Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+

Micron ◽  
2004 ◽  
Vol 35 (1-2) ◽  
pp. 137-139 ◽  
Author(s):  
P.K Wick ◽  
K.D Karlin ◽  
M Suzuki ◽  
Andreas D Zuberbühler
2000 ◽  
Vol 275 (26) ◽  
pp. 19490-19497 ◽  
Author(s):  
Jamie D. Venning ◽  
Sarah J. Peake ◽  
Philip G. Quirk ◽  
J. Baz Jackson

1980 ◽  
Vol 45 (12) ◽  
pp. 3402-3407 ◽  
Author(s):  
Jaroslav Bartoň ◽  
Vladimír Pour

The course of the conversion of methanol with water vapour was followed on a low-temperature Cu-Zn-Cr-Al catalyst at pressures of 0.2 and 0.6 MPa. The kinetic data were evaluated together with those obtained at 0.1 MPa and the following equation for the reaction kinetics at the given conditions was derived: r = [p(CH3OH)p(H2O)]0.5[p(H2)]-1.3.


2016 ◽  
Vol 33 ◽  
pp. 186-195 ◽  
Author(s):  
Abdelbaki Benamor ◽  
Mohammed Jaber Al-Marri ◽  
Majeda Khraisheh ◽  
Mustafa S. Nasser ◽  
Paitoon Tontiwachwuthikul

2016 ◽  
Vol 6 (18) ◽  
pp. 6910-6915 ◽  
Author(s):  
H. Yasumatsu ◽  
N. Fukui

Catalytic CO oxidation driven by uni-sized Pt30 bound to a Si substrate, at the interface of which electrons are accumulated. The low-temperature and anti-CO-poisoning performance has been evidenced with continuous and simultaneous supply of CO and O2.


2012 ◽  
Vol 19 (1) ◽  
pp. 55-66 ◽  
Author(s):  
Marta Siemieniec ◽  
Hanna Kierzkowska-Pawlak ◽  
Andrzej Chacuk

Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique The pseudo-first-order rate constants (kOV) for the reactions between CO2 and diethanolamine have been studied using the stopped-flow technique in an aqueous solution at 293, 298, 303 and 313 K. The amine concentrations ranged from 167 to 500 mol·m-3. The overall reaction rate constant was found to increase with amine concentration and temperature. Both the zwitterion and termolecular mechanisms were applied to correlate the experimentally obtained rate constants. The values of SSE quality index showed a good agreement between the experimental data and the corresponding fit by the use of both mechanisms.


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