Quantitative trace-element modelling of the crystallization history of the Kinojévis and Blake River groups, Abitibi Greenstone Belt, Ontario

1989 ◽  
Vol 26 (7) ◽  
pp. 1356-1367 ◽  
Author(s):  
A. D. Fowler ◽  
L. S. Jensen

The Archean tholeiitic Kinojévis suite is characterized by an iron-enrichment trend and abundant Fe–Ti oxides in its evolved basalts, andesites, and rhyolites. The rare-earth-element (REE) patterns of the suite remain flat from the basalts through to the rhyolites, with the development of small, negative Eu anomalies. Quantitative modelling of the trace elements from little-altered samples is consistent with the mineralogy, suggesting that the suite was produced through fractional crystallization of olivine, pyroxene, plagioclase, and Fe–Ti oxides. The evolved rhyolites are interpreted as having developed by greater than 90% fractional crystallization in a high-level magma chamber.The calc-alkaline Blake River Group conformably overlies the Kinojévis rocks and is characterized by enrichment in alkalis and silica. The REE patterns are light rare-earth-element (LREE) enriched, and the felsic rocks have prominent negative Eu anomalies. Geochemical modelling shows that the suite could have developed either through fractional crystallization dominated by plagioclase and clinopyroxene or by assimilation of tonalite, coupled with fractional crystallization.

1998 ◽  
Vol 35 (8) ◽  
pp. 951-963 ◽  
Author(s):  
J Dostal ◽  
D A Robichaud ◽  
B N Church ◽  
P H Reynolds

Eocene volcanic rocks of the Buck Creek basin in central British Columbia are part of the Challis-Kamloops volcanic belt extending from the United States across British Columbia to central Yukon. The volcanic rocks include two units, the Buck Creek Formation, composed of high-K calc-alkaline rocks with predominant andesitic composition, and the overlying Swans Lake unit made up of intraplate tholeiitic basalts. Whole rock 40Ar/39Ar data for both units show that they were emplaced at 50 Ma. They have similar mantle-normalized trace element patterns characterized by a large-ion lithophile element enrichment and Nb-Ta depletion, similar chondrite-normalized rare earth element patterns with (La/Yb)n ~4-14 and heavy rare earth element fractionation, and overlapping epsilonNd values (2.4-3.1) and initial Sr-isotope ratios ( ~ 0.704). These features suggest derivation of these two units from a similar mantle source, probably garnet-bearing subcontinental lithosphere. The differences between tholeiitic and calc-alkaline suites can be due, in part, to differences in the depth of fractional crystallization and the crystallizing mineral assemblage. Fractional crystallization of the calc-alkaline magmas began at a greater (mid-crustal) depth and included fractionation of Fe-Ti oxides. The volcanic rocks are probably related to subduction of the Farallon plate under the North American continent in a regime characterized by transcurrent movements and strike-slip faulting.


Author(s):  
E. Blereau ◽  
C. Clark ◽  
P. D. Kinny ◽  
E. Sansom ◽  
R. J. M. Taylor ◽  
...  

1984 ◽  
Vol 21 (6) ◽  
pp. 731-736 ◽  
Author(s):  
Nathan L. Green ◽  
Paul Henderson

A suite of hy-normative hawaiites, ne-normative mugearite, and calc-alkaline andesitic rocks from the Garibaldi Lake area exhibits fractionated, slightly concave-upward REE patterns (CeN/YbN = 4.5–15), heavy REE contents about 5–10 times the chondritic abundances, and no Eu anomalies. It is unlikely that the REE patterns provide information concerning partial melting conditions beneath southwestern British Columbia because they have probably been modified substantially by upper crustal processes including crustal contamination and (or) crystal fractionation. The REE contents of the Garibaldi Lake lavas are not incompatible with previous interpretations that (1) the hawaiites have undergone considerable fractionation of olivine, plagioclase, and clinopyroxene; and (2) the individual andesitic suites were derived from separate batches of chemically distinct magma that evolved along different high-level crystallization trends. In general, however, the andesites are characterized by lower light REE contents than the basaltic andesites. These differences in LREE abundances may reflect different amounts of LREE-rich accessory phases, such as apatite, sphene, or allanite, assimilated from the underlying quartz diorites.


1996 ◽  
Vol 33 (11) ◽  
pp. 1534-1542 ◽  
Author(s):  
A. A. Hassanipak ◽  
A. Mohamad Ghazi ◽  
J. M. Wampler

