Reaction of Ester Ethoxycarbonylhydrazones with Aliphatic Diamines

1995 ◽  
Vol 60 (5) ◽  
pp. 903-909 ◽  
Author(s):  
Aykut A. Ikizler ◽  
Kemal Sancak
Keyword(s):  
Nmr Spectra ◽  
H Nmr ◽  
Elemental Analyses ◽  
Aliphatic Diamines

Reaction of esters of (N-ethoxycarbonyl)alkanehydrazonic acids with aliphatic diamines were prepared α,ω-bis(3-alkyl-4,5-dihydro-1H -1,2,4-triazol-5- one-4-yl)alkanes. All compounds were characterized by elemental analyses, IR and 1H NMR spectra.

scholarly journals Metallkomplexe mit Tetrapyrrol-Liganden, XXXVIII [1]. Zur Kenntnis der Alkyl- und Arylimidovanadium(IV)-Porphyrine / Metal Complexes with Tetrapyrrole Ligands, XXXVIII [1]. On the Knowledge of Alkyl- and Arylimidovanadium(IV) Porphyrins

1985 ◽  
Vol 40 (10) ◽  
pp. 1362-1370 ◽  
Author(s):  
Johann W. Buchler ◽  
Stefan Pfeifer
Keyword(s):  
Mass Spectra ◽  
Nmr Spectra ◽  
Primary Amines ◽  
Reactive Intermediate ◽  
H Nmr ◽  
Vanadyl Complex ◽  
Elemental Analyses ◽  
Paramagnetic Metal ◽  
Paramagnetic Complexes ◽  
Proton Resonances

A series of novel alkyl or aryiimidovanadium(IV) 5,10,15,20-tetra(p-tolyl)porphyrinates, VNR(TTP) (4a-4g), is described. They are obtained from the vanadyl complex, VO(TTP) (2a) via the reactive intermediate VCl2(TTP) (3b) which undergoes aminolysis with the respective primary amines RNH2 (R = tBu, Ph, pTol, pClPh, pAnis, pBiph, ptBuPh)**. The formulae are proved by elemental analyses and mass spectra. The paramagnetic complexes are stable to water and may thus be purified by chromatography but are hydrolyzed to give 2 a on treatment with acetic acid. The UV/VIS and 1H NMR spectra of 4a-4g are of the same type as 2a, but the former are slightly hypsochromically shifted, and the latter do not show the proton resonances of the organylimide ligands due to the proximity of the paramagnetic metal center.

scholarly journals Synthesis and Antimicrobial Screening of Novel 4-Substituted Phenyl-5-[1-(4-fluorophenyl)-1,3-dihydroisobenzofuran-5-yl]-2H-1,2,4-triazole-3-thiones

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Namratha Bhandari ◽  
Santosh L. Gaonkar
Keyword(s):  
Convenient Method ◽  
Nmr Spectra ◽  
Spectral Studies ◽  
Antimicrobial Screening ◽  
Antifungal Activities ◽  
H Nmr ◽  
Antibacterial And Antifungal Activities ◽  
Elemental Analyses ◽  
Antibacterial And Antifungal ◽  
C Nmr

The paper describes a convenient method for the preparation of 4-substituted phenyl-5-[1-(4-fluorophenyl)-1,3-dihydroisobenzofuran-5-yl]-2H-1,2,4-triazole-3-thiones. The structures of the synthesized compounds are established by the results of LCMS, 1H NMR, 13C NMR, and IR and elemental analyses. The mercaptotriazoles are indicated to be in thione form by 1H NMR spectra. All the synthesized compounds have been screened for antibacterial and antifungal activities. Compounds 12d and 12h exhibit encouraging results, while the remaining compounds show moderate activities. On the basis of spectral studies, formation of 2-amino-1,3,4-thiadiazoles from the isobenzofuran acyl thiosemicarbazides 11(a–h) is ruled out.

scholarly journals Structural characterization and DNA-binding properties of Sm(III) complex with ofloxacin using spectroscopic methods

2009 ◽  
Vol 23 (2) ◽  
pp. 103-111 ◽  
Author(s):  
Changyun Chen ◽  
Kai Chen ◽  
Qi Long ◽  
Meihua Ma ◽  
Fei Ding
Keyword(s):  
Binding Sites ◽  
Nmr Spectra ◽  
Uv Spectroscopy ◽  
Binding Constants ◽  
Binding Properties ◽  
H Nmr ◽  
Elemental Analyses ◽  
Displacement Experiments ◽  
Ct Dna ◽  
Dna Binding Properties

