetrazolinethionolyl ring system is similarly electron-withdrawing. The relative acidities of the 1-substituted-tetrazoline-5-thiones and the 5-alkylmercaptotetrazoles have also been studied and the results support the observations made on the basis of their ultraviolet absorption spectra.

Ultraviolet absorption spectra of monomer and dimer of benzoic acid

1962 ◽  
Vol 8 (1-6) ◽  
pp. 257-275 ◽  
Author(s):  
Haruo Hosoya ◽  
Jiro Tanaka ◽  
Saburo Nagakura
Keyword(s):  
Benzoic Acid ◽  
Absorption Spectra ◽  
Ultraviolet Absorption
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