Electrical properties of Athabasca Oil Sands

1979 ◽  
Vol 16 (10) ◽  
pp. 2009-2021 ◽  
Author(s):  
F. S. Chute ◽  
F. E. Vermeulen ◽  
M. R. Cervenan ◽  
F. J. McVea

The results of a series of laboratory measurements of the electrical properties of samples of oil sand from the Athabasca deposit in northeastern Alberta are reported. The electrical conductivity and relative dielectric constant of the samples have been determined over a frequency range extending from 50–109 Hz. The measurements were performed on samples with a wide range of moisture content and over a temperature range from about 3–150 °C. A discussion of the methods and apparatus used is included.Sufficient data have been collected to permit correlation of the electrical properties of oil sand with density, moisture content, and temperature, and hence to indicate how the laboratory results can be extended to estimate in situ conductivities and dielectric constants. The results of these correlations, which are presented in graphical form, are of fundamental importance in any realistic assessment of the viability of electromagnetically heating large in situ deposits of oil sand.

1981 ◽  
Vol 18 (4) ◽  
pp. 742-750 ◽  
Author(s):  
M. Das ◽  
R. Thapar ◽  
K. Rajeshwar ◽  
J. DuBow

The electrical behavior of oil sand samples from the Athabasca, N. W. Asphalt Ridge, P. R. Spring, and Circle Cliffs deposits was studied in the frequency range 50 Hz – 103 MHz at ambient temperature and up to 550 °C. Anomalously high dielectric constants (ε′) were measured for these samples at low frequencies (<1 kHz) and at elevated temperatures (>200 °C). Accumulation of mobile charges at the phase boundaries in the oil sand matrix was probably responsible for this effect. These mobile charges were presumably created by thermal fragmentation of oil sand bitumen. The anomalous increase in the low-frequency (50 Hz – 1 MHz) ε′ values at temperatures above 150 °C was also traced to interfacial polarization effects. Dipole relaxation behavior was observed for the various samples at frequencies below ~1 kHz and in the temperature range 150–470 °C. Two distinct relaxation processes were identified. The low-temperature (150–400 °C) process had activation energies for dipole orientation ranging from 4.0 to 9.0 kJ/mol depending on the oil sand specimen. The second relaxation process, which occurred at temperatures above 400 °C, had significantly higher activation energies (30–34 kJ/mol). The occurrence of these dipole relaxation peaks may be relevant in the use of electrical techniques to map the location of pyrolysis zones in in situ oil sand retorts. Measurements on the Athabasca samples in the high-frequency range (1–103 MHz) revealed distinct changes in the dielectric parameters associated with the loss of water from the oil sand matrix. The electrical behavior of oil sands is represented in terms of an equivalent circuit model comprising discrete RC elements corresponding to various components in the oil sand matrix. Such a representation was found to aid in an assignment of the observed changes in the electrical properties with frequency and temperature to distinct physical or chemical processes occurring in the oil sand matrix.


Geophysics ◽  
1981 ◽  
Vol 46 (3) ◽  
pp. 322-332 ◽  
Author(s):  
James N. Lange ◽  
Steven S. Shope

The application of electromagnetic (EM) techniques to well logging is initiated in an environment dominated by the properties of the drilling fluids. An impulse technique using nanosecond pulses is applied to a coaxial waveguide containing drilling fluids to measure the velocity (dielectric constant ε) and absorption (attenuation coefficient α) of EM impulses. It is the large difference in dielectric constants of water and oil which makes EM propagation techniques attractive for logging. Dielectric properties of some nondispersed drilling fluids (bentonite and attapulgite clays) are found to be largely dependent upon the volume of water present. Both bentonite and attapulgite clays exhibit the same range of dielectric constants (ε = 81 → 75) when the weight percent of clay is increased to 10 percent. In contrast, the microwave attenuations of these two clays are quite different, with that of the bentonite increasing at about 4 times the rate of the attapulgite suspensions. Microwave attenuation measured for a variety of commercial drilling fluids varies over a wide range, with the lignosulfonates the largest (91 dB/m) and oil inverts the smallest (3 dB/m). The oil inverts also have a small dielectric constant (ε = 3 → 6). Temperature dependence of the attenuation for these same drilling fluids is determined in the range from 23 °C to 45 °C to indicate their behavior under in situ conditions.


