THE FLOW OF FLUIDS THROUGH ACTIVATED CARBON RODS.

1952 ◽  
Vol 30 (4) ◽  
pp. 348-371 ◽  
Author(s):  
E. A. Flood ◽  
R. H. Tomlinson ◽  
A. E. Leger

The flow rates of the vapors of benzene, ethyl chloride, diethyl ether, methanol, and water through activated carbon rods have been found to exceed, considerably, flow rates calculated by classical equations. The excess flow rates show maxima in widely different relative pressure regions and are ascribed to flow of adsorbed material. An empirical equation is presented which correlates the observed flow rates with relevant adsorption isotherms. Classical equations of flow through elliptical and rectangular pipes are discussed with reference to flow through fine-grained porous materials. It is shown that equations of the Adzumi type are roughly valid as applied to fine-grained porous bodies, but that without a knowledge of the frequency distributions of pore sizes and shapes, flow data cannot be related to pore dimensions in any literal sense. End effects are discussed.

1952 ◽  
Vol 30 (4) ◽  
pp. 372-385 ◽  
Author(s):  
E. A. Flood ◽  
R. H. Tomlinson ◽  
A. E. Leger

The flow rates of adsorbable gases through zinc chloride activated carbon rods are considerably greater than might be expected from classical considerations. From data independent of flow measurements, the pore-size frequency distributions of the activated carbon are deduced and a model macropore system presented. It is shown that flow rates of nonadsorbable gases are consistent with a mean macropore diameter of about 3 × 10−5 cm., as well as being consistent with what can be inferred concerning such structures. The macropore system is regarded as an interstitial structure and is described as a random assembly of "bottle necks" joining relatively large void spaces. The assembly is described by means of two constant parameters and one stochastic variable. The mean micro-pore diameter of zinc chloride activated carbons is generally regarded as being of the order of 2 × 10−7 cm. or less. It is shown that no ordinary type of effusive or diffusive flow through pores of the order of 2 × 10−7 cm. can be appreciable compared with the flow through the macropore system, unless surface forces increase flow rates by large factors. In the case of strongly adsorbed gases the anomalous flow rates are ascribed to a flow through the micropore system and hence it is inferred that surface forces introduce large factors tending to increase flow rates in these very small pores.


Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Francesca Giacobbo ◽  
Mauro Giudici ◽  
Mirko Da Ros

Conservative transport experiments with layered porous materials (coarse-grained vs. fine-grained) were performed through experimental cylindrical columns to assess the possible occurrence of interface processes at the discontinuity between media with different hydrodynamic and hydrodispersive properties, as proposed by some authors in the past based on modelling and experimental results. The outcomes of the present work show that, under certain conditions, the breakthrough curves (BTCs) obtained for flow through the coarse-grained and then through the fine-grained media (CtF) or vice versa (FtC) can differ. More specifically, an asymmetric behaviour is observed for cases when the ratio between the column and grain diameters is small. Moreover, the discrepancies between CtF and FtC BTCs are enhanced for low flow rates and low quantity of injected solute.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3811
Author(s):  
Zhongbao Liu ◽  
Jiayang Gao ◽  
Xin Qi ◽  
Zhi Zhao ◽  
Han Sun

In this study, the hydrothermal method was used to synthesize MIL-101(Cr), and activated carbon (AC) with different content was incorporated in to MIL-101(Cr), thereby obtaining AC-MIL-101(Cr) composite material with a huge specific surface area. The physical properties of MIL-101(Cr) and AC-MIL-101(Cr) were characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), nitrogen adsorption and desorption and specific surface area testing, and ethanol vapor adsorption performance testing. The results show that with the increase of activated carbon content, the thermal stability of AC-MIL-101(Cr) is improved. Compared with the pure sample, the BET specific surface area and pore volume of AC-MIL-101(Cr) have increased; In the relative pressure range of 0–0.4, the saturated adsorption capacity of AC-MIL-101(Cr) to ethanol vapor decreases slightly. It is lower than MIL-101(Cr), but its adsorption rate is improved. Therefore, AC-MIL-101(Cr)/ethanol vapor has a good application prospect in adsorption refrigeration systems. The exploration of AC-MIL-101(Cr) composite materials in this paper provides a reference for the future application of carbon-based/MOFS composite adsorbent/ethanol vapor working fluid in adsorption refrigeration.


Energies ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2796
Author(s):  
Andrzej Osuch ◽  
Ewa Osuch ◽  
Stanisław Podsiadłowski ◽  
Piotr Rybacki

In the introduction to this paper, the characteristics of Góreckie lake and the construction and operation of the wind-driven pulverizing aerator are presented. The purpose of this manuscript is to determine the efficiency of the pulverizing aerator unit in the windy conditions of Góreckie Lake. The efficiency of the pulverization aerator depends on the wind conditions at the lake. It was necessary to conduct thorough research to determine the efficiency of water flow through the pulverization segment (water pump). It was necessary to determine the rotational speed of the paddle wheel, which depended on the average wind speed. Throughout the research period, measurements of hourly average wind speed were carried out. It was possible to determine the efficiency of the machine by developing a dedicated mathematical model. The latest method was used in the research, consisting of determining the theoretical volumetric flow rates of water in the pulverizing aerator unit, based on average hourly wind speeds. Pulverization efficiency under the conditions of Góreckie Lake was determined based on 6600 average wind speeds for spring, summer and autumn, 2018. Based on the model, the theoretical efficiency of the machine was calculated, which, under the conditions of Góreckie Lake, amounted to 75,000 m3 per year.


