Condensation of supersaturated vapours. Homogeneous nucleation of naphthalene and phthalic anhydride

1985 ◽  
Vol 50 (6) ◽  
pp. 1349-1358 ◽  
Author(s):  
Jiří Smolík ◽  
Jaroslav Vítovec
Keyword(s):  
Surface Tension ◽  
Thermal Diffusion ◽  
Classical Theory ◽  
Phthalic Anhydride ◽  
Homogeneous Nucleation ◽  
Corresponding States ◽  
Experimental Results ◽  
Critical Supersaturation ◽  
Fluid Behaviour ◽  
Good Agreement

The critical supersaturation required for the homogeneous nucleation of naphthalene and phthalic anhydride from their vapours has been measured using upward thermal diffusion cloud chamber. The results obtained are compared with the predictions of the classical theory of homogeneous nucleation (Volmer-Becker-Doring-Zeldovich) and the corresponding states correlation of homogeneous nucleation. The classical theory is found to be in excellent agreement with the experimental results on naphthalene but overpredicts the critical supersaturation of phthalic anhydride vapours by about 30%. In order to fit the experiment and theory, the new values of surface tension of phthalic anhydride were recalculated from the theory. Critical supersaturation of naphthalene plotted versus temperature reveals the same regular departure from single fluid behaviour as found for alkylbenzenes. The experimental results on phthalic anhydride were found to be in very good agreement with the corresponding states correlation.

Nucleation and Growth of Bubbles in Elastomers

1971 ◽  
Vol 44 (5) ◽  
pp. 1363-1379 ◽  
Author(s):  
Charles W. Stewart
Keyword(s):  
Surface Tension ◽  
Homogeneous Nucleation ◽  
Nucleation And Growth ◽  
Experimental Results ◽  
Dissolved Gas ◽  
Rate Of Growth ◽  
High Degree ◽  
Approximate Expressions ◽  
Temperature Surface

Abstract The theory of homogeneous nucleation of bubbles is combined with an expression, for their rate of growth in elastomers to obtain approximate expressions for calculating the number of bubbles formed under a high degree of supersaturation. Experimental results are given for several elastomers with argon as the dissolved gas under a variety of foaming conditions. The theory adequately describes the manner in which the number of bubbles formed depends on the temperature, surface tension of the polymer, and permeability of the dissolved gas.

Homogeneous Nucleation in Supersaturated Vapors of n-Nonane

1994 ◽  
Vol 59 (2) ◽  
pp. 253-261 ◽  
Author(s):  
Vladimír Ždímal ◽  
Jiří Smolík ◽  
Ivo G. N. Meijer
Keyword(s):  
Surface Tension ◽  
Theoretical Prediction ◽  
Thermal Diffusion ◽  
Homogeneous Nucleation ◽  
Reasonable Agreement ◽  
Cloud Chamber ◽  
Temperature Dependent ◽  
Significant Underestimation

The upward thermal diffusion cloud chamber was used to measure the supersaturations of n-nonane vapors required to cause an observed rate of homogeneous nucleation of 1 droplet/cm3 s. New temperature-dependent correlations for the surface tension and the density of n-nonane have been applied in theoretical prediction of the corresponding supersaturation. The measurements are found to be in reasonable agreement with the predictions of the classical (Becker-Doering) theory whereas both the Dillmann-Meier and the Girshick-Chiu theories lead to a significant underestimation of supersaturation in the whole range of temperatures measured.

Homogeneous Nucleation of Supersaturated Vapors. A Comparison of Experimental Results with Theory

1993 ◽  
Vol 58 (12) ◽  
pp. 2831-2835
Author(s):  
Jiří Smolík ◽  
Vladimír Ždímal
Keyword(s):  
Stearic Acid ◽  
Phthalic Anhydride ◽  
Homogeneous Nucleation ◽  
Liquid Droplet ◽  
Experimental Results ◽  
Droplet Model ◽  
Polar Substance ◽  
Ethylhexyl Phthalate

Some theories of homogeneous nucleation based on liquid droplet model were tested by comparing with experimental supersaturations of naphthalene, phthalic anhydride, stearic acid, bis(2-ethylhexyl) phthalate, and bis(2-ethylhexyl) sebacate required to bring about the rate of homogeneous nucleation of about 5 drops/cm3 s-1. It was found that except for highly polar substance phthalic anhydride, the classical (Becker-Doring) theory of homogeneous nucleation, if suitably scaled, yielded fairly good predictions of the nucleation behaviour.

