Scientific genealogies of physical and mechanistic organic chemists

2005 ◽  
Vol 83 (9) ◽  
pp. 1400-1414 ◽  
Author(s):  
John Andraos

Scientific genealogy trees of scientists who contributed to the study of organic reaction mechanisms over the last century are presented. The trees show doctoral and post-doctoral connections among scientists as well as connections between scientific ideas. Contributions made by scientists working in laboratories at Canadian universities and at the National Research Council of Canada are noted throughout. These trees, covering more than two centuries, are of interest to senior scientists and young students of science alike in understanding the evolution of scientific ideas and in career development for aspiring scientists. Key patterns revealed by these trees pertaining to ideas and discoveries made, how they were made, connections between them, and who made them are also discussed.Key words: reaction mechanisms, physical organic chemistry, scientific genealogies.

2005 ◽  
Vol 83 (9) ◽  
pp. 1415-1431 ◽  
Author(s):  
John Andraos

An overview of the discovery of reaction intermediates and associated concepts in physical organic chemistry is presented. Particular attention is paid to chronology of ideas, frequency of occurrence of reaction intermediates in the library of organic reactions used in organic synthesis, and the lexicon of scientific terms used in the language of physical organic chemistry. General logic decision trees are presented for the unique or near unique identification of reaction intermediates based on experimental techniques and common patterns of reactivity documented in the literature over the last century. Contributions made by scientists working in laboratories at Canadian universities and at the National Research Council of Canada are noted throughout.Key words: physical organic chemistry, mechanistic chemistry, reaction intermediates.


Author(s):  
Kevin Lam

Dr. Mark Workentin is a Professor in the Department of Chemistry at Western University. After receiving his PhD at McMaster University and working as a Research Associate at the National Research Council (NRC) in Ottawa, Professor Workentin returned to his undergraduate alma mater to become a faculty member. His research group primarily focuses on studying the physical organic chemistry of materials. Not only has Dr. Workentin produced amazing research, but he has also been awarded for his ability and passion to teach students chemistry. Kevin Lam, a first year representative for WURJHNS, had the opportunity to interview Dr. Workentin to learn more about his research and his experiences at Western.


2005 ◽  
Vol 83 (9) ◽  
pp. 1197-1201
Author(s):  
Thomas T Tidwell

Some of the history of the development of physical organic chemistry in Canada from the 1920s is presented, including many of the individuals involved, and their major areas of interest.Key words: history of physical organic chemistry in Canada, organic reaction mechanisms, free radicals, kinetics.


2007 ◽  
Vol 79 (6) ◽  
pp. 1111-1123 ◽  
Author(s):  
Luis García-Río ◽  
J. Ramon Leis ◽  
Juan Carlos Mejuto ◽  
Moisés Pérez-Lorenzo

Microemulsions are very versatile reaction media which nowadays find many applications, ranging from nanoparticle templating to preparative organic chemistry. The thermodynamically stable and microheterogeneous nature of microemulsions, used as reaction media, induces drastic changes in the reagent concentrations, and this can be specifically used for tuning the reaction rates. In particular, amphiphilic organic molecules can accumulate and orient at the oil-water interface, inducing regiospecificity in organic reactions. In this review, we will show the recent tendencies of the use of microemulsions as organic reaction media.


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