Determination of the adsorption film characteristics of alkyltriphenylphosphonium cations from time dependent capacitance measurements

1987 ◽  
Vol 52 (2) ◽  
pp. 308-315
Author(s):  
Anastos Anastopoulos ◽  
Anastasia Christodoulou
Keyword(s):  
Adsorption Isotherm ◽  
Surface Concentration ◽  
Time Dependent ◽  
Phosphonium Salts ◽  
Adsorbed Particle ◽  
Adsorption Film ◽  
Capacitance Measurements ◽  
Film Characteristics ◽  
Quaternary Phosphonium Salts

The determination of the adsorbed film characteristics at the interface between methanolic solutions of quaternary phosphonium salts and the Hg electrode is carried out by means of time dependent capacitance measurements. The maximum surface concentration, the area per adsorbed particle and the orientation of methyltriphenyl-, cyclopropyltriphenyl-, and n-butyltriphenylphosphonium cations are derived by two methods, the first of which is free of isotherm assumptions and the second involves an adsorption isotherm obeyed by the system under examination.

scholarly journals Determination of time-dependent strengths of salt pillars based on strain energy principle

2019 ◽  
Vol 29 (2) ◽  
pp. 273-279 ◽  
Author(s):  
Prapasiri Junthong ◽  
Supattra Khamrat ◽  
Suratwadee Sartkaew ◽  
Kittitep Fuenkajorn
Keyword(s):  
Strain Energy ◽  
Time Dependent ◽  
Energy Principle

The Study of the Conformation and Dynamics of the New Quaternary Phosphonium Salts by NMR Spectroscopy

2014 ◽  
Vol 45 (7) ◽  
pp. 653-665 ◽  
Author(s):  
Oksana Aganova ◽  
Leisan Galiullina ◽  
Albert Aganov ◽  
Yurii Shtyrlin ◽  
Mikhail Pugachev ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Phosphonium Salts ◽  
Quaternary Phosphonium Salts

Orthogonal Investigation of Influencing Factors on the Modification of Montmorillonite by THPC in Acid Conditions

2014 ◽  
Vol 936 ◽  
pp. 1017-1021
Author(s):  
Pan Chen ◽  
Jin Cheng Wang
Keyword(s):  
Reaction Time ◽  
Ion Exchange ◽  
Influencing Factors ◽  
Reaction Temperature ◽  
Orthogonal Test ◽  
Test Results ◽  
Phosphonium Salts ◽  
Exchange Reactions ◽  
Quaternary Phosphonium Salts

Na-MMT was modified with quaternary phosphonium salts, tetramethylolphosphonium chloride (THPC), via ion-exchange reactions, in acid conditions. Different factors such as reaction time , reaction temperature, the types of solvent, and CEC ratios, were investigated using orthogonal test. Results showed that the best combination of these four factors were A1B3C1D1, that is, the type of the solvent was acetone and water (1:1), reaction time was 3h, CEC ratio was 1:1, and the reaction temperature was 80°C.

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