scholarly journals Molecular association at the microscopic level

2011 ◽  
Vol 89 (7) ◽  
pp. 793-797
Author(s):  
Richard M. Neumann
Keyword(s):  
Association Constant ◽  
Helmholtz Free Energy ◽  
Freezing Temperature ◽  
Separation Distance ◽  
Microscopic Level ◽  
Condensation Temperature ◽  
Dilute Solution ◽  
Dense Fluid ◽  
Configuration Integral ◽  
Definition Of

For the molecular equilibrium A + B ⇔ AB occurring in a dilute solution or gas, the two-particle Helmholtz free energy, W, is used to evaluate the association constant, KAB, which, for ionic A and B, is identical to the Bjerrum result. The criterion defining the bound species AB is not arbitrary; the cutoff separation distance in the configuration integral used to calculate KAB arises directly from the definition of W. For a one-component dense fluid, W permits the derivation of the phase-condensation temperature, which, for a gas, is the critical temperature and for a liquid the freezing temperature. For ionic A and B (e.g., molten salt), the Kosterlitz–Thouless expression for the freezing temperature is obtained.

scholarly journals Pulse Dispersion in Phased Arrays

2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Randy L. Haupt ◽  
Payam Nayeri
Keyword(s):  
Phased Array ◽  
Phased Arrays ◽  
Separation Distance ◽  
Phase Shifting ◽  
Phased Array Antenna ◽  
Phased Array Antennas ◽  
Wideband Signals ◽  
First Results ◽  
Definition Of ◽  
The Time Domain

Phased array antennas cause pulse dispersion when receiving or transmitting wideband signals, because phase shifting the signals does not align the pulse envelopes from the elements. This paper presents two forms of pulse dispersion that occur in a phased array antenna. The first results from the separation distance between the transmit and receive antennas and impacts the definition of far field in the time domain. The second is a function of beam scanning and array size. Time delay units placed at the element and/or subarrays limit the pulse dispersion.

scholarly journals Casimir free energy for massive fermions: a comparative study of various approaches

2022 ◽  
Author(s):  
Mehrdokht Sasanpour ◽  
Chenor Ajilian ◽  
Siamak Sadat Gousheh
Keyword(s):  
Free Energy ◽  
Comparative Study ◽  
Helmholtz Free Energy ◽  
Continuation Method ◽  
Fermion Field ◽  
Thermodynamic Quantities ◽  
Zero Temperature ◽  
Parallel Plates ◽  
Subtraction Method ◽  
Definition Of

Abstract We compute the Casimir thermodynamic quantities for a massive fermion field between two parallel plates with the MIT boundary conditions, using three different general approaches and present explicit solutions for each. The Casimir thermodynamic quantities include the Casimir Helmholtz free energy, pressure, energy and entropy. The three general approaches that we use are based on the fundamental definition of Casimir thermodynamic quantities, the analytic continuation method represented by the zeta function method, and the zero temperature subtraction method. We include the renormalized versions of the latter two approaches as well, whereas the first approach does not require one. Within each general approach, we obtain the same results in a few different ways to ascertain the selected cancellations of infinities have been done correctly. We then do a comparative study of the three different general approaches and their results, and show that they are in principle not equivalent to each other and they yield in general different results. In particular, we show that the Casimir thermodynamic quantities calculated only by the first approach have all three properties of going to zero as the temperature, the mass of the field, or the distance between the plates increases.

Modeling of Rockburst by Elastoplastic Damage Theory at Finite Strains

2014 ◽  
Vol 501-504 ◽  
pp. 384-390
Author(s):  
Ji Li Feng ◽  
Chao Jun Li ◽  
Zhen Yu Zhang ◽  
Zhao Yi Song ◽  
Yong Liang Hao
Keyword(s):  
Helmholtz Free Energy ◽  
Basic Mechanism ◽  
Internal Variables ◽  
Finite Strain Plasticity ◽  
Elasto Plasticity ◽  
Isotropic Damage ◽  
Damage Theory ◽  
Definition Of ◽  
Element Technique ◽  
Elastoplastic Damage

Rockburst is modeled in this paper by the theory of elastoplastic damage at finite stains. Isotropic damage coupled with elastoplasticity is assumed and multiplicative kinematics in a purely mechanical setting is further applied. Merging the finite strain plasticity framework of Simo and the thermodynamics with internal variables of Lemaitre in definition of damage including processes, the Helmholtz free energy is additively decomposed to characterize the basic mechanism of elasto-plasticity and damage of brittle materials. The numerical simulations for granite burst are conducted by finite element technique.

