Magnetic Aftereffect Due to Hydrogen in NdCo5
In single crystals of NdCo5 containing small amounts of hydrogen, a.c. susceptibility measurements reveal disaccommodation effects and low frequency loss peaks between 130 and 220 °K. Relaxation times, measured over ~5 decades, fit an Arrhenius relation of the form τ = τ0 exp (E/kT), with E = 0.40 ± 0.02 eV and τ0 = 10−12.3 ± 0.4 s. Hydrogen can be introduced by exposing the sample to the gas, or by etching it in acids; it can be removed by heating in a vacuum at ~750 °K. In the degassed material, additional relaxations, of unknown origin, are found near 375 and 720 °K, with E = 0.7 ± 0.1 and 1.6 ± 0.3 eV respectively. The possible importance of these effects to the coercivity of RCo5 compounds is pointed out.