Determination of heats of vaporization and some other thermodynamic quantities for several fluorinated halogen derivatives of ethane and propane

1980 ◽  
Vol 45 (11) ◽  
pp. 3063-3068 ◽  
Author(s):  
Vladimír Majer ◽  
Václav Svoboda ◽  
Antonín Pošta ◽  
Jiří Pick

Some physico-chemical properties were determined for 1,1,1-trichlorotrifluoroethane, 1,1,2-trichlorotrifluoroethane, 1-bromo-1-chloro-2,2,2-trifluoroethane and 1,2-dichlorohexafluoropropane. For all the substances, their heats of vaporization in dependence on temperature were measured and their densities and refractive indices at two temperatures were determined. For 1,1,1-trichlorotrifluoroethane and 1,2-dichlorohexafluoropropane the saturated vapour pressures were measured, too. The temperature dependences of standard heats of vaporization, vaporization internal energies and cohesive energies were determined on the basis of the experimental data.

1981 ◽  
Vol 46 (4) ◽  
pp. 817-822 ◽  
Author(s):  
Vladimír Majer ◽  
Václav Svoboda ◽  
Antonín Pošta ◽  
Jiří Pick

Some thermodynamic properties were investigated for three fluorinated halogen ethanes: 1-bromo-2-chloro-1,1,2-trifluoroethane, 1,2-dibromotetrafluroethane and 1,2-dibromo-1-chlorotrifluoroethane. The temperature dependence of heats of vaporization, saturated vapour pressures, densities and refractive indices was measured at two temperatures. On the basis of the experimental quantities obtained, the standard heats of vaporization and the cohesive and internal energies of vaporization in their dependence on temperature were determined.


1979 ◽  
Vol 44 (12) ◽  
pp. 3521-3528 ◽  
Author(s):  
Vladimír Majer ◽  
Václav Svoboda ◽  
Josef Koubek ◽  
Jiří Pick

The temperature dependences of heats of vaporization of propylamine, isopropylamine, butylamine, isobutylamine, sec-butylamine, cyclohexylamine, diethylamine and triethylamine and saturated vapour pressures of butylamine, isobutylamine, sec-butylamine and triethylamine were measured. The cohesive energies of amines studied in dependence on temperature were calculated from the experimental values.


1981 ◽  
Vol 46 (12) ◽  
pp. 2983-2988 ◽  
Author(s):  
Václav Svoboda ◽  
Vladimíra Charvátová ◽  
Vladimír Majer ◽  
Jiří Pick

Heats of vaporization and some other related thermodynamic quantities were determined for the four alkylcycloparaffins: ethylcyclopentane, n-butylcyclopentane, ethylcyclohexane and tert-butylcyclohexane. The temperature dependence of heats of vaporization was measured and employed for calculating standard heats of vaporization, internal and cohesive energies of vaporization, entropies of vaporization, and differences between heat capacities of liquids and vapours at constant pressure and along the saturation line of vapours.


2018 ◽  
Vol 122 ◽  
pp. 702-708 ◽  
Author(s):  
S. Sani ◽  
M.U. Kaisan ◽  
D.M. Kulla ◽  
A.I. Obi ◽  
A. Jibrin ◽  
...  

2013 ◽  
Vol 59 (No. 8) ◽  
pp. 372-377 ◽  
Author(s):  
W. Szulc ◽  
B. Rutkowska

The determination of a range of boron concentration in the soil solution, evaluation of the effect of physico-chemical soil properties on boron concentration in the soil solution as well verification whether boron quantity in the soil solution is sufficient for nutritional needs of selected plants cultivated in Poland were comprised. Average boron concentration in the soil solution of Poland&rsquo;s cultivated soils ranges from 0.59 to 5.07 &micro;mol/L and is differentiated by physico-chemical properties of soil. Taking into account decreasing effects of soil properties on the increase of boron concentration in the soil solution, the soil properties can be arranged as follows: organic C &gt;<br />soil abundance in available boron &gt; soil texture &gt; soil pH. The minimum boron quantity observed in the soil solution of Poland&rsquo;s cultivated soils was not sufficient to fulfil nutritional needs of the plants. The maximum boron quantity observed secured nutritional needs of cereals and potatoes but not those of rape plants and sugar beets. Based on the study it can be concluded that the measurement of the concentration of boron in the soil solution can be used in the diagnosis of deficiency of this element for crops.


2020 ◽  
Vol 20 (sup3) ◽  
pp. S1579-S1589
Author(s):  
Dinesh Chandra Naithani ◽  
J.M.S. Rawat ◽  
Bhupendra Singh ◽  
Vinod Prasad Khanduri ◽  
Manoj Kumar Riyal

2020 ◽  
Vol 49 (20) ◽  
pp. 6566-6571 ◽  
Author(s):  
Daniela Lalli ◽  
Stefano Marchesi ◽  
Fabio Carniato ◽  
Chiara Bisio ◽  
Lorenzo Tei ◽  
...  

A combination of solid-state NMR and 1H-NMR relaxometric investigations has been employed to characterize the structure and physico-chemical properties of a novel synthetic saponite intercalated with Gd(iii) and Y(iii) chelates.


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