Introductory paper

1966 ◽  
Vol 24 ◽  
pp. 3-5
Author(s):  
W. W. Morgan
Keyword(s):  
Line Intensity ◽  
Classification Scheme ◽  
Two Dimensional ◽  
Spectral Classification ◽  
Dimensional Array ◽  
Rr Lyrae ◽  
Metallic Line ◽  
Introductory Paper ◽  
Parameter Varying ◽  
Definition Of

1. The definition of “normal” stars in spectral classification changes with time; at the time of the publication of theYerkes Spectral Atlasthe term “normal” was applied to stars whose spectra could be fitted smoothly into a two-dimensional array. Thus, at that time, weak-lined spectra (RR Lyrae and HD 140283) would have been considered peculiar. At the present time we would tend to classify such spectra as “normal”—in a more complicated classification scheme which would have a parameter varying with metallic-line intensity within a specific spectral subdivision.

2.2. Working Group 2: Conceptual Definitions of Reference Coordinate Systems for Earth Dynamics

1975 ◽  
Vol 26 ◽  
pp. 21-26
Keyword(s):  
Coordinate System ◽  
Working Group ◽  
General Character ◽  
Coordinate Systems ◽  
Reference Coordinate System ◽  
Group 2 ◽  
Definition Of ◽  
Earth Dynamics

An ideal definition of a reference coordinate system should meet the following general requirements:1. It should be as conceptually simple as possible, so its philosophy is well understood by the users.2. It should imply as few physical assumptions as possible. Wherever they are necessary, such assumptions should be of a very general character and, in particular, they should not be dependent upon astronomical and geophysical detailed theories.3. It should suggest a materialization that is dynamically stable and is accessible to observations with the required accuracy.

Symbiotic Stars at Optical, Infrared and Radio Wavelengths

1979 ◽  
Vol 46 ◽  
pp. 125-149 ◽  
Author(s):  
David A. Allen
Keyword(s):  
Temperature Regime ◽  
Type Star ◽  
Stellar Systems ◽  
Symbiotic Stars ◽  
Lower Excitation ◽  
Definition Of ◽  
Original Type

No paper of this nature should begin without a definition of symbiotic stars. It was Paul Merrill who, borrowing on his botanical background, coined the termsymbioticto describe apparently single stellar systems which combine the TiO absorption of M giants (temperature regime ≲ 3500 K) with He II emission (temperature regime ≳ 100,000 K). He and Milton Humason had in 1932 first drawn attention to three such stars: AX Per, CI Cyg and RW Hya. At the conclusion of the Mount Wilson Ha emission survey nearly a dozen had been identified, and Z And had become their type star. The numbers slowly grew, as much because the definition widened to include lower-excitation specimens as because new examples of the original type were found. In 1970 Wackerling listed 30; this was the last compendium of symbiotic stars published.

Immunoferritin localization of intracellular antigens in positively stained frozen sections

1978 ◽  
Vol 36 (2) ◽  
pp. 168-169
Author(s):  
K. T. Tokuyasu
Keyword(s):  
Surface Tension ◽  
Water Surface ◽  
Thin Layers ◽  
The Other ◽  
Positive Staining ◽  
Frozen Sections ◽  
The Past ◽  
Ultrathin Frozen Sections ◽  
Definition Of

During the past investigations of immunoferritin localization of intracellular antigens in ultrathin frozen sections, we found that the degree of negative staining required to delineate u1trastructural details was often too dense for the recognition of ferritin particles. The quality of positive staining of ultrathin frozen sections, on the other hand, has generally been far inferior to that attainable in conventional plastic embedded sections, particularly in the definition of membranes. As we discussed before, a main cause of this difficulty seemed to be the vulnerability of frozen sections to the damaging effects of air-water surface tension at the time of drying of the sections.Indeed, we found that the quality of positive staining is greatly improved when positively stained frozen sections are protected against the effects of surface tension by embedding them in thin layers of mechanically stable materials at the time of drying (unpublished).

