scholarly journals COEXISTENCE PHENOMENA IN THE CRITICAL REGION: I. THE GRAVITY EFFECT IN ETHANE FROM LIGHT SCATTERING

1952 ◽  
Vol 30 (7) ◽  
pp. 550-561 ◽  
Author(s):  
F. E. Murray ◽  
S. G. Mason

A method of measuring density gradients caused by gravitational compression in gases near the critical region is described. Relative light scattering coefficients of ethane in bombs 40 cm. long increase, remain constant, or decrease in the downward direction, depending upon the mean filling density. These observations have been correlated with the variation of scattering coefficient with density, and show that appreciable density gradients exist. These observations are confirmed by parallel studies of condensation, and serve to explain the flat portion of the liquid–vapor coexistence curve found with a carefully purified system.

1950 ◽  
Vol 18 (5) ◽  
pp. 650-654 ◽  
Author(s):  
H. A. Cataldi ◽  
H. G. Drickamer

1958 ◽  
Vol 36 (3) ◽  
pp. 415-420 ◽  
Author(s):  
F. E. Murray ◽  
S. G. Mason

Transmittance measurements were used to investigate vertical concentration gradients, at temperatures slightly above the critical, in a binary liquid system. The gradients, which are predicted theoretically, did not begin to form during time intervals of several hours. It was found that a theoretical relation between transmittance and concentration gradient did not apply, even qualitatively, to the results obtained. The significance of these observations is discussed.


1977 ◽  
Vol 55 (24) ◽  
pp. 4243-4256 ◽  
Author(s):  
A. Okagawa ◽  
S. G. Mason

Transients in angular light scattering and turbidity of dilute suspensions of nearly monodisperse spheroidal particles undergoing simple shear flow have been investigated by combining Rayleigh–Debye light scattering theory for single dielectric particles with fluid mechanical theory for the orientation distributions of particle assemblies in shear flow. Applying shear to an initially isotropic suspension causes the orientation distributions and thus the angular scattering coefficients to oscillate. Various geometrical arrangements are considered with a view to selecting those that will maximize such rheo-optical effects.By calculating the optical scattering cross section of a single particle, the turbidity of a suspension is obtained; like the scattering coefficient, it undergoes oscillations that are damped by (1) the inevitable spread in particle shape and volume in real systems, (2) shear-induced particle interactions, and (3) rotary Brownian motion. The rates of damping, expressed as relaxation times, are considered for the three mechanisms acting alone or in concert.Preliminary measurements of the turbidity of dilute suspensions of hardened human red blood cells confirm this general pattern of behavior. Apart from their intrinsic interest, such rheo-optical effects can be used to determine a number of useful properties of dispersions.


1968 ◽  
Vol 46 (24) ◽  
pp. 2843-2845 ◽  
Author(s):  
Allan Griffin

If the temperature in an insulating crystal decreases in the z-direction, there are more phonons with momentum qz > 0 than with qz < 0. The resulting difference between the Stokes and anti-Stokes Brillouin intensities is proportional to the mean free path of the phonon involved and to the temperature gradient. The effect should be observable by either neutron or photon scattering.


2001 ◽  
Vol 55 (10) ◽  
pp. 1368-1374 ◽  
Author(s):  
Rinaldo Cubeddu ◽  
Cosimo D'Andrea ◽  
Antonio Pifferi ◽  
Paola Taroni ◽  
Alessandro Torricelli ◽  
...  

Time-resolved reflectance has been used for the nondestructive measurement of optical properties in apples. The technique is based on the detection of the temporal dispersion of a short laser pulse injected into the probed medium. The time distribution of re-emitted photons interpreted with a solution of the diffusion equation yields the mean values of the absorption and reduced scattering coefficients of the medium. The proposed technique proved useful for the measurement of the absorption and scattering spectra of different varieties of apples, revealing the spectral shape of chlorophyll. No major variations were observed in the experimental data when the fruit was peeled, showing that the optical properties measured were those of the pulp. With this technique the change in chlorophyll absorption during storage and ripening could be followed. Finally, a compact prototype working at few selected wavelengths was designed and constructed, demonstrating potentialities of the technique for industrial applications.


2017 ◽  
Vol 43 (4) ◽  
pp. 2154
Author(s):  
E. M. Scordilis

Forty-five preshock sequences preceding corresponding strong (M≥6.4) mainshocks which occurred recently (since 1980) in a variety of seismotectonic regimes (W. Mediterranean, Aegean, Anatolia, California, Japan, Central Asia, South America) have been examined to identify new predictive properties. It has been observed that the mean origin time, , and the mean magnitude, of the accelerating preshocks of each sequence are correlated with the origin time, tc, and the magnitude, M, of the mainshock, respectively. The following relations have been derived: where sa (in Joule ½ /yr.104 Km2 ) is the Benioff strain rate in each preshock (critical) region and σ is the corresponding standard deviation. The possibility for using these relations as constraints in attempts for intermediate term earthquake prediction is discussed.


1977 ◽  
Vol 18 (79) ◽  
pp. 195-215 ◽  
Author(s):  
H. Jay Zwally

Abstract Radiative transfer theory is formulated to permit a meaningful definition of emissivity for bulk emitting media such as snow. The emissivity in the Rayleigh-Jeans approximation is then the microwave brightness temperature T B divided by an effective physical temperature 〈T〉. The 〈T〉 is an average of the physical temperature, T(z), weighted by a radiative transfer function ƒ(z). Similarly, where e(z) is the local emittance. An approximate ƒ(z) is used to determine analytically the effects of various absorption coefficients, of scattering coefficients that vary with depth, and of the seasonal variation of T(z). It is shown that a mean emissivity, which is equal to the mean annual T B divided by the mean annual surface temperature T m, is a useful quantity for comparing theory and observations. Snow-crystal size measurements, r(z), at seven locations in Greenland and Antarctica are used to determine the Mie/Rayleigh scattering coefficient γs (z and to calculate the mean emissivities. The observed mean emissivities are determined by a which is the average of 12 monthly Nimbus-5 (1.55 cm) microwave observations, and the Tm measured at the same locations. The calculated emissivities are about one-half of the observed values. The assumption that each snow crystal is an independent and equally effective scatterer, and the use of an approximation to ƒ(z), tend to over-estimate the effect of scattering. Therefore, a parameter multiplying γs (z) is used. The emissivities calculated with a single value of this empirical parameter for all seven locations agree well with the observed emissivities, showing that the microwave emissivity variations of dry polar urn can be characterised as a function of the crystal sizes. One optical depth corresponds to a typical fini depth of 5 m, but significant radiation emanates from up to 30 m. Since r(z) depends on the snow accumulation rate A and T m. the sensitivity of the emissivity to changes in T m or A are estimated using this semi-empirical theory. The results show that a one degree change or uncertainty in Tm is approximately equivalent to a 10% change in A, and that such a change will affect the emissivity by 0.003 to 0.014 or the T B by about 0.6 K to 3 K, depending on the location.


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