Effect of substrate variability on activated sludge kinetics during the treatment of bleached kraft mill effluent

2007 ◽  
Vol 6 (2) ◽  
pp. 123-129
Author(s):  
Steve S Helle ◽  
Sheldon J.B. Duff
Keyword(s):  
Activated Sludge ◽  
Kraft Mill Effluent ◽  
Kraft Mill

Multi-component kinetics of activated sludge treatment of bleached kraft mill effluent

2004 ◽  
Vol 50 (3) ◽  
pp. 11-20
Author(s):  
S.S. Helle ◽  
S.J.B. Duff
Keyword(s):  
Activated Sludge ◽  
Oxygen Demand ◽  
Fed Batch ◽  
Removal Rates ◽  
Kinetic Measurements ◽  
Sludge Treatment ◽  
Batch Tests ◽  
Degradation Rates ◽  
Kraft Mill Effluent ◽  
Kraft Mill

This study investigated the discrepancies between the BOD removal rates measured during short term assays and those measured during continuous activated sludge treatment of bleached kraft mill effluent (BKME). A combination of batch tests and fed batch tests with oxygen uptake rate (OUR), chemical oxygen demand (COD), biochemical oxygen demand (BOD), and mixed liquor volatile suspended solids (MLVSS) measurements were used to characterize the degradation rates for the activated sludge treatment of BKME and to divide the soluble readily biodegradable substrate into two to five separate fractions based on biodegradation rates. The removal rates varied by over an order of magnitude between the most readily degradable substrates (1 × 10-3 mg COD/mg MLVSS minute), and the more slowly degradable substrates (2 × 10-5 mg COD/mg MLVSS minute). If the readily biodegradable fraction of BKME was modeled as one substrate, initial rate kinetic measurements from batch tests were heavily influenced by the fractions with the greatest degradation rates, while any remaining BOD in the treated effluent was predominantly from the slowly degradable fraction, giving inconsistent results. Taking the multi-component nature of the wastewater into account, batch test results can be used to predict fed-batch and continuous activated sludge reactor performance.

Bioavailability of Pulp and Paper Mill Effluent Phosphorus

1994 ◽  
Vol 29 (5-6) ◽  
pp. 93-103 ◽  
Author(s):  
Maarit Priha
Keyword(s):  
Activated Sludge ◽  
Total Phosphorus ◽  
Paper Mill ◽  
Particulate Phosphorus ◽  
Pulp And Paper Mill ◽  
Paper Mill Effluent ◽  
Dissolved Phosphorus ◽  
Kraft Mill Effluent ◽  
Kraft Mill ◽  
The Stability

The aim of this study was to examine the stability and bioavailability of different phosphorus fractions of pulp and paper mill effluents in order to assess the environmental benefits of reducing their phosphorus discharges. Two types of effluent were studied: activated sludge treated bleached kraft mill effluent and activated sludge treated paper mill effluent. Phosphorus was characterized on the basis of its solubility and chemical reactivity. The stability of particulate phosphorus was studied in long-term (6-8 weeks) degradation tests. The bioavailability of different phosphorus fractions was measured by algal growth potential tests. In bleached kraft mill effluent (BKME) the proportion of dissolved phosphorus in relation to the total phosphorus was on an average 80%, and of this, approximately 80-90% was reactive phosphorus. During a 6-8 week incubation period some 60-70% of the particulate phosphorus in BKME was dissolved as soluble phosphorus, and most of it was of the reactive type. Approximately 90% of the dissolved phosphorus and 45% of the particulate phosphorus in BKME was biologically available phosphorus (BAP). Altogether some 80% of the total phosphorus in activated sludge treated BKME was available for algae either immediately or after inherent degradation. The percentages of dissolved and particulate phosphorus of paper mill effluent (PME) total phosphorus were of the same order of magnitude as those of BKME, but less than 20% of the dissolved phosphorus was of the reactive type. Approximately 50-60% of the particulate phosphorus in PME was dissolved in degradation tests, and 90% of it was biologically available.

