The Rayleigh–Brillouin spectrum of hydrogen at high densities

1978 ◽  
Vol 56 (9) ◽  
pp. 1168-1174 ◽  
Author(s):  
A. D. May ◽  
M. Hubert ◽  
V. Ghaem-Maghami

The Rayleigh–Brillouin spectrum of light scattered from hydrogen at high densities is reported. The observations are compared with translational hydrodynamic theory and ultrasonic experiments. The range of densities includes the relaxation region and we find evidence for multiple relaxation. A mean relaxation time for normal hydrogen at 24 °C of (1.41 ± 0.06) × 10−8 s is found, in agreement with theoretical calculations.

2012 ◽  
Vol 05 ◽  
pp. 391-399
Author(s):  
NIKOLOZ M. CHIKHRADZE ◽  
CONSTANTIN POLITIS ◽  
MIKHEIL CHIKHRADZE ◽  
GEORGE ONIASHVILI

Theoretical and experimental Investigations of shock wave consolidation processes of Ti - Al nano sized and ultra-disperse powder compositions are discussed. For theoretical calculations of the shock wave loaded materials were used the hydrodynamic theory and experimental adiabatic of Ti and Al . The normal and tangential stresses in the cylindrical steel tube (containers of Ti - Al reaction mixtures) were estimated using the partial solutions of elasticity theory. The mixtures of ultra-disperse Ti and nano sized (≤ 50nm) Al powder compositions were consolidated to full or near-full density by explosive-compaction technology. The ammonium nitride based industrial explosives were used for generation of shock waves. To form ultra-fine grained bulk TiAl intermetallics with different compositions, ultra-disperse Ti particles were mixed with nano-crystalline Al . Each reaction mixture was placed in a sealed container and explosively compacted using a normal and cylindrical detonation set-up. Explosive compaction experiments were performed in range of pressure impulse (5-20) GPa. X-ray diffraction (XRD), structural investigations (SEM) and micro-hardness measurements were used to characterize the intermetallics phase composition and mechanical properties. The results of analysis revealing the effects of the compacting conditions and precursor particles sizes, affecting the consolidation and the properties of this new ultra high performance alloys are discussed.


1977 ◽  
Vol 55 (1) ◽  
pp. 23-26 ◽  
Author(s):  
M. Hubert ◽  
A. D. May

This paper reports on a comparison between the observed Rayleigh–Brillouin spectra of compressed hydrogen and those computed according to the translational hydrodynamic theory of Desai and Kapral. Reasonable agreement is found in the range of densities from 19 to 61 amagat units. It is suggested that small residual discrepancies may be due to the neglect of part of the coupling between the energy and momentum fluctuations arising from relaxation of the rotational states, i.e. due to the neglect of the 1ν1 terms.


1993 ◽  
Vol 07 (13n14) ◽  
pp. 887-893 ◽  
Author(s):  
K.T. TSEN ◽  
C. CHIA ◽  
J. WEST ◽  
H. MORKOC

Population relaxation time of confined as well as interface optical phonons in a series of GaAs-AlAs multiple quantum well structures has been measured by picosecond time-resolved Raman spectroscopy. Our experimental results have shown that (1) within the experimental accuracy, the population relaxation time of confined optical phonons in GaAs-AlAs multiple quantum well structures is independent of GaAs well-width and is given by 6±1 ps at T=10 K; (2) the population relaxation times of both GaAs -like and AlAs -like interface optical phonons increase as GaAs well-width increases from 20 Å to 100 Å. These experimental results are compared with theoretical calculations recently carried out by Gupta and Ridley (Ref. 3).