1984 ◽  
Vol 24 (04) ◽  
pp. 417-430 ◽  
Author(s):  
Yoshiaki Ito

Ito, Yoshiaki, SPE, Gulf Canada Resources Inc. Abstract Historically, a vertical or horizontal fracture is believed to be a main recovery mechanism for a cyclic steam-injection process in unconsolidated oil sands. Most current computer process in unconsolidated oil sands. Most current computer models for the process are based on the fracture concept. With the postulated sand deformation concept, on the other hand, the injected fluid is able to penetrate the unconsolidated oil sand by creating micro channels. When the pore pressure is reduced during production, these secondary flow channels will collapse totally or partially. Condensed steam tends to sweep fluids where the bitumen had been heated and imparts mobility as a result of the injected hot fluid. Flow geometry of the new concept is described in this paper. The physical differences between the sand paper. The physical differences between the sand deformation zone and the no-deformation zone are also investigated. The three major differences between these two zones are porosity change, pressure level, and energy and flow characteristics resulting from the existence of micro channels. All these modifications were incorporated successfully into a conventional numerical thermal simulator. The new model provided an excellent match for all the field observations (steam-injection pressure, oil-and-water production rates, fluid production temperature, downhole production rates, fluid production temperature, downhole production pressure, and salinity changes) of a production pressure, and salinity changes) of a steam-stimulated well in an unconsolidated oil sand. The study indicates that the most important phenomenon for in-situ recovery of bitumen is the one-way-valve effect of the micro channels, which are opened during injection and closed during production. Introduction A physical interaction between the injected fluid and the reservoir formation is required to inject large volumes of steam into the oil sand formation. Until now, this physical interaction was believed to be a vertical or a physical interaction was believed to be a vertical or a horizontal fracture, depending on the strength of the directional stress. Many authors investigated and incorporated this concept into numerical thermal simulators and used it for history match and prediction studies. There are many difficulties in analyzing the actual performance of steam stimulated wells by means of the performance of steam stimulated wells by means of the fracture concept. Some of the evidence is extremely difficult or impossible to explain with the conventional fracture concept. A few of these problems are discussed later. I, therefore, have postulated a new flow geometry to achieve a realistic interpretation of well performances. The new flow geometry has been termed the "sand deformation concept." The well performance characteristics for the bitumen recovery process can be described more clearly with the new concept process can be described more clearly with the new concept than with the conventional fracture concept. Sand Deformation Concept Although unconsolidated oil sand might not behave like a consolidated rock under stress, fracturing is assumed to be an important mechanism in most mathematical models for in-situ recovery of bitumen by steam injection. Fig. 1 A shows this process when the horizontal fracture is assumed to be the main recovery mechanism. Injected steam and condensate are contained primarily in a thin fracture zone so the fluid accommodated in the fracture will leak off. The process is similar to a linear displacement of oil by hot fluid. With the sand deformation concept, on the other hand, the injected fluid is able to penetrate oil sand through the creation of micro channels. Fig. 1 B shows this process. Since the micro channeling is postulated in the new model, a significant amount of resident fluid, including oil and connate water, will remain around the well without contacting the injected fluid. The extra space required to create the channels may be obtained by overburden heaving. Therefore, overburden movement will control the directional orientation of the channel creation. The preferential directional orientation is likely to be created as a result of preferential overburden movement. preferential overburden movement. Fig. 2 shows the rough dimensions of the pressurized channeling envelope surrounding the well when approximately 10 000 m3 [353,147 cu ft] of cold water equivalent as steam was injected. The shape of the areal extension is determined from the strength of the overburden stresses. SPEJ p. 417


Geophysics ◽  
1937 ◽  
Vol 2 (1) ◽  
pp. 33-54 ◽  
Author(s):  
J. J. Jakosky ◽  
R. H. Hopper

This paper contains the results of detailed research study to determine the factors which govern the electrical conductivities of oil sands and rocks. The experimental work shows the electrical resistivity to be an inverse function of the percentage of conductive water present in any rock type. It was found that the resistivity‐moisture curve of both petroliferous and non‐petroliferous rock are of a general hyperbolic form. For the higher values of moisture content, the curves rapidly approached the conductivity of the electrolyte contained within the rock or oil sands, while for the lower values of moisture content the resistivity values are high and governed by the properties of the rock. Rocks containing soluble salts have critical points on their resistivity‐moisture curves, with the greatest change occurring in the neighborhood of ten per cent moisture content. Rocks containing fresh water have relatively high resistance values which change fairly uniformly with the variations in moisture content. The research work indicates that the presence of oil does not appreciably effect electrical resistance of the rock. Since the resistivity values are dependent upon the electrolytic effect, the work indicates that resistivity values alone are not a reliable criterion for predicting the presence or absence of an oil sand. The work explains further why high electrical resistivity values are not to be expected when applying electrical geophysical methods for mapping subsurface structure.