Chlorinated Phenolics Removal from Bleached Kraft Mill Wastewater in Three Secondary Treatment Processes

1994 ◽  
Vol 29 (5-6) ◽  
pp. 177-187 ◽  
Author(s):  
E. R. Hall ◽  
W. G. Randle
Keyword(s):  
Activated Sludge ◽  
Treatment Process ◽  
Operating Conditions ◽  
Secondary Treatment ◽  
Threshold Values ◽  
Sludge Treatment ◽  
Treatment Processes ◽  
Kraft Mill Effluent ◽  
Kraft Mill ◽  
Removal Efficiencies

Laboratory-scale activated sludge (AS), facultative stabilization basin (FSB) and aerated stabilization basin (ASB) processes were operated in parallel treating bleached kraft mill effluent under controlled SRT and temperature conditions, to assess the chlorinated phenolics removal efficiencies attainable in each. The structure and extent of chlorination of the chlorophenolic compounds monitored appeared to contribute to the differing removal efficiencies observed. Under most operating conditions, treatment process effluents contained chronically toxic levels of pentachlorophenol-equivalent toxicity (TEQ). A companson of the results obtained from the FSB, ASB and AS processes indicated that, under most operating conditions, chlorophenolics removal in low rate treatment systems is superior to that in a higher rate activated sludge treatment process. However, it was also observed that operation at long SRT and moderate temperature permitted enhanced removal of chlorophenolics and reduced TEQs to less than threshold values, in all three treatment processes.

The Occurrence and Bioavailability of Retene and Resin Acids in Sediments of a Lake Receiving BKME (Bleached Kraft Mill Effluent)

1999 ◽  
Vol 40 (11-12) ◽  
pp. 131-138 ◽  
Author(s):  
H. J. T. Leppänen ◽  
A. O. J. Oikari
Keyword(s):  
Activated Sludge ◽  
Waste Water Treatment ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Resin Acids ◽  
Background Concentration ◽  
Pulp And Paper Mill ◽  
Paper Mill Effluents ◽  
Kraft Mill Effluent ◽  
Kraft Mill

Retene (7-isopropyl-1-methylphenantrene) is an alkyl substituted PAH derived primarily from bacterial aromatization of abietic type resin acids. Retene has been shown to induce cytochrome P450 1A in rainbow trout whereas e.g. dehydroabietic acid does not induce it. We analysed resin acids and retene in sediments from seven sites receiving pulp and paper mill effluents from 4 mills, and from two reference sites. All mills have employed treatment of waste waters by activated sludge. The highest concentration of retene measured in sediment was 1600 μg/g d.w. (11 700 μg/g organic carbon, OC) while the highest concentration of resin acids was 1500 μg/g d.w. (9 300 μg/g OC). Downstream from the point (12 km) of bleached kraft mill effluent discharge, the concentration of retene at the depth of 5-10 cm in sediment was still 16 μg/g d.w. (650 μg/g OC) and the concentration of resin acids 139 μg/g d.w. (1700 μg/g OC). Background concentration for retene on the upstream reference site was below 0.1 μg/g d.w and for resin acids below 70 μg/g d.w. Substantial concentrations of retene (54 μg/g d.w.) and resin acids (1470 μg/g d.w.) were also detected in sedimenting particles collected at the sediment sampling sites. When the concentrations and sedimentation rates before and after the installation of activated sludge systems were compared, the effect of improved waste water treatment on total amount of sedimenting resin acids and retene (μg/m2/day) is clear. To assess the bioavailability of retene we analysed its concentration in the bile of feral fish caught 1-2 km downstream of pulp and paper mill. Data on roach shows that retene in sediments can be bioavailable to fish feeding on benthic food chain.

Responses in a Fathead Minnow (Pimephales promelas) Lifecycle Test and in Wild White Sucker (Catostomus commersoni) Exposed to a Canadian Bleached Kraft Mill Effluent

2010 ◽  
Vol 45 (2) ◽  
pp. 187-200 ◽  
Author(s):  
Joanne L. Parrott ◽  
L. Mark Hewitt ◽  
Tibor G. Kovacs ◽  
Deborah L. MacLatchy ◽  
Pierre H. Martel ◽  
...  
Keyword(s):  
Egg Production ◽  
Fathead Minnow ◽  
Pimephales Promelas ◽  
Fish Reproduction ◽  
White Sucker ◽  
Catostomus Commersoni ◽  
Liver Size ◽  
Paper Mill Effluent ◽  
Kraft Mill Effluent ◽  
Kraft Mill

Abstract To evaluate currently available bioassays for their use in investigating the causes of pulp and paper mill effluent effects on fish reproduction, the responses of wild white sucker (Catostomus commersoni) collected from the receiving environment at the bleached kraft mill at La Tuque, Quebec, were compared with responses of fathead minnow (Pimephales promelas) exposed to effluent in a laboratory lifecycle test. White sucker collected at effluent exposed sites had increased liver size but none of the reproductive effects that had been documented in earlier field studies at this site. Exposure to 1, 3, 10, 30, and 100% bleached kraft mill effluent (BKME) in the lab led to significantly decreased length, but increased weight and liver size in male fathead minnow. Female length was also decreased and liver size was increased at high effluent exposures. Most effluent concentrations (1 to 30%) significantly increased egg production compared with controls. The fathead minnow lifecycle assay mirrored the effects seen in wild fish captured downstream of the BKME discharge. These results will be used to select short-term fish tests for investigating the causes of and solutions to the effects of mill effluents on fish reproduction.