A novel complex Sm(III) complex with ofloxacin was synthesized and characterized on the basis of elemental analyses, molar conductivities, IR spectra, thermal analysis (TG-DSC),1H-NMR spectra. Then, spectrometric titration, ethdium bromide displacement experiments by UV spectroscopy, ionic influence, viscosity measurements and Circular Dichroism (CD) spectroscopic measurements were conducted to characterize the interaction between the complex and CT-DNA. Results obtained indicate that the complex bound with CT-DNA via an intercalation mechanism. The binding constants and binding sites number of the Sm(III) complex with CT-DNA were 1.80×105l·mol−1and 1, respectively.

Synthesis of new phthalocyanines substituted with four 1H-benzoimidazol-2-ylsulfanyl and 2-(1H-benzo[d]imidazol-2-ylthioetoxy) groups

2006 ◽  
Vol 10 (02) ◽  
pp. 117-121 ◽  
Author(s):  
M. Salih Ağırtaş ◽  
Ümit Yıldıko ◽  
Ayfer Yılan
Keyword(s):  
Nmr Spectra ◽  
H Nmr ◽  
Elemental Analyses ◽  
Uv Visible

The synthesis of new two phthalonitrile derivatives is described. Using these starting materials, metallophthalocyanines substituted with four 1 H -benzoimidazol-2-ylsulfanyl and 2-(1 H -benzo[d]imidazol-2-ylthioetoxy) have been synthesized, respectively. The newly synthesized compounds have been characterized by elemental analyses, UV-visible, IR and 1 H NMR spectra.

Synthesis of Substituted Furo[2',3':4,5]pyrrolo[1,2-d][1,2,4]triazolo[3,4-f][1,2,4]triazines

1995 ◽  
Vol 60 (4) ◽  
pp. 709-714 ◽  
Author(s):  
Vladimír Bobošík ◽  
Alžbeta Krutošíková ◽  
Miloslava Dandárová
Keyword(s):  
Nmr Spectra ◽  
H Nmr ◽  
Elemental Analyses

The title compounds were prepareed by reaction of 1,2-dihydrofuro[2',3':4,5]pyrolo[1,2-d][1,2,4]-1-hydrazones by cyclization with triethyl orthoformiate or triethyl orthoacetate. All compounds were characterized by elemental analyses, UV and 1H NMR spectra.

scholarly journals Synthesis, Characterization, and Antimicrobial Activity Studies of Ni(II) Complex with Pyridine as a Ligand

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Faridul Islam ◽  
Md. Amran Hossain ◽  
Nur Mostaq Shah ◽  
Hridika Talukder Barua ◽  
Md. Alamgir Kabir ◽  
...  
Keyword(s):  
Antimicrobial Activity ◽  
Nmr Spectra ◽  
Conductivity Measurement ◽  
Molar Conductivity ◽  
Molecular Formula ◽  
H Nmr ◽  
Square Planar ◽  
Elemental Analyses ◽  
Prepared Complex ◽  
C Nmr

We represent a metal complex which has been synthesized by the simple reaction with Ni(II) chloride and pyridine (as a lignd) affording a complex having the molecular formula [NiC5H5N2Cl2], characterized on the basis of elemental analyses, electronic, infrared,1H NMR,13C NMR spectra, magnetic susceptibility, and also aid of molar conductivity measurement. Conductivity measurement reveals nonelectrolytic nature of the complex. IR and13C NMR spectra reveal the presence ofcis- andtrans-structure. On the basis of above analyses the square planarcis- andtrans-structures are proposed for the prepared complex.

New Polymer Synthesis 99. Hyperbranched Poly(Ester-Imide)S Derived from 4,5-Dichlorophthalic Acid

1998 ◽  
Vol 10 (3) ◽  
pp. 217-229 ◽  
Author(s):  
Hans R Kricheldorf ◽  
Oliver Bolender ◽  
Thomas Wollheim
Keyword(s):  
Nmr Spectra ◽  
Variable Degree ◽  
Carboxylic Group ◽  
Degree Of Branching ◽  
Glass Transition Temperatures ◽  
Oh Groups ◽  
H Nmr ◽  
Hyperbranched Poly ◽  
Elemental Analyses ◽  
Phenolic Oh Groups