Geophysics ◽  
1992 ◽  
Vol 57 (7) ◽  
pp. 894-901 ◽  
Author(s):  
Virginia A. Clark

Direct hydrocarbon indicators (DHIs) on seismic sections are commonly thought to be diagnostic only of gas. However, oil sands can also generate DHIs such as bright spots and flat events since oils under in‐situ conditions can contain large amounts of solution gas. This dissolved gas substantially decreases the velocity of sound and the density of the oils as compared to measurements of these properties at surface conditions. Hydrocarbon indicators caused by oil sands are investigated by first measuring the elastic properties of an oil as a function of gas‐oil ratio, next, calculating the elastic properties of additional oil compositions under in‐situ conditions using standard pressure‐volume‐temperature (PVT) measurements, and then calculating the compressional velocity in oil‐saturated rocks for several typical oils using Gaasmann’s equation. The potential for seismic anomalies caused by oil‐saturated rocks is higher than thought because the properties of oil under reservoir conditions can differ significantly from those of surface oils. Specifically: 1) The properties of oil depend on its composition: the higher the API gravity and the gas‐to‐oil ratio (GOR), the lower the density and velocity of sound (adiabatic bulk modulus) and the lower the velocity of a rock saturated with the oil. 2) Calculations of oil‐sand velocities using the in situ properties of oils show that areas having light oils and/or poorly consolidated rocks are the most likely areas in which to encounter oil DHIs. Since overpressured areas can have both poorly consolidated rocks and high GOR oils, they are especially prone to large oil responses.


2006 ◽  
Vol 9 (06) ◽  
pp. 654-663 ◽  
Author(s):  
Jonathan L. Bryan ◽  
An T. Mai ◽  
Florence M. Hum ◽  
Apostolos Kantzas

Summary Low-field nuclear magnetic resonance (NMR) relaxometry has been used successfully to perform estimates of oil and water content in unconsolidated oil-sand samples. This work has intriguing applications in the oil-sands mining and processing industry, in the areas of ore and froth characterization. Studies have been performed on a database of ore and froth samples from the Athabasca region in northern Alberta, Canada. In this paper, new automated algorithms are presented that predict the oil- and water-weight content of oil-sand ores and froths. Suites of real and synthetic samples of bitumen, water, clay, and sand have also been used to investigate the physical interactions of the different parameters on the NMR spectra. Preliminary observations regarding spectral properties indicate that it may be possible in the future to estimate the amount of clay in the samples, based upon shifts in the NMR spectra. NMR estimates of oil and water content are fairly accurate, thus enhancing the possibility of using NMR for oil-sands development and in the oil-sands mining industry. Introduction The oil sands of northern Alberta contain some of the world's largest deposits of heavy oil and bitumen. As our conventional oil reserves continue to decline, these oil sands will be the future of the Canadian oil industry for years to come and will allow Canada to continue to be a world leader in both oil production and technology development. Approximately 19% of these bitumen reserves are found in unconsolidated deposits that lie close enough to the surface that they can be recovered with surface-mining technology (Alberta Energy and Utilities Board 2004). In 2003, this translated to 35% of all heavy-oil and bitumen production (Alberta Energy and Utilities Board 2004), and numerous companies have invested billions of dollars in oil-sands mine-development projects. Furthermore, many in-situ bitumen-recovery options are currently being designed and field tested for recovering oil in deeper formations (Natl. Energy Board 2004). Being able to predict oil properties and fluid saturation in situ and process optimization of bitumen extraction (frothing) is therefore of considerable value to the industry. There are several areas in oil-sands development operations where it is important to have an estimate of the oil, water, and solids content of a given sample. During initial characterization of the reservoir, it is necessary to determine oil and water content with depth and location in the reservoir. Fluid-content determination with logging tools would be beneficial for all reservoir-characterization studies, whether for oil-sands mining or in-situ bitumen recovery. In mining operations, during the processing of the mined oil-sand ore, having information about the oil, water, and solids content during the extraction process will allow for improved process optimization and control. The industry standard for measuring oil, water, and solids content accurately is the Dean-Stark (DS) extraction method (Core Laboratories 1992). This is essentially a distillation procedure, whereby boiling solvent is used to vaporize water and separate the oil from the sand. Oil, water, and solids are separated and their contents measured separately. The problem with DS is that it requires large amounts of solvents and is time consuming. Centrifuge technology is often used for faster process control, but this can be inaccurate because of similar fluid densities and the presence of emulsions. New methods for fast measurements of oil, water, and solids content are needed.