Fractal Characteristics of Viscous Fingering

Fractals ◽  
1997 ◽  
Vol 05 (02) ◽  
pp. 221-227 ◽  
Author(s):  
Songyue Tang ◽  
Zhonglei Wei
Keyword(s):  
Surface Tension ◽  
Monte Carlo ◽  
Stochastic Simulation ◽  
Viscosity Ratio ◽  
Fractal Dimensions ◽  
Viscous Fingering ◽  
Experimental Results ◽  
Fractal Characteristics ◽  
Hele Shaw Cell ◽  
Good Agreement

Viscous fingering is investigated by experiment in a 2-dimensional radial Hele-Shaw cell and Monte Carlo stochastic simulation. Experimental results show that viscosity ratio between the driving and driven fluids determines whether or not viscous fingerings occur and that surface tension makes the viscous fingering patterns "fatter". Simulation patterns are in good agreement with experimental ones. The fractal dimensions of the viscous fingering patterns by both experiments and simulations are about Df=1.2-1.6.

Inducing Frictional Force to Enhance the Transient Response in Beams

2019 ◽  
Vol 22 (2) ◽  
pp. 88-93
Author(s):  
Hamed Khanger Mina ◽  
Waleed K. Al-Ashtrai
Keyword(s):  
Numerical Analysis ◽  
Transient Response ◽  
Frictional Force ◽  
Damping Ratio ◽  
Experimental Results ◽  
Damping Capacity ◽  
Tightening Force ◽  
Contact Areas ◽  
Good Agreement ◽  
Ansys Workbench

This paper studies the effect of contact areas on the transient response of mechanical structures. Precisely, it investigates replacing the ordinary beam of a structure by two beams of half the thickness, which are joined by bolts. The response of these beams is controlled by adjusting the tightening of the connecting bolts and hence changing the magnitude of the induced frictional force between the two beams which affect the beams damping capacity. A cantilever of two beams joined together by bolts has been investigated numerically and experimentally. The numerical analysis was performed using ANSYS-Workbench version 17.2. A good agreement between the numerical and experimental results has been obtained. In general, results showed that the two beams vibrate independently when the bolts were loosed and the structure stiffness is about 20 N/m and the damping ratio is about 0.008. With increasing the bolts tightening, the stiffness and the damping ratio of the structure were also increased till they reach their maximum values when the tightening force equals to 8330 N, where the structure now has stiffness equals to 88 N/m and the damping ratio is about 0.062. Beyond this force value, increasing the bolts tightening has no effect on stiffness of the structure while the damping ratio is decreased until it returned to 0.008 when the bolts tightening becomes immense and the beams behave as one beam of double thickness.

PHOTOINDUCED NONLINEAR OCTUPOLAR POLARIZATION: TRANSIENT AND PERMANENT REGIMES

1996 ◽  
Vol 05 (04) ◽  
pp. 653-670 ◽  
Author(s):  
CÉLINE FIORINI ◽  
JEAN-MICHEL NUNZI ◽  
FABRICE CHARRA ◽  
IFOR D.W. SAMUEL ◽  
JOSEPH ZYSS
Keyword(s):  
Theoretical Analysis ◽  
Second Harmonic ◽  
Experimental Results ◽  
Polar Field ◽  
Rotational Spectrum ◽  
Dual Frequency ◽  
One Dimensional ◽  
Ethyl Violet ◽  
Disperse Red 1 ◽  
Good Agreement

An original poling method using purely optical means and based on a dual-frequency interference process is presented. We show that the coherent superposition of two beams at fundamental and second-harmonic frequencies results in a polar field with an irreducible rotational spectrum containing both a vector and an octupolar component. This enables the method to be applied even to molecules without a permanent dipole such as octupolar molecules. After a theoretical analysis of the process, we describe different experiments aiming at light-induced noncentrosymmetry performed respectively on one-dimensional Disperse Red 1 and octupolar Ethyl Violet molecules. Macroscopic octupolar patterning of the induced order is demonstrated in both transient and permanent regimes. Experimental results show good agreement with theory.

scholarly journals Comparison of Experimental and Numerical Transient Drop Deformation during Transition through Orifices in High-Pressure Homogenizers