Computation ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 27
Author(s):  
Nattakarn Numpanviwat ◽  
Pearanat Chuchard

The semi-analytical solution for transient electroosmotic flow through elliptic cylindrical microchannels is derived from the Navier-Stokes equations using the Laplace transform. The electroosmotic force expressed by the linearized Poisson-Boltzmann equation is considered the external force in the Navier-Stokes equations. The velocity field solution is obtained in the form of the Mathieu and modified Mathieu functions and it is capable of describing the flow behavior in the system when the boundary condition is either constant or varied. The fluid velocity is calculated numerically using the inverse Laplace transform in order to describe the transient behavior. Moreover, the flow rates and the relative errors on the flow rates are presented to investigate the effect of eccentricity of the elliptic cross-section. The investigation shows that, when the area of the channel cross-sections is fixed, the relative errors are less than 1% if the eccentricity is not greater than 0.5. As a result, an elliptic channel with the eccentricity not greater than 0.5 can be assumed to be circular when the solution is written in the form of trigonometric functions in order to avoid the difficulty in computing the Mathieu and modified Mathieu functions.


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3481
Author(s):  
Joanna Lach ◽  
Agnieszka Ociepa-Kubicka ◽  
Maciej Mrowiec

The aim of the work was to evaluate the possibility of using commercial and modified activated carbons for the removal of oxytetracycline from aqueous solutions. The kinetics and statics of adsorption as well as the effect of the activated carbon dose and solution pH on the efficiency of the oxytetracycline adsorption were analyzed. Based on the study of oxytetracycline adsorption isotherms, the activated carbons were ranked in the following order: F-300 > WG-12 > Picabiol > ROW08 > WACC 8 × 30 > F-100 > WAZ 0.6–2.4. The most effective activated carbons were characterized by large specific surfaces. The best matching results were obtained for: Redlich–Peterson, Thot and Jovanovic models, and lower for the most frequently used Freundlich and Langmuir models. The adsorption proceeded better from solutions with pH = 6 than with pH = 3 and 10. Two ways of modifying activated carbon were also assessed. A proprietary method of activated carbon modification was proposed. It uses the heating of activated carbon as a result of current flow through its bed. Both carbons modified at 400 °C in the rotary kiln and on the proprietary SEOW (Joule-heat) modification stand enabled to obtain adsorbents with higher and comparable monolayer capacities. The advantage of the proposed modification method is low electricity consumption.


2001 ◽  
Author(s):  
David P. Haack ◽  
Kenneth R. Butcher ◽  
T. Kim ◽  
T. J. Lu

Abstract An overview of open cell metal foam materials with application to advanced heat exchange devices is presented. The metal foam materials considered consist of interconnected cells in a random orientation. Metal foam materials, manufacture and fabrication into complex heat exchange components are described. Experiments with flat foam panels brazed to copper sheets shows increasing heat removal effectiveness with decreasing product pore size at equivalent coolant flow rates. However, the high-pressure drop associated with flow through small pore-size material makes the use of larger pore size material more attractive.


Author(s):  
A.C. Fox ◽  
T.W. Clyne

Abstract A simple test procedure, based on steady state flow through a membrane, has been developed for measurement of the gas permeability of specimens over a range of temperature. The reliability of this equipment has been verified by testing solid disks containing single perforations and comparing the measured flow rates with those expected on the basis of laminar flow. Coatings of yttria-stabilised zirconia have been produced by plasma spraying in vacuum and in air. The specific permeability of these coatings has been measured at temperatures ranging up to 600°C, using hydrogen gas. It has been found that permeability is increased for coatings produced with longer stand-off distances and at higher pressures. Porosity levels have been measured using densitometry and microstructural features have been examined using SEM. A model has been developed for prediction of the permeability from such microstructural features, based on percolation theory. Agreement between predicted and measured permeabilities is good, although it is clear that more comprehensive data are needed in order to validate the model systematically.


Author(s):  
Massimo Masi ◽  
Andrea Lazzaretto

The flow path close to the suction side of fan rotor blades mostly affects the overall drag of the blading. The blade lift is affected as well because of the separation of the low energy boundary layer that drives the blade into stall at low fan flow rates. Forward sweep allows to position the airfoil sections of blades featuring a positive circulation gradient along the span so that they “accompany” the near-wall flow trajectories at the blade suction side. So, rotor efficiency and stall margin of the fan can be improved. On the other hand, blade end effects play a relevant role in high hub-to-tip and low aspect ratio rotors and may compromise the effectiveness of forward sweep. Nevertheless, some authors in the literature stated the beneficial contribution of changing the sweep angle at the ends of the blade both at design and off-design conditions. The paper studies the end effects on constant-swirl design rotors by means of CFD simulations focusing on the distribution of blade sweep in the near-tip region. In particular, the performance and efficiency calculated for a forward swept tube-axial fan featuring a hub-to-tip ratio equal to 0.4 are compared with those estimated for the corresponding unswept fan at equal duty point. Several modifications of the sweep distribution in the blade tip region are considered in the swept fan to quantify their effect on performance, efficiency and stall margin. Results show that the addition of up to 6 degrees of local forward sweep at the blade tip to the unswept blading does not affect fan pressure at design operation. On the other hand, this local increase of the sweep angle allows for a very notable increase of the peak pressure and efficiency at flow rates close to stall inception.


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