A new trifunctional monomer was prepared from ethyl-4-(4,5-dichlorophthalimido) benzoate and 4-mercaptophenol. The phenolic OH groups were acetylated, and the carboxylic group was silylated to reduce the melting temperature. A successful homopolycondensation yielding a completely soluble hyperbranched poly(ester-imide) was only obtained when the silylated monomer was used. This branching monomer was polycondensed with a difunctional imide monomer to yield co(polyester-imide)s having a variable degree of branching. Furthermore, copolycondensations with 3-acetoxybenzoic acid or 3,5-bisacetoxybenzoic acid (and their trimethylsilyl esters) were studied. The composition of the resulting copolyesters were checked by elemental analyses and 1H NMR spectra. The glass transition temperatures ( T g s) showed a systematic variation between the values of the parent homopolyesters.

Synthesis and Ligand Exchange Reaction of Some Organotin(IV) Bis(N-arylsulphonyl-N-arylhydroxylaminates)

1993 ◽  
Vol 48 (2) ◽  
pp. 185-188
Author(s):  
Mrinal K. Das ◽  
Matilal Nath ◽  
Somnath De
Keyword(s):  
Exchange Reaction ◽  
General Formula ◽  
Ligand Exchange ◽  
Nmr Spectra ◽  
Ligand Exchange Reaction ◽  
H Nmr ◽  
Elemental Analyses

AbstractSeveral diorganotin(IV)-bis(N-arylsulphonyl-N-arylhydroxylaminates) of the general formula R2Sn[ON(R1)SO2R2]2 have been synthesized and characterized by elemental analyses and by IR and 1H NMR spectra. A representative ligand exchange reaction with N-benzoyl- N-phenylhydroxylamine has been carried out.

Flüssig-kristalline Verbindungen aus der Thiophenreihe, Teil 4. Azomethine und Vinylene mit zentralen Azobenzol-, Stilben- und 1,2-Di(2-thienyl)ethylen-Einheiten / Liquid Crystalline Compounds in the Thiophene Series, Part 4. Azomethines and Vinylenes with Central Azobenzene, Stilbene and 1,2-Di(2-thienyl)ethylene Moieties

1987 ◽  
Vol 42 (4) ◽  
pp. 478-488 ◽  
Author(s):  
Gerhard Koßmehl ◽  
Detlev Budwill
Keyword(s):  
Nmr Spectra ◽  
Liquid Crystalline ◽  
Polarized Light ◽  
H Nmr ◽  
Thiophene Series ◽  
Elemental Analyses ◽  
Dta Analysis ◽  
Related Compounds

Abstract Azomethines and vinylenes, containing azobenzene, stilbene or 1,2-di(2-thienyl)ethylene moieties as central groups with additional thiophene systems has been synthesized and charac-terized by their elemental analyses, IR and 1H NMR spectra and studied in relation to their liquid crystalline properties by DTA analysis and visually by their textures microscoping under polarized light. The liquid crystalline properties of these compounds and some related compounds described in literature are compared and the geometrical elements of their structures are discussed.

Conformational structure of ethylene glycol dibenzoate. Vibrational and NMR spectra

1981 ◽  
Vol 46 (8) ◽  
pp. 1913-1929 ◽  
Author(s):  
Bohdan Schneider ◽  
Pavel Sedláček ◽  
Jan Štokr ◽  
Danica Doskočilová ◽  
Jan Lövy
Keyword(s):  
Ethylene Glycol ◽  
Vibrational Spectra ◽  
Nmr Spectra ◽  
Coupling Constants ◽  
Conformational Structure ◽  
Infrared And Raman Spectra ◽  
H Nmr ◽  
Liquid States ◽  
Crystalline Forms ◽  
C Nmr

It was found that three crystalline forms of ethylene glycol dibenzoate can be prepared. Infrared and Raman spectra of these three forms, as well as of the glassy and liquid states, were measured. From 3JHH coupling constants obtained by analysis of the 13C satellite band of the -CH2- group in 1H NMR spectra, and from the 3JCH coupling constants of the -CO.O.CH2- fragment obtained by analysis of the carbonyl band in 13C NMR spectra it was found that in the liquid state the -CH2-CH2- group exists predominantly in the gauche conformational structure, and the bonds C-O-C-C assume predominantly a trans orientation. The results of the analysis of NMR and vibrational spectra were used for the structural interpretation of conformationally sensitive bands in vibrational spectra of ethylene glycol dibenzoate.

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