2021 ◽  
Vol 5 (3) ◽  
pp. 32
Author(s):  
Benedikt Mutsch ◽  
Peter Walzel ◽  
Christian J. Kähler
Keyword(s):  
High Pressure ◽  
Visual Analysis ◽  
Imaging Technique ◽  
Extensional Flow ◽  
Droplet Breakup ◽  
Experimental Results ◽  
Drop Deformation ◽  
Droplet Deformation ◽  
Shadow Imaging ◽  
Good Agreement

The droplet deformation in dispersing units of high-pressure homogenizers (HPH) is examined experimentally and numerically. Due to the small size of common homogenizer nozzles, the visual analysis of the transient droplet generation is usually not possible. Therefore, a scaled setup was used. The droplet deformation was determined quantitatively by using a shadow imaging technique. It is shown that the influence of transient stresses on the droplets caused by laminar extensional flow upstream the orifice is highly relevant for the droplet breakup behind the nozzle. Classical approaches based on an equilibrium assumption on the other side are not adequate to explain the observed droplet distributions. Based on the experimental results, a relationship from the literature with numerical simulations adopting different models are used to determine the transient droplet deformation during transition through orifices. It is shown that numerical and experimental results are in fairly good agreement at limited settings. It can be concluded that a scaled apparatus is well suited to estimate the transient droplet formation up to the outlet of the orifice.

scholarly journals Nonlinear two-dimensional free surface solutions of flow exiting a pipe and impacting a wedge

2021 ◽  
Vol 126 (1) ◽  
Author(s):  
Alex Doak ◽  
Jean-Marc Vanden-Broeck
Keyword(s):  
Surface Tension ◽  
Integral Equation ◽  
Free Surface ◽  
Boundary Integral ◽  
Boundary Integral Method ◽  
Two Dimensional ◽  
Numerical Schemes ◽  
Additional Advantage ◽  
Infinite Wedge ◽  
Good Agreement

AbstractThis paper concerns the flow of fluid exiting a two-dimensional pipe and impacting an infinite wedge. Where the flow leaves the pipe there is a free surface between the fluid and a passive gas. The model is a generalisation of both plane bubbles and flow impacting a flat plate. In the absence of gravity and surface tension, an exact free streamline solution is derived. We also construct two numerical schemes to compute solutions with the inclusion of surface tension and gravity. The first method involves mapping the flow to the lower half-plane, where an integral equation concerning only boundary values is derived. This integral equation is solved numerically. The second method involves conformally mapping the flow domain onto a unit disc in the s-plane. The unknowns are then expressed as a power series in s. The series is truncated, and the coefficients are solved numerically. The boundary integral method has the additional advantage that it allows for solutions with waves in the far-field, as discussed later. Good agreement between the two numerical methods and the exact free streamline solution provides a check on the numerical schemes.

Effects of Wind on the Heat Flow of FPSO Topsides Subject to Fire: An Experimental and Numerical Study

2010 ◽  
Author(s):  
Joon Young Yoon ◽  
Seong Hwan Kim ◽  
Gwon Cheol Yu ◽  
Jung Kwan Seo ◽  
Bong Ju Kim ◽  
...  
Keyword(s):  
Thermal Diffusion ◽  
Numerical Study ◽  
Wind Tunnel Test ◽  
Experimental Results ◽  
Test Facility ◽  
Test Model ◽  
Cfd Simulations ◽  
Fire Engineering ◽  
Diffusion Characteristics ◽  
Fire Loads

The aim of this paper is to examine the effect of wind on the thermal diffusion characteristics of floating production storage and offloading (FSPO) topside models subject to fire. It is motivated by the need to identify the fire loads on FPSO topsides, taking into account the effects of wind speed and direction. The results of an experimental and numerical study undertaken for these purposes are reported here. This paper is part of Phase II of the joint industry project on explosion and fire engineering of FPSOs (EFEF JIP) [1]. An experiment was performed on a 1/14-scale FPSO topside model using a wind tunnel test facility. The locations of the heat source of the fire were varied, as were the speed and direction of the wind, and the temperature distribution was measured. Computational fluid dynamics (CFD) simulations using the ANSYS CFX program were performed on the test model, with the results obtained compared with the experimental results. It is concluded that wind has a significant effect on the thermal diffusion characteristics of the test model and that the CFD simulations are in good agreement with the experimental results. The insights developed in this study will be very useful for the fire engineering of FPSO topsides.

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