THE OXIDATION, IGNITION, AND DETONATION OF FUEL VAPORS AND GASES: XIV. THE CAUSE OF THE EFFECT OF HYDROGEN SULPHIDE TO REDUCE THE COMPRESSION RATIOS AT WHICH FUEL GASES CAN BE USED IN SPARK IGNITION ENGINES
Experimental results are given for trials of the C.F.R. engine at 900 r.p.m. and 12: 1 C.R. on Toronto town gas alone and with an addition of hydrogen sulphide. The sulphide led to such severe preignition that measurements of power were impossible except for very weak or very rich mixtures. The former included the 50% weak mixture for which thermal efficiency is a maximum. The sulphide was then of beneficial effect, a maximum value of 44% for indicated thermal efficiency being obtained as compared to a maximum of 42.5% without it. The experimental results are interpreted in the light of combustion tube experiments showing that hydrogen in mixtures with air is not ignited by red hot surfaces on which it is oxidized with sufficient rapidity to steam, but that ignition occurs at relatively low temperatures if the surface reaction is inhibited by hydrogen sulphide. The conclusion is that fuel gases containing hydrogen in large proportion can be used for full power engine operation at compression ratios even higher than 12: 1 if the oxidation of the hydrogen in part to steam, on the hot surfaces in the combustion chamber, is not inhibited by the poisoning effect of the hydrogen sulphide commonly present in the gases.