scholarly journals Ammonium Formate/Palladium on Carbon: A Versatile System for Catalytic Hydrogen Transfer Reductions of Carbon-Carbon Double Bonds

Synthesis ◽  
2003 ◽  
pp. 2594-2594
Keyword(s):  
Hydrogen Transfer ◽  
Ammonium Formate ◽  
Double Bonds ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Transfer ◽  
Palladium On Carbon

Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst

1997 ◽  
Vol 62 (9) ◽  
pp. 1497-1502 ◽  
Author(s):  
Zuzana Dobrovolná ◽  
Libor Červený
Keyword(s):  
Palladium Catalyst ◽  
Hydrogen Transfer ◽  
Ammonium Formate ◽  
Unsaturated Hydrocarbons ◽  
Cyclic Diene ◽  
Competitive Hydrogenation ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Transfer

Competitive hydrogenation of alkenes (cyclohexene, hex-1-ene, hept-1-ene, oct-1-ene) and dienes (octa-1,7-diene, cyclohexa-1,3-diene) was carried out by catalytic hydrogen transfer from ammonium formate on palladium in methanol. The adsorptivity and reactivity of the hydrocarbons decreased in the series: cyclic diene > linear diene > linear 1-alkene > cyclic alkene.

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