Arctic vs. North Atlantic water mass exchanges in Fram Strait from Pb isotopes in sedimentsThis article is one of a series of papers published in this Special Issue on the theme Polar Climate Stability Network.

2008 ◽  
Vol 45 (11) ◽  
pp. 1253-1263 ◽  
Author(s):  
Jean Carignan ◽  
Claude Hillaire-Marcel ◽  
Anne de Vernal

Surface sediment samples (n = 10), collected between Spitzbergen and Greenland, and two cores raised east (C04) and west (C16) from Fram Strait were analyzed for their chemical and isotopic (Pb) compositions to trace the source of sediments and water masses exchanging between the Arctic and the North Atlantic oceans. In surface sediments, variable major and trace element concentrations suggest variations in both the mineralogy (carbonate and quartz dilution of other silicate minerals) and source regions of detrital supplies, based on Th/Zr and, to a lesser extent, on Th/U ratios. Each core site shows specific but nearly constant Th/Zr ratios, indicating homogeneous source supplies. At both core sites, Pb concentrations and isotopic compositions display similar patterns: homogeneous low Pb and radiogenic crustal signals below 5–10 cm, contrasting with high Pb and less radiogenic anthropogenic inputs at core-tops. However, the differing pre-anthropogenic Pb isotopic ratios in C04 and C16 confirm the involvement of distinct source supplies east and west of Fram Strait. We suggest that this isotopic specificity is mainly owing to inputs of material carried from northwestern Europe by the North Atlantic water mass and from the Laptev Sea by the Transpolar Drift, respectively. Some material from the Greenland margin and possibly from the North Atlantic Ocean may reach this zone as well. Sediments from the western Arctic are not significantly transported into the Fram Strait area, suggesting that the Canadian and the Eurasian basins remained decoupled, at least during the time span of the cored sediments (∼2000 years).

2021 ◽  
Vol 18 (5) ◽  
pp. 1689-1701
Author(s):  
Jon Olafsson ◽  
Solveig R. Olafsdottir ◽  
Taro Takahashi ◽  
Magnus Danielsen ◽  
Thorarinn S. Arnarson

Abstract. The North Atlantic north of 50∘ N is one of the most intense ocean sink areas for atmospheric CO2 considering the flux per unit area, 0.27 Pg-C yr−1, equivalent to −2.5 mol C m−2 yr−1. The northwest Atlantic Ocean is a region with high anthropogenic carbon inventories. This is on account of processes which sustain CO2 air–sea fluxes, in particular strong seasonal winds, ocean heat loss, deep convective mixing, and CO2 drawdown by primary production. The region is in the northern limb of the global thermohaline circulation, a path for the long-term deep-sea sequestration of carbon dioxide. The surface water masses in the North Atlantic are of contrasting origins and character, with the northward-flowing North Atlantic Drift, a Gulf Stream offspring, on the one hand and on the other hand the cold southward-moving low-salinity Polar and Arctic waters with signatures from Arctic freshwater sources. We have studied by observation the CO2 air–sea flux of the relevant water masses in the vicinity of Iceland in all seasons and in different years. Here we show that the highest ocean CO2 influx is to the Arctic and Polar waters, respectively, -3.8±0.4 and -4.4±0.3 mol C m−2 yr−1. These waters are CO2 undersaturated in all seasons. The Atlantic Water is a weak or neutral sink, near CO2 saturation, after poleward drift from subtropical latitudes. These characteristics of the three water masses are confirmed by data from observations covering 30 years. We relate the Polar Water and Arctic Water persistent undersaturation and CO2 influx to the excess alkalinity derived from Arctic sources. Carbonate chemistry equilibrium calculations clearly indicate that the excess alkalinity may support at least 0.058 Pg-C yr−1, a significant portion of the North Atlantic CO2 sink. The Arctic contribution to the North Atlantic CO2 sink which we reveal was previously unrecognized. However, we point out that there are gaps and conflicts in the knowledge about the Arctic alkalinity and carbonate budgets and that future trends in the North Atlantic CO2 sink are connected to developments in the rapidly warming and changing Arctic. The results we present need to be taken into consideration for the following question: will the North Atlantic continue to absorb CO2 in the future as it has in the past?


2018 ◽  
Author(s):  
Cheryl M. Zurbrick ◽  
Edward A. Boyle ◽  
Rick Kayser ◽  
Matthew K. Reuer ◽  
Jingfeng Wu ◽  
...  

