Synthesis, spectral properties and pesticidal activity of some O-(2,4,5-trichloro-6-bromo/iodo, nitro/phenyl) esters of carbamic and thiocarbamic acids

1979 ◽  
Vol 44 (3) ◽  
pp. 918-927 ◽  
Author(s):  
Václav Konečný ◽  
Štefan Varkonda ◽  
Naďa Kulíčková
Keyword(s):  
Powdery Mildew ◽  
Spectral Properties ◽  
Fungicidal Activity ◽  
Uv Spectra ◽  
Herbicidal Activity ◽  
Phenyl Ester ◽  
Powdery Mildew Disease ◽  
Ir And Uv Spectra

2,4,5-Trichloro-6-bromo/iodo, nitro/phenyl carbamates have been prepared by reaction of 2,4,5-trichloro-6-bromo/iodo, nitro/phenyl chlorocarbonates with amines or by reaction of carbamoyl chloride with sodium 2,4,5-trichloro-6-bromo/iodo, nitro/phenolate, and the thiocarbamate esters have been prepared by reaction of O-(2,4,5-trichloro-6-bromo/iodo, nitro/phenyl) ester of chlorothiocarbonic acid with amines. IR and UV spectra of the synthetized compounds have been interpreted. The compounds have been tested for contact and systeme insecticidal, acaricidal, ovicidal, fungicidal and herbicidal activity. The highest fungicidal activity has been observed against powdery mildew disease.

Synthesis, spectral properties, and pesticidal activity of 4-amino(alkylamino, dialkylamino)-5-chloro-2-substituted-3-oxo-2H-pyridazines and 5-amino(alkylamino, dialkylamino)-4-chloro-2-substituted-3-oxo-2H-pyridazines

1985 ◽  
Vol 50 (2) ◽  
pp. 492-502 ◽  
Author(s):  
Václav Konečný ◽  
Štefan Kováč ◽  
Štefan Varkonda
Keyword(s):  
Nucleophilic Substitution ◽  
Spectral Properties ◽  
Fungicidal Activity ◽  
Aprotic Solvent ◽  
Uv Spectra ◽  
Herbicidal Activity ◽  
Hill Reaction ◽  
Solvent Structure ◽  
Substitution Reactions ◽  
The Hill

4-Amino(alkylamino)-5-chloro-2-substituted-3-oxo-2H-pyridazines and 5-amino(alkylamino, dialkylamino)-4-chloro-2-substituted-3-oxo-2H-pyridazines have been prepared by nucleophilic substitution reactions of 4,5-dichloro-2-substituted-3-oxo-2H-pyridazines with amines in aprotic solvent. Structure of the compounds prepared has been proved by IR and UV spectra. Fungicidal and herbicidal activity of the compounds prepared have been tested. None of the compounds prepared exceeds the standard Vitavax in the fungicidal activity tests. Compounds VIII and XII show equal or better activity on the Hill reaction as compared with the standard pyrazone.

Syntheses, spectral properties and pesticide activity of O-ethyl-S-propyl-O-(1-alkyl, phenyl-5-chloro, alkoxy-6-oxo-1H-pyridazine-4-yl)esters of dithiophosphoric acid

1980 ◽  
Vol 45 (8) ◽  
pp. 2247-2253 ◽  
Author(s):  
Václav Konečný ◽  
Štefan Varkonda ◽  
Vojtech Kubala
Keyword(s):  
Spectral Properties ◽  
Uv Spectra ◽  
Dithiophosphoric Acid ◽  
Insecticide Activity ◽  
Ir And Uv Spectra

Syntheses of O-ethyl-S-propyl-O-(1-alkyl, phenyl-5-chloro, alkoxy-6-oxo-1H-pyridazine-4-yl) esters of dithiophosphoric acid are described. The compounds were investigated for their IR and UV spectra and for their contact and system activities as insecticides, acaricides, ovicides, fungicides and herbicides. Some of the compounds proved efficient acaricides; compound VIII also had an insecticide activity.