A simplified method of emulsion coating and development for quantitative electron microscopic radioautography

1978 ◽  
Vol 36 (2) ◽  
pp. 64-65
Author(s):  
K. Yoshida ◽  
F. Murata ◽  
S. Ohno ◽  
T. Nagata
Keyword(s):  
Mass Production ◽  
Identical Condition ◽  
Microscopic Level ◽  
Electron Microscopic Level ◽  
Electron Microscopic ◽  
Simplified Method ◽  
Complicated Process ◽  
Critical Problems ◽  
Electron Microscopic Radioautography ◽  
Quantitative Radioautography

IntroductionSeveral methods of mounting emulsion for radioautography at the electron microscopic level have been reported. From the viewpoint of quantitative radioautography, however, there are many critical problems in the procedure to produce radioautographs. For example, it is necessary to apply and develop emulsions in several experimental groups under an identical condition. Moreover, it is necessary to treat a lot of grids at the same time in the dark room for statistical analysis. Since the complicated process and technical difficulties in these procedures are inadequate to conduct a quantitative analysis of many radioautographs at once, many factors may bring about unexpected results. In order to improve these complicated procedures, a simplified dropping method for mass production of radioautographs under an identical condition was previously reported. However, this procedure was not completely satisfactory from the viewpoint of emulsion homogeneity. This paper reports another improved procedure employing wire loops.

Ultrastructural Investigation of Spontaneous Pituitary Adenomas in Aging Sprague-Dawley Rats

1982 ◽  
Vol 40 ◽  
pp. 216-217
Author(s):  
D. J. McComb ◽  
J. Beri ◽  
F. Zak ◽  
K. Kovacs
Keyword(s):  
Microscopic Study ◽  
Pituitary Adenomas ◽  
Wistar Rats ◽  
Microscopic Level ◽  
Sprague Dawley ◽  
Prolactin Cells ◽  
Light Microscopic Level ◽  
Ultrastructural Investigation ◽  
Sprague Dawley Rats ◽  
Long Evans

Investigation of the spontaneous pituitary adenomas in rat have been limited mainly to light microscopic study. Furth et al. (1973) described them as chromophobic, secreting prolactin. Kovacs et al. (1977) in an ul trastructural investigation of adenomas of old female Long-Evans rats, found that they were composed of prolactin cells. Berkvens et al. (1980) using immunocytochemistry at the light microscopic level, demonstrated that some spontaneous tumors of old Wistar rats could contain GH, TSH or ACTH as well as PRL.

Initial Polymerization Sites Indicated During Mitochondrial Oxidation of Diaminobenzidine after Toluene Treatment

1977 ◽  
Vol 35 ◽  
pp. 408-409
Author(s):  
W. A. Shannon ◽  
M. A. Matlib
Keyword(s):  
Membrane Permeability ◽  
Cytochrome Oxidase ◽  
Rat Liver ◽  
Precise Definition ◽  
Cytochemical Localization ◽  
Oxidative Reaction ◽  
Mitochondrial Oxidation ◽  
Definition Of ◽  
Exogenous Substrates

Numerous studies have dealt with the cytochemical localization of cytochrome oxidase via cytochrome c. More recent studies have dealt with indicating initial foci of this reaction by altering incubation pH (1) or postosmication procedure (2,3). The following study is an attempt to locate such foci by altering membrane permeability. It is thought that such alterations within the limits of maintaining morphological integrity of the membranes will ease the entry of exogenous substrates resulting in a much quicker oxidation and subsequently a more precise definition of the oxidative reaction.The diaminobenzidine (DAB) method of Seligman et al. (4) was used. Minced pieces of rat liver were incubated for 1 hr following toluene treatment (5,6). Experimental variations consisted of incubating fixed or unfixed tissues treated with toluene and unfixed tissues treated with toluene and subsequently fixed.

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