Rotation–Vibration Coupling in Diatomic Molecules and the Factorization Method. II. Closed Form Formulas for the Morse–Pekeris Intensities
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It is shown that, by applying an "accelerated" ladder operatorial formalism or an equivalent matrix procedure, one can obtain, easily, for the case of a Morse–Pekeris potential, a closed form expression of the rotation–vibration nuclear dipole moment matrix elements. This explicit expression, which is valid for any degree k of the dipole moment Taylor's expansion, allows the determination of the rotation–vibration intensities for any ΩνJ → Ω′ν′J′ transition.
1995 ◽
Vol 142
(6)
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pp. 492
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1991 ◽
Vol 205
(5)
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pp. 311-316
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2021 ◽
Vol 48
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pp. 91-96
2011 ◽
Vol 38
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pp. 494-499
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