INFRARED SPECTRA OF XANTHATE COMPOUNDS: III. ORGANIC SOLVENT EFFECT ON THE C=S FREQUENCY

1961 ◽  
Vol 39 (9) ◽  
pp. 1783-1786 ◽  
Author(s):  
L. H. Little ◽  
G. W. Poling ◽  
J. Leja

The previously made absorption-band assignment (1) for the C=S stretching mode in xanthate-type compounds, 1020–1070 cm−1, has been confirmed by the characteristic behavior of the C=S dipole in a range of different solvents (Bellamy and Rogasch (2)).

1959 ◽  
Vol 1 (3) ◽  
pp. 19-22 ◽  
Author(s):  
M. Horák ◽  
J. Jonáš ◽  
J. Plíva

1970 ◽  
Vol 13 (4) ◽  
pp. 1332-1334
Author(s):  
M. A. Orel ◽  
I. V. Kagarlitskaya ◽  
I. V. Lapatukhin ◽  
R. A. Kabirova

1997 ◽  
Vol 46 (9) ◽  
pp. 695-702 ◽  
Author(s):  
Toshio OGAWA ◽  
Kenji HAYASHI ◽  
Satoshi OSAWA ◽  
Tetsuya KOYAMA

1956 ◽  
Vol 34 (6) ◽  
pp. 798-808 ◽  
Author(s):  
Paul A. Giguère ◽  
K. B. Harvey

The infrared spectra (from 2 to 30 μ) of thin films of H2O and D2O were measured at various temperatures between 20 ° and −180 °C. A strong absorption band due to the librational mode of the water molecule has its maximum around 710 cm.−1 in the liquid. In ice it is shifted to 800 cm.−1 at −15 °C. and 850 cm.−1 at −170 °C. The corresponding D2O bands show the normal isotope shift. Thin films of water pressed between silver chloride plates could not be crystallized even at liquid air temperature as confirmed by their spectra, which were almost identical with those of the liquid.


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