1978 ◽  
Vol 100 (2) ◽  
pp. 287-294 ◽  
Author(s):  
A. Harnoy

The hydrodynamic theory of lubrication in journal bearings is extended to elastico-viscous lubricants. The stress relaxation effect upon flow, pressure distribution, friction, and bearing load capacity is considered. This analysis deals with the case of a small relaxation time compared with the transit time required for the lubricant to pass through the bearing. A lubricant model is assumed with a constant relaxation time and without any cross stresses. It is found that the bearing load capacity of an elastic liquid lubrication film is higher than that of a Newtonian one, while the friction torque remains unchanged. Existing experimental studies have shown considerable improvement in journal bearing performance with elastico-viscous lubricants. This analysis suggests stress relaxation to be one of the factors giving rise to this improvement.


1980 ◽  
Vol 35 (4) ◽  
pp. 447-452
Author(s):  
H. Jena ◽  
W. Kreische ◽  
H. U. Maar ◽  
H. Niedrig ◽  
K. Reuter ◽  
...  

Abstract In aqueous BeF2-solutions of different concentrations and therefore different viscosities the magnetic relaxation time T1 was measured as a function of the viscosity over a wide range by pulsed NMR-technique. For small viscosities a linear dependence of T1 on the viscosity was observed as predicted by theoretical calculations. Since the ground state spin of 19F is I = 1/2, the quadrupole moment vanishes. For observing quadrupole relaxation of the F-nuclei, one has to use an excited level. With the time differential perturbed angular distribution method (TDPAD) we observed the quadrupole relaxation time TRel of 19F in aqueous BeF2-solutions.


1972 ◽  
Vol 50 (12) ◽  
pp. 1227-1229 ◽  
Author(s):  
E. H. Hara ◽  
A. D. May

The observations presented by Hara et al. for the Brillouin spectrum of H2, D2, and HD are compared with the thermo-hydrodynamic theory of Bhatia and Tong. It is noted that although this theory is qualitatively correct it fails to describe accurately the spectrum at low to medium densities. It is suggested that the introduction of a relaxing thermal conduction might account for the discrepancy observed.


1975 ◽  
Vol 53 (4) ◽  
pp. 343-350 ◽  
Author(s):  
M. Hubert ◽  
A. D. May

This paper reports the observation at high resolution of the Rayleigh–Brillouin spectrum of normal and parahydrogen at room temperature. The spectra are compared with a number of kinetic model calculations based on the Wang–Chang Uhlenbeck equation. It is concluded that n-H2 behaves effectively as a system characterized by a single relaxation time for the internal degrees of freedom and that the S6 model of Tenti et al. gives a very good description of the Rayleigh–Brillouin spectrum of a molecular gas at low and medium densities. At higher densities the models fail because the Wang–Chang Uhlenbeck equation is no longer valid.


1988 ◽  
Vol 102 ◽  
pp. 71-73
Author(s):  
E. Jannitti ◽  
P. Nicolosi ◽  
G. Tondello

AbstractThe photoabsorption spectra of the carbon ions have been obtained by using two laser-produced plasmas. The photoionization cross-section of the CV has been absolutely measured and the value at threshold, σ=(4.7±0.5) × 10−19cm2, as well as its behaviour at higher energies agrees quite well with the theoretical calculations.


Author(s):  
R. H. Morriss ◽  
J. D. C. Peng ◽  
C. D. Melvin

Although dynamical diffraction theory was modified for electrons by Bethe in 1928, relatively few calculations have been carried out because of computational difficulties. Even fewer attempts have been made to correlate experimental data with theoretical calculations. The experimental conditions are indeed stringent - not only is a knowledge of crystal perfection, morphology, and orientation necessary, but other factors such as specimen contamination are important and must be carefully controlled. The experimental method of fine-focus convergent-beam electron diffraction has been successfully applied by Goodman and Lehmpfuhl to single crystals of MgO containing light atoms and more recently by Lynch to single crystalline (111) gold films which contain heavy atoms. In both experiments intensity distributions were calculated using the multislice method of n-beam diffraction theory. In order to obtain reasonable accuracy Lynch found it necessary to include 139 beams in the calculations for gold with all but 43 corresponding to beams out of the [111] zone.


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