The Band Ziarat complex of southeastern Iran is located on the western boundary of the Jaz Murian depression and is bounded by two major fault systems. The principal rock units of this complex are a gabbro sequence that includes low-and high-level cumulate gabbros, a late intrusive sequence that consists of diorite and plagiogranite, and a volcanic sequence that includes diabase dikes and a lesser amount of basaltic lava. Mantle rocks are virtually absent because of the presence of the two bounding fault systems, but we consider the complex to be an ophiolite in nature. Rare earth element (REE) whole-rock data clearly differentiate the classic ophiolitic lithologies for the crustal rocks in this complex. Based on the REE data, there are two distinct types of basalt present at Band Ziarat: (i) those that formed from an initial basaltic melt with a light rare earth element (LREE) enriched signature (similar to intraplate basalts), and (ii) those that have LREE-depleted patterns (similar to normal mid-ocean-ridge basalts). The data also suggest (i) that the gabbros are accumulates and were derived from a source slightly enriched in LREE, with fractionation controlled by removal of clinopyroxene or hornblende and plagioclase, and (ii) that the late intrusive rocks as well as a majority of the diabase dikes are cogenetic and were derived from the same LREE-enriched source. K–Ar ages ranging from 134 ± 4 to 146 ± 5 Ma for low-level gabbros and from 121 ± 4 to 130 ± 4 Ma for high-level gabbros were measured on five hornblende and two whole-rock samples, which suggests that these rocks may have formed early in the Cretaceous period.


2016 ◽  
Vol 80 (1) ◽  
pp. 77-102 ◽  
Author(s):  
Kenzo Sanematsu ◽  
Terumi Ejima ◽  
Yoshiaki Kon ◽  
Takayuki Manaka ◽  
Khin Zaw ◽  
...  

AbstractGeochemical characteristics and rare-earth element (REE)-bearing minerals of calc-alkaline granites in southern Myanmar were investigated to identify the minerals controlling fractionation between light and heavyREE(LREE and HREE) during magmatic differentiation and weathering. The granites were classified on the basis of the mineral assemblages into two contrasting groups: allanite-(Ce)- and/or titanite-bearing granites; and more HREE-enriched granites characterized by hydrothermal minerals including synchysite(Y), parisite-(Ce), bastnäsite-(Ce), xenotime-(Y), monazite-(Ce), Y-Ca silicate, waimirite-(Y) and fluorite. This suggests that allanite-(Ce) and titanite are not stable in differentiated magma and HREE are eventually preferentially incorporated into the hydrothermal minerals. The occurrence of theREE-bearing minerals is constrained by the degree of magmatic differentiation and the boundary of two contrasting granite groups is indicated by SiO2contents of ∼74 wt.% or Rb/Sr ratios of ∼3–8. Fractionation between LREE and HREE during weathering of the granites is influenced by weathering resistance of theREE-bearing minerals, i.e. allanite-(Ce), titanite, theREEfluorocarbonates and waimirite-(Y) are probably more susceptible to weathering, whereas zircon, monazite-(Ce) and xenotime-(Y) are resistant to weathering. Ion-exchangeableREEin weathered granites tend to be depleted in HREE relative to the whole-rock compositions, suggesting that HREE are more strongly adsorbed on weathering products or that HREE remain in residual minerals.


1980 ◽  
Vol 17 (9) ◽  
pp. 1292-1299 ◽  
Author(s):  
I. E. M. Smith

In well exposed, well developed greenstone belts of the Superior Province there is a clear progression from stratigraphically lower, geochemically primitive volcanic rock types (komatiites, tholeiites) to overlying geochemically evolved calc-alkaline volcanic rock types. In the western Blake River Group of the Abitibi Greenstone Belt the change from tholeiitic to calc-alkaline volcanics represents a geochemical discontinuity defined by an increase in incompatible elements and light/heavy rare-earth element fractionation in the overlying rocks. Quantitative modelling of the parameters of the discontinuity indicates that it can be explained by a change to very small amounts of melting of unmodified mantle lherzolite, although this is not a unique solution. In calc-alkaline suites showing high degrees of rare-earth element fractionation the calculated melt fraction required of unmodified mantle becomes unrealistically low and models involving a geochemically evolved source may have to be considered.


1989 ◽  
Vol 26 (12) ◽  
pp. 2465-2478 ◽  
Author(s):  
O. Rouer ◽  
H. Lapierre ◽  
C. Coulon ◽  
A. Michard

The mid-Paleozoic volcanics of northern Sierra Nevada consist of the Sierra Buttes rhyolites, the Taylor basalts and andesites, and the Keddie Ridge basalt–latite–rhyolite suite. The Sierra Buttes calc-alkaline rhyolites display strong light rare-earth element enrichment and negative εNd values. The Taylor basalts and andesites in the northern Hough and Genesee blocks exhibit calc-alkaline affinities (REE rare-earth element patterns highly enriched in LREE), whereas in the southern Hough block they are tholeiitic (flat rare-earth element patterns). The abundance of silicic lavas, the low εNd values of both the Sierra Buttes and Taylor volcanics and the δ18O values of the Sierra Buttes rhyolite and Bowman Lake trondjhemite provide evidence that the northern Sierra Nevada island arc was continent based. The Keddie Ridge differentiated volcanics, characterized by high Zr, Y, Nb, K, and light rare-earth elements, are geochemically similar to a shoshonite suite. Their eruption at the end of the mid-Paleozoic volcanic episode suggests a reversal of subduction, uplift, and block faulting in the island arc.The mid-Paleozoic volcanics of the northern Sierra Nevada are thought to represent the remnant of a mature island arc because calc-alkaline rocks predominate over tholeiitic ones, the lavas display a K enrichment with time, and the volcanics are evolved in their isotopes, compared with rocks erupted in young or primitive island arcs.


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