Rotation–Vibration Coupling in Diatomic Molecules and the Factorization Method. I. Closed Form Formulas for the Vibration Intensities

1973 ◽  
Vol 51 (19) ◽  
pp. 2075-2085 ◽  
Author(s):  
M. Badawi ◽  
N. Bessis ◽  
G. Bessis

It is shown that the factorization method followed by an “accelerated" operatorial formalism or an equivalent matrix procedure leads to explicit formulas for calculating transition matrix elements. The calculation has been completely carried out for the pure vibration case of diatomic molecules, for any degree k of the dipole moment Taylor's expansion. The intuitive approximate proportionality between the radial dipole matrix element and an overlap integral is demonstrated.

1974 ◽  
Vol 52 (2) ◽  
pp. 110-119 ◽  
Author(s):  
M. Badawi ◽  
N. Bessis ◽  
G. Bessis ◽  
G. Hadinger

It is shown that, by applying an "accelerated" ladder operatorial formalism or an equivalent matrix procedure, one can obtain, easily, for the case of a Morse–Pekeris potential, a closed form expression of the rotation–vibration nuclear dipole moment matrix elements. This explicit expression, which is valid for any degree k of the dipole moment Taylor's expansion, allows the determination of the rotation–vibration intensities for any ΩνJ → Ω′ν′J′ transition.


2001 ◽  
Vol 08 (03n04) ◽  
pp. 321-325
Author(s):  
ŞAKIR ERKOÇ ◽  
HATICE KÖKTEN

We have performed self-consistent field (SCF) calculations of the electronic structure of GaAs/Ga 1-x Al x As superlattices with parabolic potential profile within the effective mass theory. We have calculated the optical transition matrix elements involving transitions from the hole states to the electron states, and we have also computed the oscillator strength matrix elements for the transitions among the electron states.


2017 ◽  
Vol 95 (1) ◽  
Author(s):  
B. A. Brown ◽  
A. B. Garnsworthy ◽  
T. Kibédi ◽  
A. E. Stuchbery

1981 ◽  
Vol 103 (4-5) ◽  
pp. 255-258 ◽  
Author(s):  
A.M. Bernstein ◽  
V.R. Brown ◽  
V.A. Madsen

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Onno R. Diermann ◽  
Martin Holthaus

AbstractWe demonstrate that a periodically driven quantum system can adopt a quasistationary state which is effectively much colder than a thermal reservoir it is coupled to, in the sense that certain Floquet states of the driven-dissipative system can carry much higher population than the ground state of the corresponding undriven system in thermal equilibrium. This is made possible by a rich Fourier spectrum of the system’s Floquet transition matrix elements, the components of which are addressed individually by a suitably peaked reservoir density of states. The effect is expected to be important for driven solid-state systems interacting with a phonon bath predominantly at well-defined frequencies.


2009 ◽  
Vol 79 (15) ◽  
Author(s):  
Carlos F. Destefani ◽  
Chris McDonald ◽  
Suren Sukiasyan ◽  
Thomas Brabec

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