The synthesis, spectral properties and pesticidal activity of O-(1-benzyl, cyclohexyl, methyl-5-ethoxy, methoxy, methylthio-6-oxo-1H-pyridazin-4-yl) esters of phosphoric, thiophosphoric and thiophosphonic acids

1979 ◽  
Vol 44 (6) ◽  
pp. 1761-1771 ◽  
Author(s):  
Václav Konečný ◽  
Štefan Varkonda
Keyword(s):  
High Activity ◽  
Spectral Properties ◽  
Uv Spectra ◽  
Ovicidal Activity ◽  
Cyclohexyl Methyl ◽  
Ir And Uv Spectra

The synthesis of O-(5-ethoxy-1-methyl-6-oxo-1H-pyridazin-4-yl), O-(5-methoxy-1-benzyl-6-oxo-1H-pyridazin-4-yl), O-(5-methylthio-1-methyl-6-oxo-1H-pyridazin-4-yl) and O-(5-methoxy-1-cyclohexyl-6-oxo-1H-pyridazin-4-yl) esters of phosphoric, thiophosphoric and thiophosphonic acids is described. The IR and UV spectra of the synthetized compounds were measured and interpreted and their contact and systemic insecticidal, acaricidal and ovicidal activity was determined. Several of the compounds tested displayed high activity.

Incidence of powdery mildew on cucurbit plants in Katsina, Nigeria

2019 ◽  
pp. 05-09
Keyword(s):  
Powdery Mildew ◽  
Low Cost ◽  
Frequency Of Occurrence ◽  
Sphaerotheca Fuliginea ◽  
Causal Organism ◽  
Powdery Mildews ◽  
Powdery Mildew Disease ◽  
Important Disease

The presence study deals with powdery mildews in various cucurbits in Katsina city (Barhim Estate, Kofar Durbi, Kofar Sauri, Kofar Marusa and Low Cost), Nigeria. The finding shows that the areas infested with powdery mildew is one of the important disease of cucurbits. The Sphaerotheca fuliginea was identified to be the causal organism present on all observed cucurbits in the study. Highest frequency of disease was found in Kofar Sauri(79%) fallowed by Kofar Marusa (68%), Kofar Durbi (66%), Barhim Estate (65%) and the lowest frequency of occurrence of disease was found in Low Cost (55%).The intensity of the disease was moderate to severe in general but it was high in many fields, the area-wise variation was also noticed. On vegetables, the highest frequency of occurrence of powdery mildew disease was observed on L. cylindrica (76.4%) followed by C. moschata (60%), C. sativus (59.3%), C. vulgaris (53.9%) and lowest was found on C. melo (44.4%). The highest intensity of disease was found on C. moschata, followed by L. cylindrica, C. sativus, C. vulgaris and C. melo.

Thermal cyclocondensations of 3-N(4- and 5-benzimidazolyl and benztriazolyl)amino derivatives of 2-propenoic acid

1987 ◽  
Vol 52 (12) ◽  
pp. 2918-2925 ◽  
Author(s):  
Viktor Milata ◽  
Dušan Ilavský
Keyword(s):  
Uv Spectra ◽  
Propenoic Acid ◽  
Amino Derivatives ◽  
Derivatives Of ◽  
C Nmr ◽  
Ir And Uv Spectra

The cyclization of 3-N(4- and 5-benzimidazolyl and benztriazolyl)amino-2-cyano- and 2-ethoxycarbonyl-2-propenoate esters Ia, b-IVa, b under the conditions of the Gould-Jacobs reaction leads to angularly ring-fused substituted imidazo or triazolo[4,5-f] (V, VI) and [4,5-h] (VII, VIII) quinolines, respectively. The esters Vb-VIIIb have been transformed into the corresponding chloroderivatives Vc-VIIIc. 3-N(5-Benzimidazolyl and 5-benztriazolyl)amino-2-cyano-2-propenenitriles are cyclized in the presence of aluminium(III) chloride to give the aminoquinolines Vd, VId. The structure of the products has been characterized by their 1H, 13C NMR, IR, and UV spectra.

IR and UV spectra of complexes of N-vinylazoles with organohalostannanes

1973 ◽  
Vol 9 (12) ◽  
pp. 1517-1521
Author(s):  
N. N. Chipanina ◽  
N. I. Shergina ◽  
Yu. N. Ivlev ◽  
E. S. Domnina ◽  
D. D. Taryashinova ◽  
...  
Keyword(s):  
Uv Spectra ◽  
Ir And Uv Spectra
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