Mutagenicity in Pulp and Paper Mill Effluents and in Recipient

1988 ◽  
Vol 20 (2) ◽  
pp. 143-152 ◽  
Author(s):  
A. Langi ◽  
M. Priha
Keyword(s):  
Activated Sludge ◽  
Mutagenic Activity ◽  
Chinese Hamster Ovary Cells ◽  
Chinese Hamster ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Pulp And Paper Mill ◽  
Sludge Treatment ◽  
Paper Mill Effluents ◽  
Kraft Mill

The mutagenic properties of pulp and paper mill effluents were studied in three mills: bleached kraft mill with aerated lagoon treatment (Mill 1), bleached kraft mill with activated sludge treatment (Mill 2) and mechanical pulp/paper mill (Mill 3). Both treated and untreated effluents, process streams and molecular fractions were tested for mutagenicity (Ames test. Salmonella typhimurium TA100 and SCE sister chromatid exchange test, Chinese hamster ovary cells). To verify the potential environmental effects the mutagenic activity of concentrated recipient lake water (Mill 2) was also studied. The Ames mutagenicity of the bleached kraft mill effluent (BKME) originated from the first chlorination filtrate, SCE mutagenicity also occurred in the alkali extraction stage filtrate (Mill 1). No Ames mutagenicity was detected in the paper mill effluent, but it was SCE mutagenic. Activated sludge treatment of BKME removed both Ames and SCE mutagenicity, but the aerated lagoon treated BKME was still SCE mutagenic. No mutagenic activity was detected in the recipient water concentrates.

Assessment of the Acute Toxicity, Growth Impairment, and Flesh Tainting Potential of a Bleached Kraft Mill Effluent on Rainbow Trout (Salmo gairdneri)

1977 ◽  
Vol 34 (6) ◽  
pp. 869-878 ◽  
Author(s):  
D. M. Whittle ◽  
K. W. Flood
Keyword(s):  
Rainbow Trout ◽  
Acute Toxicity ◽  
Continuous Flow ◽  
Effluent Treatment ◽  
Salmo Gairdneri ◽  
Freshwater Ecosystem ◽  
Juvenile Rainbow Trout ◽  
Effluent Concentration ◽  
Kraft Mill Effluent ◽  
Kraft Mill

Static and continuous-flow bioassays utilizing juvenile rainbow trout (Salmo gairdneri) were conducted on a northern Ontario bleached kraft mill effluent to assess the range of acute toxicity and related sublethal effects. The acute toxicity of the total mill effluent, as determined by static bioassay procedures, ranged from a 96-h LC50 value of 14–49.0% vol/vol. The results of these bioassays depended on testing methodology and effluent treatment systems employed by the mill when samples were collected. Continuous-flow bioassays conducted on the effluent Produced 96-h LC50 values of 21.8 and 24.8% vol/vol. Growth rate of juvenile rainbow trout (1–2 g) held under continuous-flow conditions for 18 days was significantly reduced at 6% vol/vol effluent concentration (P < 0.05). Flavor of yearling rainbow trout [Formula: see text] exposed to 3% effluent for 48 h was significantly impaired (P < 0.05). This effluent concentration, the lowest level impairing flavor represents approximately 0.12 of the 96-h LC50 derived from continuous-flow bioassays. No significant flavor impairment was detected in fish exposed for 144 h to a 2% effluent concentration Flavor impairment at a 3% vol/vol effluent concentration, the most sensitive sublethal response measured in this study, may also be the most critical response when assessing the economic impact of a kraft mill discharge to a freshwater ecosystem.

Decolorization of a kraft mill effluent with fungal mycelium immobilized in calcium alginate gel

1981 ◽  
Vol 3 (12) ◽  
pp. 701-706 ◽  
Author(s):  
D. Livernoche ◽  
L. Jurasek ◽  
M. Desrochers ◽  
I. A. Veliky
Keyword(s):  
Calcium Alginate ◽  
Fungal Mycelium ◽  
Alginate Gel ◽  
Calcium Alginate Gel ◽  
Kraft Mill Effluent ◽  
Kraft Mill
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