Oxidation States of Manganese Hematoporphyrin IX in Aqueous Solution*

Biochemistry ◽  
1963 ◽  
Vol 2 (2) ◽  
pp. 361-371 ◽  
Author(s):  
Paul A. Loach ◽  
Melvin Calvin
Nature ◽  
1964 ◽  
Vol 202 (4930) ◽  
pp. 343-345 ◽  
Author(s):  
PAUL A. LOACH ◽  
MELVIN CALVIN

1963 ◽  
Vol 41 (1) ◽  
pp. 108-111 ◽  
Author(s):  
Ruth M. Bennett ◽  
Owen G. Holmes

When dissolved in fused alkali nitrate, manganese (II) is oxidized to MnO2. In the same solvent MnO4− decomposes to MnO2. Peroxide ion arrests the decomposition at MnO42−, while the presence of hydroxide ion results in the formation of MnO43−. The spectra of MnO42− and MnO43− in molten nitrate show great similarity to their spectra in alkaline aqueous solution.


1953 ◽  
Vol 75 (22) ◽  
pp. 5652-5654 ◽  
Author(s):  
Loren G. Hepler ◽  
Z Z. Hugus ◽  
Wendell M. Latimer

1988 ◽  
Vol 41 (9) ◽  
pp. 1433 ◽  
Author(s):  
TA Odonnell

Recently observed spectra of solvated d- and f-transition element cations in superacidic media, together with spectra of aqua cations in acidic aqueous solution, are used to propose that cationic speciation is much more general in acidic solvents and melts than is usually accepted. It will be shown that cations in unusually low oxidation states are stabilized in highly acidic media, and that these cations disproportionate as the acidity of the medium is decreased and that in general these latter phenomena are independent of the chemical nature or the temperature domain of the medium.


ChemInform ◽  
1988 ◽  
Vol 19 (33) ◽  
Author(s):  
U. W. SCHERER ◽  
J. V. KRATZ ◽  
M. SCHAEDEL ◽  
W. BRUECHLE ◽  
K. E. GREGORICH ◽  
...  

1949 ◽  
Vol 71 (2) ◽  
pp. 687-693 ◽  
Author(s):  
J. C. Hindman ◽  
L. B. Magnusson ◽  
T. J. LaChapelle

1988 ◽  
Vol 146 (2) ◽  
pp. 249-254 ◽  
Author(s):  
U.W. Scherer ◽  
J.V. Kratz ◽  
M. Schädel ◽  
W. Brüchle ◽  
K.E. Gregorich ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document