Determination of K shell absorption parameters for some lanthanides using the X-ray attenuation method

2015 ◽  
Vol 93 (12) ◽  
pp. 1532-1540 ◽  
Author(s):  
F. Akman ◽  
R. Durak ◽  
M.R. Kaçal
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Experimental Results ◽  
Secondary Source ◽  
X Rays ◽  
Strength Parameters ◽  
X Ray ◽  
Total Attenuation ◽  
First Time

The total attenuation cross section at the K edge, absorption jump ratio, jump factor, Davisson–Kirchner ratio, and oscillator strength parameters for the K shell were determined by measuring the total attenuation cross sections around the K edge for Pr, Nd2O3, and Sm. The measurements were performed in a secondary excitation geometry using the Kα2, Kα1, Kβ1, and Kβ2 X-rays (in the region from 31.817 to 55.293 keV) from different secondary source targets excited by the 59.54 keV γ-photons from an 241Am annular source. It is the first time that the Davisson–Kirchner ratio values have been determined for present samples. The experimental results were compared with the theoretically calculated and other available experimental results.

Destruction of C2H4O2 isomers in ice-phase by X-rays: Implication on the abundance of acetic acid and methyl formate in the interstellar medium

2017 ◽  
Vol 13 (S332) ◽  
pp. 418-424
Author(s):  
Marina G. Rachid ◽  
K. Faquine ◽  
S. Pilling
Keyword(s):  
Acetic Acid ◽  
Cross Sections ◽  
Methyl Formate ◽  
X Rays ◽  
Formation Cross Section ◽  
X Ray ◽  
Synchrotron Light ◽  
The Difference ◽  
Astrophysical Ices

AbstractC2H4O2 isomers, methyl formate (HCOOCH3), acetic acid (CH3COOH) and glycoaldehyde (HOCH2CHO), have been detected in a lot of sources in ISM. However, their abundances are very different, with methyl formate much more abundant than the other two isomers. This fact may be related to the different destruction by ionizing radiation of these molecules. The goal of this work is experimentally study the photodissociation processes of methyl formate and acetic acid ices when exposed to broadband soft X-ray from 6 up to 2000 eV. The experiments were performed coupled to the SGM beamline in the Brazilian Synchrotron Light Source (LNLS/CNPEM) at Campinas, Brazil. The simulated astrophysical ices (12K) were monitored throughout the experiment using infrared vibrational spectroscopy. The analysis of processed ices allowed the determination of the effective destruction cross sections of the parent molecules as well as the effective formation cross section of daughter molecular species. The relative abundance between acetic acid and methyl formate (NCH3COOH/NHCOOCH3) in different astronomical scenarios and their column density evolution in the presence of X-rays were calculated and our results suggests that such radiation field can be one of the factors that explain the difference in the isomers C2H4O2 abundances. We also quantified the daugther species after the establishment of a chemical equilibrium in the samples.

Photon-Induced L-Shell X-Ray Production Cross Sections for Lanthanides at 59.54 keV

2017 ◽  
Vol 890 ◽  
pp. 223-226 ◽  
Author(s):  
Rıdvan Durak ◽  
Ferdi Akman ◽  
Abdulhalik Karabulut
Keyword(s):  
High Resolution ◽  
Cross Sections ◽  
Production Cross ◽  
Theoretical Data ◽  
Experimental Results ◽  
X Rays ◽  
X Ray ◽  
Reflection Geometry ◽  
Experimental Values ◽  
Annular Source

The Ll, Lα and Lβ X-ray production cross sections for Pr, Nd, Sm, Eu, Gd and Tb elements were determined using a reflection geometry. The excitation was performed with a 241Am radioactive annular source and the L X-rays emitted from targets were counted with a high-resolution Si (Li) detector. The experimental values were compared with other available experimental results and theoretical data. An agreement is observed between the measured and other experimental results or theoretical data.

