Detection of copper precipitates in Cu2O by NMR

1985 ◽  
Vol 63 (3) ◽  
pp. 397-401 ◽  
Author(s):  
D. G. Hughes ◽  
S. Mohanty ◽  
L. Pandey ◽  
F. L. Weichman

Weak 63Cu NMR signals characteristic of metallic copper have been found in three type-C Cu2O crystals, but not in types A and B. This is in accordance with presently accepted models of these materials. The resonances are asymmetric in two of the three crystals. One shows skin-depth effects, implying particle sizes [Formula: see text], the other shows some second-order quadrupole broadening, presumably associated with strains or surface effects. From the areas under the absorption curves, mass concentrations of copper precipitates ranging from 0.023 to 0.034% are deduced. However, the smallest value is found from an asymmetric resonance where significant loss of signal must have occurred. The data are not inconsistent with a concentration of about 0.034% for all three crystals. For type-A and -B material, an upper limit of 3–7 ppm can be placed on the concentration, depending on the assumed contribution of the satellites to the resonance. 63Cu resonances associated with the transitions between Zeeman-split ± 1/2 quadrupole states in Cu2O were troublesome, since they overlapped the metal resonance at many sample orientations. Strong Cu2O signals, observed at one orientation, indicated that part of the crystal must have grown with {111} faces.

1981 ◽  
Vol 59 (5) ◽  
pp. 663-672 ◽  
Author(s):  
K-E. J. Hallin ◽  
J. W. C. Johns ◽  
A. Trombetti

The gas phase spectrum of N2H2 has been investigated in the region of 7.6 μm at a resolution of about 0.06cm−1. Two bands have been identified; one, near 1288 cm−1, is a type C band and must correspond to ν4 (the hitherto unidentified Au torsional mode), and the other, near 1317 cm−1, is a type A–B hybrid and corresponds to ν6 (the Bu bending mode). Analysis of the spectrum is complicated by the simultaneous presence of strong A-type and B-type Coriolis interactions which couple the observed levels.


1964 ◽  
Vol 19 (2) ◽  
pp. 383-389 ◽  
Author(s):  
A. J. Riopelle ◽  
U. Rahm ◽  
N. Itoigawa ◽  
W. A. Draper
Keyword(s):  
Type A ◽  

Twelve rhesus monkeys were trained to discriminate between (a) lateral mirror-image problem, (b) vertical mirror-image problem, (c) problems in which one stimuli was rotated 90°, and (d) nonidentical problems. Type (a) problems were most readily discriminated whereas type (c) problems were least readily discriminated. The other problems were of intermediate difficulty. Stimuli placed one above the other were less discriminable than those placed side by side. No interaction existed between type of stimulus placement and direction of the comparison. The results are explained by the fact that the monkeys tend to inspect the bottom edges of the stimuli, which differ in discriminability as a function of the direction of the mirror-image reflection.


