Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst

Zuzana Dobrovolná; Libor Červený

doi:10.1135/cccc19971497

Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19971497 ◽

1997 ◽

Vol 62 (9) ◽

pp. 1497-1502 ◽

Cited By ~ 6

Author(s):

Zuzana Dobrovolná ◽

Libor Červený

Keyword(s):

Palladium Catalyst ◽

Hydrogen Transfer ◽

Ammonium Formate ◽

Unsaturated Hydrocarbons ◽

Cyclic Diene ◽

Competitive Hydrogenation ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer

Competitive hydrogenation of alkenes (cyclohexene, hex-1-ene, hept-1-ene, oct-1-ene) and dienes (octa-1,7-diene, cyclohexa-1,3-diene) was carried out by catalytic hydrogen transfer from ammonium formate on palladium in methanol. The adsorptivity and reactivity of the hydrocarbons decreased in the series: cyclic diene > linear diene > linear 1-alkene > cyclic alkene.

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ChemInform Abstract: Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formate on a Palladium Catalyst

ChemInform ◽

10.1002/chin.199809045 ◽

2010 ◽

Vol 29 (9) ◽

pp. no-no

Author(s):

Z. DOBROVOLNA ◽

L. CERVENY

Keyword(s):

Palladium Catalyst ◽

Hydrogen Transfer ◽

Ammonium Formate ◽

Unsaturated Hydrocarbons ◽

Competitive Hydrogenation

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A Facile Synthesis of α-Amino Esters via Reduction of α-Nitro Esters Using Ammonium Formate as a Catalytic Hydrogen Transfer Agent

Synthesis ◽

10.1055/s-1986-31497 ◽

1986 ◽

Vol 1986 (02) ◽

pp. 133-135 ◽

Cited By ~ 30

Author(s):

Siya Ram ◽

Richard E. Ehrenkaufer

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Facile Synthesis ◽

Amino Esters ◽

Catalytic Hydrogen ◽

Nitro Esters ◽

Catalytic Hydrogen Transfer

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Rapid debenzylation of N-benzylamino derivatives to amino-derivatives using ammonium formate as catalytic hydrogen transfer agent

Tetrahedron Letters ◽

10.1016/s0040-4039(00)95769-1 ◽

1987 ◽

Vol 28 (5) ◽

pp. 515-516 ◽

Cited By ~ 90

Author(s):

Siya Ram ◽

Leonard D Spicer

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Catalytic Hydrogen ◽

Amino Derivatives ◽

Catalytic Hydrogen Transfer

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ChemInform Abstract: A Facile Synthesis of α-Amino Esters via Reduction of α-Nitro Esters Using Ammonium Formate as a Catalytic Hydrogen Transfer Agent.

Chemischer Informationsdienst ◽

10.1002/chin.198625171 ◽

1986 ◽

Vol 17 (25) ◽

Author(s):

S. RAM ◽

R. E. EHRENKAUFER

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Facile Synthesis ◽

Amino Esters ◽

Catalytic Hydrogen ◽

Nitro Esters ◽

Catalytic Hydrogen Transfer

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Ammonium Formate/Palladium on Carbon: A Versatile System for Catalytic Hydrogen Transfer Reductions of Carbon-Carbon Double Bonds

Synthesis ◽

10.1055/s-2003-43301 ◽

2003 ◽

pp. 2594-2594

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Double Bonds ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer ◽

Palladium On Carbon

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ChemInform Abstract: A GENERAL PROCEDURE FOR MILD AND RAPID REDUCTION OF ALIPHATIC AND AROMATIC NITRO COMPOUNDS USING AMMONIUM FORMATE AS A CATALYTIC HYDROGEN TRANSFER AGENT

Chemischer Informationsdienst ◽

10.1002/chin.198503128 ◽

1985 ◽

Vol 16 (3) ◽

Author(s):

S. RAM ◽

R. E. EHRENKAUFER

Keyword(s):

Hydrogen Transfer ◽

General Procedure ◽

Nitro Compounds ◽

Ammonium Formate ◽

Rapid Reduction ◽

Aromatic Nitro Compounds ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer ◽

Aromatic Nitro

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Ammonium Formate in Organic Synthesis: A Versatile Agent in Catalytic Hydrogen Transfer Reductions

Synthesis ◽

10.1055/s-1988-27478 ◽

1988 ◽

Vol 1988 (02) ◽

pp. 91-95 ◽

Cited By ~ 160

Author(s):

Siya Ram ◽

Richard E. Ehrenkaufer

Keyword(s):

Organic Synthesis ◽

Hydrogen Transfer ◽

Ammonium Formate ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer

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ChemInform Abstract: Reduction of Aldehydes and Ketones to Methylene Derivatives Using Ammonium Formate as a Catalytic Hydrogen Transfer Agent.

ChemInform ◽

10.1002/chin.198902103 ◽

1989 ◽

Vol 20 (2) ◽

Author(s):

S. RAM ◽

L. D. SPICER

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Aldehydes And Ketones ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer

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Ammonium Formate/Palladium on Carbon: A Versatile System for Catalytic Hydrogen Transfer Reductions of Carbon—Carbon Double Bonds.

ChemInform ◽

10.1002/chin.200406035 ◽

2004 ◽

Vol 35 (6) ◽

Author(s):

Zdzislaw Paryzek ◽

Hanna Koenig ◽

Bartlomiej Tabaczka

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Double Bonds ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer ◽

Palladium On Carbon

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Ammonium Formate/Palladium on Carbon: A Versatile System for Catalytic Hydrogen Transfer Reductions of Carbon-Carbon Double Bonds

Synthesis ◽

10.1055/s-2003-41024 ◽

2003 ◽

pp. 2023-2026 ◽

Cited By ~ 31

Author(s):

Zdzisław Paryzek ◽

Hanna Koenig ◽

Bartłomiej Tabaczka

Keyword(s):

Hydrogen Transfer ◽

Ammonium Formate ◽

Double Bonds ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer ◽

Palladium On Carbon

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