Quantitative Determimatioh of Sulfur, Chlorine, Potassium, Calcium, Scandium and Titanium in Aqueous Solutions by Radioisotopic Excited Fluorescent Spectrometer and by Conventional X-Ray Spectrometer

1970 ◽  
Vol 14 ◽  
pp. 102-126 ◽  
Author(s):  
Frank L. Chan ◽  
W. Barclay Jones
Keyword(s):  
Particle Size ◽  
Aqueous Solutions ◽  
Experimental Results ◽  
The Other ◽  
X Rays ◽  
Helium Atmosphere ◽  
X Ray ◽  
Effect Of Particle Size ◽  
The One

AbstractAn x-ray spectrometer with experimental results is herewith described using a radiosotope source Fe55 having a halflife of 2.6 years. As a result of the disintegration, the managanese x-rays are capable of exciting fluorescent x-rays of such elements as sulfur, chlorine, potassium, calcium, scandium and titanium in aqueous solutions. These elements with the Ka wavelengths ranging from 5.3729 Å to 2.7496 Å may be designated as between the very soft x-rays on the one hand and the hard x-rays on the other. The x-ray spectrometer presently described has achieved a resolution of 136 ev, FWHM.Simultaneously, these elements have also been quantitatively determined by conventional x-ray fluorescent spectrometers. Since one of the spectrometers is designed to operate in vacuum as well as in helium or air, determination of sulfur, potassium and calcium were carried out in vacuum. Determination of chlorine was carried out in a helium atmosphere, Calcium, scandium and titanium were determined in air with an air-path spectrometer.In the present study aqueous solutions containing these elements were used. The use of aqueous solutions has the inherent advantages of being homogeneous and free from effect of particle size.

Angular variations of K and L X-ray fluorescence cross sections for some lanthanides

2008 ◽  
Vol 86 (2) ◽  
pp. 361-367 ◽  
Author(s):  
I Han ◽  
M Şahin ◽  
L Demir
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Emission Angle ◽  
X Rays ◽  
X Ray ◽  
Isotropic Distribution ◽  
Fluorescence Cross Section ◽  
Intensity Ratios ◽  
Experimental Values ◽  
Photon Source

Kα, Kβ, Lα, and Lβ X-ray fluorescence cross sections for lanthanides in the atomic range 62 ≤ Z ≤ 68 (Sm, Eu, Gd Tb, Dy, Ho, and Er) were simultaneously measured by 59.54 keV incident photon energy at five angles ranging from 120° to 160°. The measurements were performed using an Am-241 radioisotope as the photon source and a Si(Li) detector. The Lα X-ray fluorescence cross section (σLα) was found to decrease with increasing emission angle and showed an anisotropic distribution of Lα X-rays. Kα, Kβ, and Lβ X-ray fluorescence cross sections (σKα, σKβ, and σLβ) were observed to be angle-independent and showed an isotropic distribution of Kα, Kβ, and Lβ X-rays. The Kα and Kβ X-rays originate from filling of the K shell (J = 1/2) vacancies, Lβ X-rays from filling of the L1 and L2 (J = 1/2) subshell vacancies, and Lα X-rays from filling of the L3 subshell (J = 3/2) vacancy. The fluorescent X-rays originating from the vacancy states with J = 1/2 are isotropic and unpolarized, but fluorescent X-rays originating from the vacancy states with J > 1/2 are anisotropic and polarized. Thus, the atomic inner shells vacancy states with J > 1/2 are aligned whereas vacancy states with J = 1/2 are not aligned. Lα fluorescence X-rays have an anisotropic distribution, while Kα, Kβ, and Lβ fluorescence X-rays have isotropic distribution. Furthermore, the IKβ/IKα, ILα/IKα}, ILβ/IKα, and ILβ/ILα intensity ratios for the elements under investigation were determined. The experimental cross sections and intensity ratios for Kα, Kβ, Lα, and Lβ fluorescence X-rays were also determined, and these experimental values were compared with our calculated theoretical values.PACS Nos.: 32.30.Rj, 32.80.Cy

Ar K X-ray production in slow, highly charged Ar q+(q = 8–18) + Ar collisions

2002 ◽  
Vol 80 (12) ◽  
pp. 1579-1589 ◽  
Author(s):  
H Tawara ◽  
P Richard
Keyword(s):  
Cross Sections ◽  
X Rays ◽  
Enhanced Fluorescence ◽  
Energy Correlation ◽  
X Ray ◽  
Ion Collisions ◽  
Wide Range ◽  
First Time ◽  
Rotational Coupling ◽  
Shell Vacancy