Author(s):  
Yrjö Lauranto

This article examines object case marking in a Finnish verb structure called the Projected Directive Construction, e.g. Liisa pyysi Matti-a lähte-mä-än ‘Liisa asked Matti to leave’ (Liisa.NOMINATIVE asked Matti-PARTITIVE leave-INF-ILLATIVE). The PDC is divided into three subtypes. Type A includes verbs such as pyytää ‘to request’, which take a partitive object regardless of the outcome of the action. Verbs used in type B, such as määrätä ‘to order’, take an accusative object despite the result of the action. Type C comprises verbs such as suostutella ‘to persuade’ taking either a partitive or an accusative object, depending on the outcome of the semiotic causation expressed in the clause. The object case marking in the three subtypes reflects the two-faceted nature of the construction: on the one hand, it is a construction used for reporting of speech, on the other, it is a causative construction. It seems that boundedness – as it has traditionally been defined – does not suffice to describe the alternation of the object case in the PDC.Kokkuvõte. Yrjö Lauranto: Projitseeritud direktiivsed konstruktsioonid ja objekti käände markeerimine soome keeles. Artiklis käsitletakse objekti käänet soome keele projitseeritud direktiivses konstruktsioonis (PDK), nt Liisa pyysi Matti-a lähte-mä-än ‘Liisa palus Matit ära minna’. PDK võib jagada kolme alltüüpi. Tüüp A sisaldab verbe nagu pyytää ‘paluda’, mis nõuavad partitiivobjekti, sõltumata tegevuse tulemusest. Tüüp B verbid nagu määrätä ‘käskida’ nõuavad akusatiivobjekti, sõltumata tegevuse tulemuslikkusest. Tüüpi C kuuluvad verbid nagu suostutella ‘veenda’, mis võivad võtta nii partitiivse kui akusatiivse objekti, sõltuvalt lausega väljendatud semiootilise põhjustatuse tulemusest. Kolme alltüübi käändemarkeering peegeldab konstruktsiooni kahetist olemust: ühelt poolt kasutatakse konstruktsiooni kõne vahendamiseks, teiselt poolt on tegemist kausatiivse konstruktsiooniga. Seega ei piisa PDK objekti käändevahelduse selgitamiseks vaid piiritletuse mõistest.Võtmesõnad: objekti käände markeerimine; piiritletus; akusatiiv; partitiiv; kõne ja mõtete vahendamine; projitseerimine; kausatiivne konstruktsioon; soome keel


2012 ◽  
Vol 50 (No. 10) ◽  
pp. 439-442 ◽  
Author(s):  
H. Kalender ◽  
Ertas HB ◽  
B. Cetinkaya ◽  
A. Muz ◽  
N. Arslan ◽  
...  

In this study, C. perfringens strains isolated from healthy and diseased sheep were analysed by multiplex PCR in order to to detect the presence of the alpha, beta, epsilon, iota and enterotoxin genes. C. perfringens was isolated from 52 of 104 sheep with enterotoxemia signs and from 61 of 194 clinically healthy sheep. Genotyping of 52 strains from diseased sheep indicated that 33 (64%) were type A, 11 (21%) type D and 8 (15%) type C. Of 61 strains from healthy sheep, 58 (95%) were type A and 3 (5%) type D. The other types of C. perfringens were not detected, and none of the isolates contained the enterotoxin gene. This result indicates that the enterotoxin of C. perfringens does not play the important role in the occurence of enterotoxemia in sheep.


2021 ◽  
pp. 175319342098321
Author(s):  
Anyuan Wang ◽  
Jian Ding ◽  
Long Wang ◽  
Tinggang Chu ◽  
Zhipeng Wu ◽  
...  

We present the MRI findings for 39 Wassel Type IV duplicated thumbs in 38 patients. We found that MRI revealed the morphology of the cartilaginous connection between the thumb anlages and the location of the deviation corresponding to the classification of Horii, which allowed precise preoperative planning of corrective osteotomies. All 39 thumbs were available for follow-up after surgical reconstruction at a mean of 29 months (range 25 to 39). Four out of nine Horii Type A cases and all 12 Type B, as well as the six Type C and the six Type D cases, achieved good results according to the Tada scoring system. Five Type A cases achieved fair results with residual stiffness of the interphalangeal joint. No secondary operations were needed. We conclude that MRI proved useful in subclassifying Wassel Type IV duplicated thumbs and may aid in planning the osteotomies needed for their reconstruction. Level of evidence: IV


