Fifty years of the closo-decaborate anion chemistry

2010 ◽  
Vol 75 (11) ◽  
pp. 1149-1199 ◽  
Author(s):  
Igor B. Sivaev ◽  
Alexander V. Prikaznov ◽  
Daoud Naoufal
Keyword(s):  
Oxidation Reactions ◽  
Hydrogen Atoms ◽  
Main Attention ◽  
First Report ◽  
General Stability ◽  
Closo Decaborate Anion

The review covers the fifty-year period of chemistry of the closo-decaborate anion [B10H10]2– from the first report by Hawthorne and Pitochelli. The main attention is paid to reactions of substitution of various atoms and groups for hydrogen atoms. The general stability of the closo-decaborate cage, including its protonation, cage-opening and cage oxidation reactions, is considered as well. A review with 242 references.

Complexation and exopolyhedral substitution of the terminal hydrogen atoms in the decahydro-closo-decaborate anion in the presence of cobalt(II)

Polyhedron ◽  
2019 ◽  
Vol 162 ◽  
pp. 65-70 ◽  
Author(s):  
Varvara V. Avdeeva ◽  
Irina N. Polyakova ◽  
Andrei V. Churakov ◽  
Anna V. Vologzhanina ◽  
Elena A. Malinina ◽  
...  
Keyword(s):  
Hydrogen Atoms ◽  
Closo Decaborate Anion

scholarly journals Plasmonic O2 Dissociation and Spillover Expedite Selective Oxidation of Primary C–H Bonds

2021 ◽  
Author(s):  
Hao Li ◽  
Huan Shang ◽  
Fuze Jiang ◽  
Xingzhong Zhu ◽  
Qifeng Ruan ◽  
...  
Keyword(s):  
Chemical Synthesis ◽  
Selective Oxidation ◽  
Environmental Remediation ◽  
Oxidation Reactions ◽  
O2 Activation ◽  
First Report ◽  
O2 Dissociation

Manipulating O2 activation via nanosynthetic chemistry is critical in many oxidation reactions central to environmental remediation and chemical synthesis. Based on a carefully-designed plasmonic Ru/TiO2–x catalyst, we first report a...

A fossil Aspergillus from Eocene Dominican amber

1988 ◽  
Vol 62 (01) ◽  
pp. 141-143 ◽  
Author(s):  
Gerard M. Thomas ◽  
George O. Poinar
Keyword(s):  
Dominican Republic ◽  
Fossil Species ◽  
First Report ◽  
Dominican Amber ◽  
Eocene Amber

A sporulating Aspergillus is described from a piece of Eocene amber originating from the Dominican Republic. The Aspergillus most closely resembles a form of the white spored phase of Aspergillus janus Raper and Thom. This is the first report of a fossil species of Aspergillus.

Remarks on the diffuse interstellar lines

1967 ◽  
Vol 31 ◽  
pp. 91-93 ◽  
Author(s):  
G. Herzberg
Keyword(s):  
Hydrogen Atoms ◽  
Interstellar Gas

It is suggested that the diffuse interstellar lines are produced in the interstellar gas by molecules consisting of a few hydrogen atoms and one other atom, such as CH4+ or NH4. Diffuseness of the lines is assumed to result from predissociation of these molecules.

1392: First Report of a New Transurethral Detaching Prostatectomy of the Prostate (TUDP)

2005 ◽  
Vol 173 (4S) ◽  
pp. 377-378
Author(s):  
Yasunori Hiraoka ◽  
Kazuhiko Yamada ◽  
Yuji Shimizu ◽  
Hiroyuki Abe
Keyword(s):  
First Report
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