Relative viscosities and quasi-thermodynamics of solutions of tert-butyl alcohol in the methanol–water system: a different view of the alkyl–water interaction

1993 ◽  
Vol 89 (18) ◽  
pp. 3381-3388 ◽  
Author(s):  
David Feakins ◽  
Fiona M. Bates ◽  
W. Earle Waghorne ◽  
Kenneth G. Lawrence
Keyword(s):  
Water System ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Water Interaction ◽  
System A ◽  
Tert Butyl Alcohol ◽  
Thermodynamics Of Solutions

Isothermal and isobaric vapour-liquid equilibrium data in the tetrachloromethane-tert-butyl alcohol system

1983 ◽  
Vol 48 (6) ◽  
pp. 1669-1675
Author(s):  
Jan Linek ◽  
Svatoslava Bernatová
Keyword(s):  
Experimental Data ◽  
Butyl Alcohol ◽  
Correlation Equations ◽  
Wilson Equation ◽  
Liquid Equilibrium ◽  
Tert Butyl ◽  
System A ◽  
Tert Butyl Alcohol ◽  
Equilibrium Data ◽  
Alcohol System

Isothermal vapour-liquid equilibrium data at 55, 63 and 70 °C and isobaric ones at 101.3 kPa were measured in the tetrachloromethane-tert-butyl alcohol system. A modified circulation still of the Gillespie type was used for the measurements. Under the conditions of measurement, the system exhibits positive deviations from Raoult's law and minimum boiling-point azeotropes. The experimental data were fitted to a number of correlation equations, the most suitable being the Wilson equation.

Thermodynamic and Kinetic Investigation of the Solvent Effect on the Oxidation of [Co(en)2SCH2COO]+ with S2O82- In Water-Methanol and Water-tert-Butyl Alcohol Mixtures

1993 ◽  
Vol 58 (5) ◽  
pp. 1001-1006 ◽  
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Transfer Functions ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Oxidation Of Co ◽  
Kinetics Of Oxidation ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Mixtures ◽  
Kinetics Of

The kinetics of oxidation of [Co(en)2SCH2COO]+ with S2O82- was studied in water-methanol and water-tert-butyl alcohol mixtures. Changes in the reaction activation parameters ∆H≠ and ∆S≠ with varying concentration of the co-solvent depend on the kind of the latter, which points to a significant role of salvation effects. The solvation effect on the reaction is discussed based on a comparison of the transfer functions ∆Ht0, ∆St0 and ∆Gt0 for the initial and transition states with the changes in the activation parameters accompanying changes in the CO-solvent concentration. The transfer enthalpies of the reactant were obtained from calorimetric measurements.

scholarly journals Impacts of Sn(II) doping on the Keggin heteropolyacid-catalyzed etherification of glycerol with tert-butyl alcohol

2021 ◽  
pp. 116913
Author(s):  
Márcio José da Silva ◽  
Diego Morais Chaves ◽  
Sukarno Olavo ferreira ◽  
Rene Chagas da Silva ◽  
Jose Balena Gabriel Filho ◽  
...  
Keyword(s):  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol
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