1984 ◽  
Vol 62 (1) ◽  
pp. 97-106 ◽  
Author(s):  
Jacqueline Kovoor

Although hersiliid spiders do not spin any webs, their silk glands, which belong to six types, are large and complex. Two groups of ampullate glands, one opening on the anterior spinnerets and the other on the median spinnerets, secrete two proteins each. About 180 pyriform glands are clearly bipartite. Over 200 type A aciniform glands opening on the median and posterior spinnerets are made up of three categories of secretory cells. Silk from these glands consists of two proteins (core and outer coat) joined together by an intermediary layer of acidic glycoprotein. All the 160 type B aciniform glands opening on the posterior spinnerets secrete a single protein. Fifty tubuliform glands opening on the median and posterior spinnerets produce two proteins, one of which is coloured. As in Urocteinae, long posterior spinnerets and large, numerous aciniform and tubuliform glands are correlated with swathing of prey and egg-cocoon construction. In Lycosidae and Agelenidae, the ampullate glands show the same number and distribution according to the spinnerets. However, anatomical and histochemical features of hersiliid aciniform and ampullate glands are close to those of some Araneoidea. Apart from peculiar characteristics, silk glands of Hersilia might represent an intermediate evolutionary stage towards Araneoidea.


1993 ◽  
Vol 13 (9) ◽  
pp. 5513-5523
Author(s):  
K Mizuno ◽  
K Hasegawa ◽  
T Katagiri ◽  
M Ogimoto ◽  
T Ichikawa ◽  
...  

Protein tyrosine phosphatases (PTPs), together with protein tyrosine kinases (PTKs), are involved in the regulation of cell activation, growth, and differentiation. To further elucidate the fine tuning of cell growth and differentiation through tyrosine phosphorylation, we tried to isolate mouse receptor-type PTP (RPTP) cDNA clones by screening mouse brain cDNA libraries with mouse CD45 PTP domain probes under reduced-stringency conditions. Characterization of isolated cDNA clones for RPTP showed that the cytoplasmic region contains two tandem repeats of PTP domain of about 230 amino acids with intrinsic phosphatase activity. The extracellular region was composed of immunoglobulin (Ig)-like domains and fibronectin type III (FN-III)-like domains. The gene was highly homologous to human PTP delta (HPTP delta) and thus was named MPTP delta (murine counterpart of HPTP delta). The MPTP delta gene appeared to generate at least three species of mRNA, which differ in the composition of the extracellular domain: type A, one Ig-like and four FN-III-like domains; type B, one Ig-like and eight FN-III-like domains; and type C, three Ig-like and eight FN-III-like domains. Interestingly, the 5' untranslated region and the leader peptide of types A and B were completely different from those of type C. Northern (RNA) blot analysis demonstrated that brain, kidney, and heart cells express three mRNA species of about 7 kb. Antibody directed against part of the extracellular domain of type A MPTP delta recognized a 210-kDa protein in brain and kidney lysates. In situ hybridization of brain samples revealed that MPTP delta mRNA is present in the hippocampus, thalamic reticular nucleus, and piriform cortex, where some Src family PTKs have been also demonstrated to exist. Although MPTP delta mRNA was not detected in lymphoid tissues, all of the pre-B-cell lines tested and one of three B-cell lines tested expressed MPTP delta mRNA, whereas antibody-producing B-cell hybridomas and T-cell and macrophage lines did not. Finally, the MPTP delta locus was tightly linked to the brown (b) locus on mouse chromosome 4.


Circulation ◽  
2015 ◽  
Vol 132 (suppl_3) ◽  
Author(s):  
Andrea Colli ◽  
Laura Besola ◽  
Lorenzo Bagozzi ◽  
Erica Manzan ◽  
Eleonora Bizzotto ◽  
...  