In the present work, mechanisms of Ar K X-ray production have been investigated under low-energy Arq+ + Ar collisions in a wide range of the ion-charge states. Ar K X-rays have been observed as a function of the collision energy over (0.75–3.75)q keV/u and of the charge state over q = 8–16 of projectile Arq+ ions. If the L-shell vacancies become available (q = 9), Ar K X-ray yields are found to be enhanced roughly three orders of magnitude, compared with Ar8+ ions with no L-shell vacancy; to show some threshold; and to tend to quickly saturate at higher collision energies. The present analysis, based on the energy correlation diagrams of the quasi-molecules, suggests that Ar K X-rays originate entirely from target Ar atoms through promotion via the rotational coupling between 2pσ –2pπ molecular orbitals. Furthermore, the observed cross sections are found to increase nonlinearly with the projectile Arq+ ion charge q (q = 9). This can be understood because of the combined effects of two contributions: (i) the increased number of the L-shell vacancies of projectile Arq+ ions and (ii) the enhanced fluorescence yields of target Ar atom. In addition, Ar K X-rays have been observed under 2.5q keV/u Ar17+ and Ar18+ + Ar collisions and found to originate from the decay of K-shell vacancies initially present in the projectile Ar ions through electron capture into their highly excited states, followed by cascade down to the ground states. For the first time, though very weak, the X-rays due to the two-electron–one-photon transition, namely, K αα lines, have also been observed in bare Ar18+ ion collisions. PACS Nos.: 34.70+e, 32.80Rm

X-RAY PRODUCTION, INNER SHELL IONIZATION AND READING’S THEOREM IN ION · ATOM COLLISIONS

1992 ◽  
Vol 02 (03) ◽  
pp. 197-209
Author(s):  
KEIZO ISHII
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Production Cross ◽  
X Rays ◽  
Ionization Cross ◽  
Heavy Charged Particles ◽  
X Ray ◽  
Inner Shell Ionization ◽  
Ionization Cross Sections ◽  
Shell Ionization

When a solid or gaseous target is bombarded with heavy charged particles, inner shell electrons of target atoms are ionized and characteristic x rays are produced. We can easily observe these x rays with a Si(Li) detector and derive inner-shell ionization cross section from the x-ray production cross sections. In this paper, we make a review of x-ray production, inner shell ionization and Reading’s theorem in light ion·atom collisions. This theorem is one of the most important ones in the ion·atom collision physics and permits precise discussion on comparison between experimental inner-shell ionization cross sections obtained with a Si(Li) detector and the calculations based on usual theories where the incident particle is assumed to interact with only one electron in an atom and the presence of other electrons is ignored.

A Secondary-Source, Energy-Dispersive X-Ray Spectrometer and its Application to Quantitative Analytical Chemistry

1973 ◽  
Vol 17 ◽  
pp. 571-583
Author(s):  
R. P. Larsen ◽  
J. O. Karttunen
Keyword(s):  
Background Radiation ◽  
Energy Dispersive ◽  
Excitation Source ◽  
Secondary Source ◽  
X Rays ◽  
X Ray ◽  
Secondary Sources ◽  
The Individual ◽  
Detection Instrument

AbstractAn energy-dispersive X-ray spectrometer that (1) uses as the primary excitation source the power supply and tungsten X-ray tube from a conventional crystal spectrometer (General Electric XRD-6) and (2) uses as the secondary excitation source elemental metal foils that are readily interchangeable has been built and operated. The use of an X-ray tube with a high-voltage capability, 75 kilovolts max, enables the determination of elements with atomic numbers as high as 66 (terbium) to be based on the K series of X-rays; the highpower capability, 3.7 kilowatts max, enables a particularly intense beam of X-rays to be generated by the secondary source and hence, provides a particularly high detection capability for trace elements in a sample. An instrument that uses interchangeable secondary sources to irradiate the samples has several advantages over those instruments in which excitation is accomplished by direct irradiation with an X-ray tube: (1) the background radiation in the energy range where the X-rays of interest are measured is several orders of magnitude lower and is very uniform and (2) the energy of the excitation radiation can be closely matched to the absorption edges of the elements of interest in the sample.In the application of the instrument, particular emphasis has been placed on the development of tectmiques that will enable an energy-dispersive X-ray spectrometer to be used as the detection instrument for quantitative elemental analysis. Methods for the determination of the individual rare earths, plutonium and uranium at the microgram level with an accuracy of ± 1% are outlined and for the determination of plutonium and uranium at the milligram level with an accuracy of ± 0.1% are proposed.