Abstract. During the 2014 GEOVIDE transect, seawater samples were collected for dissolved Pb and Pb isotope analysis. These samples provide a high resolution snapshot of the source regions for the present Pb distribution in the North Atlantic Ocean. Some of these stations were previously occupied for Pb from as early as 1981, and we compare the 2014 data with these older data some of which are reported here for the first time. Lead concentrations were highest in subsurface Mediterranean Water (MW) near the coast of Portugal, which agrees well with other recent observations by the U.S. GEOTRACES program (Noble et al., 2015). The recently formed Labrador Sea Water (LSW) between Greenland and Nova Scotia is much lower in Pb concentration than the older LSW found in the Western European Basin due to decreases in Pb emissions into the atmosphere during the past 20 years. Comparison of North Atlantic data from 1989–2014 shows decreasing Pb concentrations consistent with decreased anthropogenic inputs, active scavenging, and advection/convection. The nearly-homogenous isotopic composition of northern North Atlantic seawater implies that the relative proportions of U.S. and European Pb sources to the ocean have been relatively uniform during the past two decades. Using our measurements in conjunction with emissions inventories, we support the findings of previous atmospheric analyses that up to 50 % of the Pb deposited to the ocean in 2014 was natural, although it remains unclear if that natural dust is from the mid- or high-latitudes.


2008 ◽  
Vol 21 (10) ◽  
pp. 2239-2258 ◽  
Author(s):  
Aixue Hu ◽  
Bette L. Otto-Bliesner ◽  
Gerald A. Meehl ◽  
Weiqing Han ◽  
Carrie Morrill ◽  
...  

Abstract Responses of the thermohaline circulation (THC) to freshwater forcing (hosing) in the subpolar North Atlantic Ocean under present-day and the last glacial maximum (LGM) conditions are investigated using the National Center for Atmospheric Research Community Climate System Model versions 2 and 3. Three sets of simulations are analyzed, with each set including a control run and a freshwater hosing run. The first two sets are under present-day conditions with an open and closed Bering Strait. The third one is under LGM conditions, which has a closed Bering Strait. Results show that the THC nearly collapses in all three hosing runs when the freshwater forcing is turned on. The full recovery of the THC, however, is at least a century earlier in the open Bering Strait run than the closed Bering Strait and LGM runs. This is because the excessive freshwater is diverged almost equally toward north and south from the subpolar North Atlantic when the Bering Strait is open. A significant portion of the freshwater flowing northward into the Arctic exits into the North Pacific via a reversed Bering Strait Throughflow, which accelerates the THC recovery. When the Bering Strait is closed, this Arctic to Pacific transport is absent and freshwater can only be removed through the southern end of the North Atlantic. Together with the surface freshwater excess due to precipitation, evaporation, river runoff, and melting ice in the closed Bering Strait experiments after the hosing, the removal of the excessive freshwater takes longer, and this slows the recovery of the THC. Although the background conditions are quite different between the present-day closed Bering Strait run and the LGM run, the THC responds to the freshwater forcing added in the North Atlantic in a very similar manner.


2012 ◽  
Vol 9 (3) ◽  
pp. 3003-3030
Author(s):  
M. Vázquez-Rodríguez ◽  
F. F. Pérez ◽  
A. Velo ◽  
A. F. Ríos ◽  
H. Mercier

Abstract. The lack of observational pH data has made difficult assessing recent rates of ocean acidification, particularly in the high latitudes. Here we present a time series of high-quality carbon system measurements in the North Atlantic, comprising fourteen cruises spanning over 27 yr (1981–2008) and covering important water mass formation areas like the Irminger and Iceland basins. We provide direct quantification of anthropogenic acidification rates in upper and intermediate North Atlantic waters by removing the natural variability of pH from the observations. Bottle data were normalised to basin-average conditions using climatological data and further condensed into averages per water mass and year to examine the temporal trends. The highest acidification rates of all inspected water masses were associated with surface waters in the Irminger Sea (−0.0018 ± 0.0001 yr−1) and the Iceland Basin (−0.0012 ± 0.0002 yr−1) and, unexpectedly, with Labrador Seawater (LSW) which experienced an unprecedented pH drop of −0.0015 ± 0.001 yr−1. The latter stems from the formation by deep convection and the rapid propagation in the North Atlantic subpolar gyre of this well-ventilated water mass. The high concentrations of anthropogenic CO2 are effectively transported from the surface into intermediate waters faster than via downward diffusion, thus accelerating the acidification rates of LSW. An extrapolation of the observed lineal trends of acidification suggests that the pH of LSW could drop 0.45 units with respect to pre-industrial levels by the time atmospheric CO2 concentrations double the present ones.


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