Introduction: TOP-MINI is a new micro invasive surgical procedure to treat degenerative mitral valve regurgitation due to flail/prolapse. Hypothesis: This prospective single centre study sought to assess the safety and effectiveness of the TOP-MINI procedure up to one year follow-up. Methods: Clinical and Echocardiographic outcomes were evaluated at 1, 3, 6 months and 1 year follow-up for all patients underwent TOP-MINI procedure from November 2013 to March 2015. Procedural success was defined as residual MR≤2+ at any time. Results: Sixty-one patients were treated during study period. One year survival was 96.7±2.3%. Freedom from MR>2+ is shown in figure 1 Panel A, Freedom from MR>2+ according to valve anatomy (Type A isolated P2 disease, Type B posterior multisegment disease, Type C anterior or bileaflet and/or calcified disease) is shown in Figure 1 Panel B. Freedom from MR>2+ according to STS risk profile is shown in Figure 2. The trend of Echocardiographic parameters is shown in Figure 3. Conclusions: TOP-MINI is a safe and effective procedure at 1 year FU. Residual MR is influenced by valve anatomy showing good results in Type A and B patients. Future techniques refinements are needed in order to improve outcomes of Type C patients. The lack of annuloplasty procedure does not influence negatively left ventricle reverse remodeling.


2013 ◽  
Vol 33 (8) ◽  
pp. 963-969 ◽  
Author(s):  
Eduardo C. Cruz Junior ◽  
Felipe M. Salvarani ◽  
Rodrigo O.S. Silva ◽  
Marcos X. Silva ◽  
Francisco C.F. Lobato ◽  
...  

The purpose of the study was to evaluate the real importance of anaerobic enteropathogens and rotavirus in contrast to more common agents as cause of diarrhea in piglets within the first week of life. Sixty 1- to 7-day-old piglets, 30 diarrheic and 30 non-diarrheic (control), from 15 different herds were selected, euthanized and necropsied. Samples of the jejunum, ileum, colon, cecum and feces were collected from the piglets and analyzed to determine the presence of the following enteropathogens: enterotoxigenic Escherichia coli (ETEC), Clostridium perfringens types A and C, Clostridium difficile, rotavirus and Isospora suis. Among diarrheic piglets, 23.3% were positive for C. difficile, 70% for C. perfringens type A cpb2+, 14.3% for rotavirus and 10% for ETEC. Among non-diarrheic control piglets, 10% were positive for C. difficile, 76.7% for C. perfringens type A cpb2+, 0% for rotavirus, 3.3% for ETEC and 3.3% for I. suis. C. perfringens type C was not detected in any of the animals. Histological lesions characteristic of C. difficile, E. coli and rotavirus were observed. However, no C. perfringens type A suggestive lesions were detected. There was a positive correlation between mesocolon edema and the presence of C. difficile toxins. Although C. perfringens type A cpb2+ was the most frequently detected enteropathogen, there was no association between its presence and diarrhea or macro or microscopic changes. C. difficile and Rotavirus were the most relevant pathogens involved with neonatal diarrhea in this study, and histopathology associated with microbiological test proved to be the key to reach a final diagnosis.


2017 ◽  
Vol 17 (3) ◽  
pp. 39-56 ◽  
Author(s):  
Sérgio Roberto Andrade Dantas ◽  
Fulvio Vittorino ◽  
Kai Loh

Abstract Contact of facades with degradation agents and direct incidence of ultraviolet radiation on external coatings make them more opaque over time, affecting their colour and reflectance characteristics. This study evaluated the effect of adding different TiO2 contents to mortars applied in concrete substrates in order to verify the reflectance maintenance on surfaces after exposure over time. Mortar with different concentrations of TiO2 (1%, 5%, 10%) were produced in relation to the total dry premix, added as a powder and compared to unpainted mortar without TiO2 (type "A") and painted mortar without TiO2 (type "B"), both used as a reference for colour and reflectance. Exposed over 16 months to climate conditions in São Paulo, regarding the maintenance of reflectance and solar radiation, the results showed that type "B" (0%TiO2) painted mortar presented the best performance. Type "C" (1%TiO2) and type "D" (5%TiO2) unpainted mortar remained more stable. Type "A" (0%TiO2) and type "E" (10%TiO2) unpainted mortar showed greater differences according to the Just Noticeable Difference (JND) range caused by dirt pick up.


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