Isothermal and isobaric vapour-liquid equilibrium data in the tetrachloromethane-tert-butyl alcohol system

1983 ◽  
Vol 48 (6) ◽  
pp. 1669-1675
Author(s):  
Jan Linek ◽  
Svatoslava Bernatová

Isothermal vapour-liquid equilibrium data at 55, 63 and 70 °C and isobaric ones at 101.3 kPa were measured in the tetrachloromethane-tert-butyl alcohol system. A modified circulation still of the Gillespie type was used for the measurements. Under the conditions of measurement, the system exhibits positive deviations from Raoult's law and minimum boiling-point azeotropes. The experimental data were fitted to a number of correlation equations, the most suitable being the Wilson equation.

1983 ◽  
Vol 48 (9) ◽  
pp. 2446-2453 ◽  
Author(s):  
Jan Linek

Isothermal vapour-liquid equilibrium data at 65, 73 and 80 °C and isobaric ones at 101.3 kPa were measured in the tetrachloromethane-sec-butyl alcohol system. A modified circulation still of the Gillespie type was used for the measurements. Under the conditions of measurement, the system exhibits positive deviations from Raoult's law and minimum boiling-point azeotropes. The experimental data were fitted to a number of correlation equations, the most suitable being the Wilson equation.


1983 ◽  
Vol 48 (10) ◽  
pp. 2879-2887 ◽  
Author(s):  
Jan Linek

Isothermal vapour-liquid equilibrium data at 65, 73 and 80 °C and isobaric ones at 101.3 kPa were measured in the tetrachloromethane-n-butyl alcohol system. A modified circulation still of the Gilespie type was used for the measurements. Under the conditions of measurements, the system exhibits positive deviations from Raoult's law and minimum boiling-point azeotropes. The experimental data were fitted to a number of correlation equations. The best correlation was reached with the Wilson equation but the regression failed in some cases. Therefore the results for the 5th order Redlich-Kister equation are presented.


1979 ◽  
Vol 44 (12) ◽  
pp. 3509-3514 ◽  
Author(s):  
Jan Linek ◽  
Jiřina Klimánková

Isothermal vapour-liquid equilibrium data at 65, 75 and 83°C and isobaric ones at 101.325 kPa have been measured in the tetrachloromethane-isobutyl alcohol system. A modified circulation still of the Gillespie type has been used for the measurements. The experimental data have been correlated by the Margules 3rd and 4th order equation.


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