Experimental determination of the dipole moments of the X(2Σ+) and B(2Σ+) states of the CN molecule

1968 ◽  
Vol 46 (24) ◽  
pp. 2815-2819 ◽  
Author(s):  
Ritchie Thomson ◽  
F. W. Dalby
Keyword(s):  
Emission Spectrum ◽  
Experimental Determination ◽  
Electric Fields ◽  
Dipole Moments ◽  
High Electric Fields

From observation of the electronic emission spectrum in high electric fields, the dipole moments of the X(2Σ+) and B(2Σ+) states of the CN molecule have been determined to be 1.45 ± 0.08 and 1.15 ± 0.08 debye, respectively. The relative signs of the dipole moments in these two states are shown to be opposite.

An experimental determination of the dipole moments of the X(1Σ) and A(1Π) states of the BH molecule

1969 ◽  
Vol 47 (11) ◽  
pp. 1155-1158 ◽  
Author(s):  
Ritchie Thomson ◽  
F. W. Dalby
Keyword(s):  
Emission Spectrum ◽  
Experimental Determination ◽  
Electric Fields ◽  
Discharge Tube ◽  
Dipole Moments ◽  
Optical Emission ◽  
Optical Emission Spectrum ◽  
Stark Effects ◽  
High Electric Fields

The optical emission spectrum of the BH radical produced in a discharge tube designed to give high electric fields shows Stark effects. From these, the dipole moments of the X(1Σ+) and A(1Π) states are determined to be (1.27 ± 0.21) D and (0.58 ± 0.04) D, respectively.

scholarly journals Experimental determination of line energies, line widths and relative transition probabilities of the Gadolinium L x-ray emission spectrum

Metrologia ◽  
2019 ◽  
Vol 56 (6) ◽  
pp. 065007
Author(s):  
Malte Wansleben ◽  
Yves Kayser ◽  
Philipp Hönicke ◽  
Ina Holfelder ◽  
André Wählisch ◽  
...  
Keyword(s):  
Emission Spectrum ◽  
Experimental Determination ◽  
Transition Probabilities ◽  
X Ray ◽  
Relative Transition ◽  
Line Widths

Experimental Determination of Dipole Moments of Some Benzamide Derivatives

1998 ◽  
Vol 53 (8) ◽  
pp. 684-688
Author(s):  
J. Heidt ◽  
J. R. Heidt ◽  
M. Raciniewskab
Keyword(s):  
Excited State ◽  
Experimental Determination ◽  
Gas Phase ◽  
Electronic Absorption ◽  
Dipole Moments ◽  
Absorption Bands ◽  
Excited State Dipole Moments ◽  
Benzamide Derivatives

Abstract The excited state dipole moments of some benzamide derivatives are determined. The method of solvent induced shifts of electronic absorption bands in comparison with their positions in the gas phase is used. Some regular trends revealed in the obtained data are discussed. The present results are compared with those available in the literature.

Determination of the dipole moments of molecular ions from the rotational Zeeman effect by tunable far-infrared laser spectroscopy

1988 ◽  
Vol 324 (1578) ◽  
pp. 109-119 ◽  
Keyword(s):  
Dipole Moment ◽  
Experimental Determination ◽  
Laser Spectroscopy ◽  
Dipole Moments ◽  
Zeeman Effect ◽  
Far Infrared ◽  
Molecular Ions ◽  
Far Infrared Laser ◽  
Infrared Laser Spectroscopy

The details of the first experimental determination of the dipole moment of a molecular ion from the rotational Zeeman effect are presented, along with an assessment of the ultimate accuracy of the technique.

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