Complexation and exopolyhedral substitution of the terminal hydrogen atoms in the decahydro-closo-decaborate anion in the presence of cobalt(II)

Polyhedron ◽  
2019 ◽  
Vol 162 ◽  
pp. 65-70 ◽  
Author(s):  
Varvara V. Avdeeva ◽  
Irina N. Polyakova ◽  
Andrei V. Churakov ◽  
Anna V. Vologzhanina ◽  
Elena A. Malinina ◽  
...  
Keyword(s):  
Hydrogen Atoms ◽  
Closo Decaborate Anion

Fifty years of the closo-decaborate anion chemistry

2010 ◽  
Vol 75 (11) ◽  
pp. 1149-1199 ◽  
Author(s):  
Igor B. Sivaev ◽  
Alexander V. Prikaznov ◽  
Daoud Naoufal
Keyword(s):  
Oxidation Reactions ◽  
Hydrogen Atoms ◽  
Main Attention ◽  
First Report ◽  
General Stability ◽  
Closo Decaborate Anion

The review covers the fifty-year period of chemistry of the closo-decaborate anion [B10H10]2– from the first report by Hawthorne and Pitochelli. The main attention is paid to reactions of substitution of various atoms and groups for hydrogen atoms. The general stability of the closo-decaborate cage, including its protonation, cage-opening and cage oxidation reactions, is considered as well. A review with 242 references.

Remarks on the diffuse interstellar lines

1967 ◽  
Vol 31 ◽  
pp. 91-93 ◽  
Author(s):  
G. Herzberg
Keyword(s):  
Hydrogen Atoms ◽  
Interstellar Gas

It is suggested that the diffuse interstellar lines are produced in the interstellar gas by molecules consisting of a few hydrogen atoms and one other atom, such as CH4+ or NH4. Diffuseness of the lines is assumed to result from predissociation of these molecules.

SURFACE PLASMA SOURCE OF HYDROGEN ATOMS WITH AN ENERGY OF HUNDREDS eV

1979 ◽  
Vol 40 (C7) ◽  
pp. C7-479-C7-480 ◽  
Author(s):  
V. G. Dudnikov ◽  
G. I. Fiksel'
Keyword(s):  
Plasma Source ◽  
Surface Plasma ◽  
Hydrogen Atoms

H NMR Evidence for a Change in The Local Hydrogen Environment of Sites Associated with the Staebler-Wronski Effect in a-Si:H

2002 ◽  
Vol 715 ◽  
Author(s):  
T. Su ◽  
Robin Plachy ◽  
P. C. Taylor ◽  
S. Stone ◽  
G. Ganguly ◽  
...  
Keyword(s):  
Line Shape ◽  
Defect Density ◽  
Hydrogen Atoms ◽  
Hydrogen Environment ◽  
H Nmr ◽  
Line Shapes ◽  
Different Temperatures ◽  
Staebler Wronski Effect

AbstractWe study the H NMR line shapes of a sample of a-Si:H under several conditions: 1) as grown, 2) light-soaked for 600 hours, and 3) light-soaked followed by annealing at different temperatures. At T = 7 K, the NMR line shape of the sample after light soaking exhibits an additional doublet compared to that of the sample as-grown. This doublet is an indication of a closely separated hydrogen pair. The distance between the two hydrogen atoms is estimated to be about (2.3 ± 0.2) Å. The concentration of these hydrogen sites is estimated to be between 1017 and 1018 cm-3 consistent with ESR measurements of the defect density after light soaking. This doublet disappears after the sample is annealed at 200°C for 4 hours.

Formation of surface layer of hydrogen in pure aluminum

2019 ◽  
Vol 484 (1) ◽  
pp. 56-60
Author(s):  
D. A. Indejtsev ◽  
E. V. Osipova
Keyword(s):  
Surface Layer ◽  
Hydrogen Atom ◽  
Ab Initio ◽  
Pure Aluminum ◽  
Hydrogen Atoms ◽  
Energy Characteristics ◽  
Aluminum Crystal

Hydrogen atom behavior in pure aluminum is described by ab initio modelling. All main energy characteristics of the system consisting of hydrogen atoms in a periodic aluminum crystal are found.

The Influence of Hydrogen atoms on the Performance of Radial Distribution Function Based Descriptors in the Chemoinformatic Studies of HIV-1 Prote-ase Complexes with Inhibitors.

2020 ◽  
Vol 17 ◽  
Author(s):  
Jurica Novak ◽  
Maria A. Grishina ◽  
Vladimir A. Potemkin
Keyword(s):  
Distribution Function ◽  
Radial Distribution Function ◽  
Radial Distribution ◽  
Current Model ◽  
Direct Interaction ◽  
Hydroxyl Group ◽  
Linear Regression Method ◽  
Hydrogen Atoms ◽  
Protease Enzyme ◽  
Hiv 1

: In this letter the newly introduced approach based on the radial distribution function (RDF) weighted by the number of va-lence shell electrons is applied for a series of HIV-1 protease enzyme and its complexes with inhibitors to evaluate the influ-ence of hydrogen atoms on the performance of the model. The multiple linear regression method was used for the selection of the relevant descriptors. Two groups of residues having dominant contribution to the RDF descriptor are identified as relevant for the inhibition. In the first group are residues like Arg8, Asp25, Thr26, Gly27 and Asp29, which establish direct interaction with the inhibitor, while the second group consists of the amino acids at the interface of the two homodimer sub-units or with the solvent. The crucial motif pointed out by our approach as the most important for inhibition of the enzyme’s activity and present in all inhibitors is hydroxyl group that establish hydrogen bond with Asp25 side chain. Additionally, the comparison to the model without hydrogen showed that both models are of similar quality, but the downside of the current model is the need for the determination of residues’ protonation states.

Features of Formation of Mononuclear and Binuclear Copper(II) Complexes with 2,2'-Bipyridyl and closo-Decaborate Anion

2020 ◽  
Vol 65 (9) ◽  
pp. 1343-1350
Author(s):  
E. A. Malinina ◽  
V. V. Avdeeva ◽  
S. E. Korolenko ◽  
S. E. Nefedov ◽  
L. V. Goeva ◽  
...  
Keyword(s):  
Binuclear Copper ◽  
Closo Decaborate Anion
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