2012 ◽  
Vol 49 (No. 4) ◽  
pp. 125-136 ◽  
Author(s):  
Z. Hlaváčová

Determination of electrical properties is utilized in a wide range of disciplines and industries. A brief compendium of agricultural materials and food electrical properties exploitation is presented in this paper. The measurement of electrical conductivity or resistivity can be utilized at investigation of cell membrane properties on microscopic level. Moreover the electrical conductivity have utilization at the salinity of soils and irrigation water determination. Biological material properties are determined from their leachates too. The conductivity measurement are applied for determination of various characteristics of agricultural materials and food, for example for determination of the frost sensitiveness, of chilling and freezing tolerance, of moisture content, of seeds germination, of mechanical stress, of pasteurization, of other properties of grains, seeds, meat, sugar, milk, wood, soil, fruit and vegetable, infected food, &hellip; The utilization of dielectric properties are also described; for example in agricultural materials and food quality sensing (moisture content, maturity of fruit, freshness of eggs, potential insect control in seeds, radio frequency heating, &hellip;). The classification of permittivity measurement techniques at the low frequencies is mentioned.


1987 ◽  
Vol 109 (2) ◽  
pp. 66-70
Author(s):  
M. A. Abdrabboh ◽  
G. A. Karim

The physical processes that occur typically within an oil sand bed are considered when the bed is subjected to a hot gaseous stream. In this study, the extent of fluid volatilization was obtained from a consideration of the simultaneous heat and mass transfer processes within the oil sands. The resulting system of equations together with the boundary conditions were solved numerically using an implicit finite difference method. The transient fluid concentration and temperature distributions within the oil sand bed were then obtained under a wide range of operating conditions. The resulting theoretical rates of volatilization and temperatures show generally good agreement with corresponding experimental values that were obtained for the purpose.


Author(s):  
W. E. King

A side-entry type, helium-temperature specimen stage that has the capability of in-situ electrical-resistivity measurements has been designed and developed for use in the AEI-EM7 1200-kV electron microscope at Argonne National Laboratory. The electrical-resistivity measurements complement the high-voltage electron microscope (HVEM) to yield a unique opportunity to investigate defect production in metals by electron irradiation over a wide range of defect concentrations.A flow cryostat that uses helium gas as a coolant is employed to attain and maintain any specified temperature between 10 and 300 K. The helium gas coolant eliminates the vibrations that arise from boiling liquid helium and the temperature instabilities due to alternating heat-transfer mechanisms in the two-phase temperature regime (4.215 K). Figure 1 shows a schematic view of the liquid/gaseous helium transfer system. A liquid-gas mixture can be used for fast cooldown. The cold tip of the transfer tube is inserted coincident with the tilt axis of the specimen stage, and the end of the coolant flow tube is positioned without contact within the heat exchanger of the copper specimen block (Fig. 2).


Author(s):  
F. M. Ross ◽  
R. Hull ◽  
D. Bahnck ◽  
J. C. Bean ◽  
L. J. Peticolas ◽  
...  

We describe an investigation of the electrical properties of interfacial dislocations in strained layer heterostructures. We have been measuring both the structural and electrical characteristics of strained layer p-n junction diodes simultaneously in a transmission electron microscope, enabling us to correlate changes in the electrical characteristics of a device with the formation of dislocations.The presence of dislocations within an electronic device is known to degrade the device performance. This degradation is of increasing significance in the design and processing of novel strained layer devices which may require layer thicknesses above the critical thickness (hc), where it is energetically favourable for the layers to relax by the formation of misfit dislocations at the strained interfaces. In order to quantify how device performance is affected when relaxation occurs we have therefore been investigating the electrical properties of dislocations at the p-n junction in Si/GeSi diodes.


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