Measurement of Li X-ray fluorescence production cross sections and intensity ratios of some elements at 59.54 keV

2015 ◽  
Vol 93 (10) ◽  
pp. 1057-1066 ◽  
Author(s):  
F. Akman ◽  
R. Durak ◽  
M.R. Kaçal ◽  
M.F. Turhan
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Reasonable Agreement ◽  
Production Cross ◽  
Radioactive Source ◽  
Experimental Results ◽  
X Ray ◽  
Intensity Ratios ◽  
Theoretical Results ◽  
Excitation Geometry

The Li (i = l, α, β, γ) X-ray production cross section and Lα/Ll, Lα/Lβ, Lα/Lγ, Ll/Lβ, Ll/Lγ, and Lβ/Lγ intensity ratio values for Yb, Ta, W, Hg, Tl, Pb, Bi, Th, and U have been determined using an excitation geometry at 59.54 keV incident photon energy. The measurements were performed using an Am-241 annular radioactive source and a high resolution Si(Li) detector. The experimental results of Li X-ray production cross sections and intensity ratios were compared with three different theoretical results and other available experimental results in the literature. Reasonable agreement is typically observed between the present and theoretical results.

Application of Multilayer Structures to the Determination of Optical Constants in the X-Ray, Soft X-Ray and Extreme Ultra Violet Spectral Ranges

1988 ◽  
Vol 143 ◽  
Author(s):  
Troy W. Barbee
Keyword(s):  
Cross Sections ◽  
Optical Constants ◽  
Extreme Ultraviolet ◽  
Ultra Violet ◽  
Multilayer Structures ◽  
X Rays ◽  
X Ray ◽  
Spectral Ranges ◽  
Scattering Cross Sections

AbstractThe dispersion of x-rays (XR), soft x-rays (SXR) and extreme ultraviolet (EUV) light by multilayer structures is dependent on the scattering and absorption cross-sections of the elements used to synthesize the multilayer. In this paper it will be shown that this dependence provides a means for the accurate experimental determination of the optical constants of the multilayer constituents. Two specific approaches will be presented and discussed. First, it will be shown that detailed analysis of the energy dependence of the reflectivity of a simple depth periodic multilayer allows the unfolding of the optical constants. Secondly a new optic structure, the multilayer diffraction grating, will be described and it will be demonstrated that such combined microstructure optics allow the scattering cross-sections of the multilayer constituents to be accurately determined over broad spectral ranges.

scholarly journals Determination of the mass attenuation coefficient for Aluminum element using (Cu,Mo) X-rays tubes

2019 ◽  
Vol 24 (1) ◽  
pp. 82
Author(s):  
Ahmad Mohamed Kheder ◽  
Muhsin Hasan Ali
Keyword(s):  
Experimental Data ◽  
Attenuation Coefficient ◽  
Cross Sections ◽  
Mass Attenuation Coefficient ◽  
X Rays ◽  
Attenuation Coefficients ◽  
X Ray ◽  
Mass Attenuation Coefficients ◽  
Mass Attenuation

In this study the value of linear  and mass  attenuation coefficients of Aluminum element (Al) were determinated by using x-ray Cu-tube of energies CuKα (8.048) KeV, CuKβ (8.906) KeV, and Mo-tube of energies MoKα (17.480) KeV and MoKβ (19.609) KeV.the voltage between the two electrodes are up to 35 KV.The measured  values are compared with other experimental data showing a general agreement within a precision of 0.2% - 0.8%. The mass attenuation cross-sections were thus derived and compared with other experimental data available on database of x-ray attenuation cross-sections. The agreement is always within ±7%.   http://dx.doi.org/10.25130/tjps.24.2019.013

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