Kinetics of catalytic conversion of methanol at higher pressures

1980 ◽  
Vol 45 (12) ◽  
pp. 3402-3407 ◽  
Author(s):  
Jaroslav Bartoň ◽  
Vladimír Pour

The course of the conversion of methanol with water vapour was followed on a low-temperature Cu-Zn-Cr-Al catalyst at pressures of 0.2 and 0.6 MPa. The kinetic data were evaluated together with those obtained at 0.1 MPa and the following equation for the reaction kinetics at the given conditions was derived: r = [p(CH3OH)p(H2O)]0.5[p(H2)]-1.3.

2016 ◽  
Vol 6 (18) ◽  
pp. 6910-6915 ◽  
Author(s):  
H. Yasumatsu ◽  
N. Fukui

Catalytic CO oxidation driven by uni-sized Pt30 bound to a Si substrate, at the interface of which electrons are accumulated. The low-temperature and anti-CO-poisoning performance has been evidenced with continuous and simultaneous supply of CO and O2.


1979 ◽  
Vol 44 (12) ◽  
pp. 3676-3687 ◽  
Author(s):  
Vlastimil Vyskočil ◽  
Miloš Kraus

The kinetics of the title reactions has been measured at 350°C and atmospheric pressure on six Co-Mo-AL2O3 catalysts prepared by successive impregnation of the support with solutions of molybdenum and cobalt salts and containing these components in different ratios as well as on a commercial Cherox 36-00 catalyst. The activity of these catalysts depend strongly on their composition and showed similar trends for both reactions. Kinetic data were correlated by equations of Langmuir-Hishelwood type. Their adsorption coefficients have a similar value for different catalysts and all differences in the activity reflected in rate constants. Surface concentrations of molybdenum were determined by low temperature oxygen adsorption and were correlated with experimental rate constants.


Rare Metals ◽  
2010 ◽  
Vol 29 (2) ◽  
pp. 121-125 ◽  
Author(s):  
Xiuyan Wang ◽  
Jiemin Liu ◽  
Mei Li ◽  
Huili Fan ◽  
Qishan Yang

2018 ◽  
Vol 57 (29) ◽  
pp. 9716-9724 ◽  
Author(s):  
Louis J. Du Preez ◽  
Jakobus P. Barnard ◽  
Linda H. Callanan ◽  
Johannes H. Knoetze

Icarus ◽  
2014 ◽  
Vol 227 ◽  
pp. 123-131 ◽  
Author(s):  
Ludovic Biennier ◽  
Sophie Carles ◽  
Daniel Cordier ◽  
Jean-Claude Guillemin ◽  
Sébastien D. Le Picard ◽  
...  

Micron ◽  
2004 ◽  
Vol 35 (1-2) ◽  
pp. 137-139 ◽  
Author(s):  
P.K Wick ◽  
K.D Karlin ◽  
M Suzuki ◽  
Andreas D Zuberbühler

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