The kinetics of substitution reaction of cis-dichlorobis(ethylenediamine)chromium(III) ion with thiocyanate ion in methanol

1970 ◽  
Vol 35 (5) ◽  
pp. 1506-1513 ◽  
Author(s):  
V. Holba
Keyword(s):  
Substitution Reaction ◽  
Thiocyanate Ion ◽  
Kinetics Of

The mechanism of the oxidation of thiocyanate ion by peroxomonosulphate in aqueous solution. II. Kinetics of the reaction

1966 ◽  
Vol 19 (8) ◽  
pp. 1365 ◽  
Author(s):  
RH Smith ◽  
IR Wilson
Keyword(s):  
Aqueous Solution ◽  
Initial Rate ◽  
Stopped Flow ◽  
Thiocyanate Ion ◽  
First Order ◽  
Conductance Method ◽  
Rate Of Reaction ◽  
Kinetics Of

Initial rates of reaction for the above oxidation have been measured by a stopped-flow conductance method. Between pH 2 and 3.6, the initial rate of reaction, R, is given by the expression R{[HSO5-]+[SCN-]} = {kb+kc[H+]}[HSO5-]0[SCN-]20+ka[H+]-1[HSO5]20[SCN-]0 As pH increases, there is a transition to a pH-independent rate, first order in each thiocyanate and peroxomonosulphate concentrations.

scholarly journals The Kinetics of Substitution Reaction between Lead(II) and Zinc(II)-1, 2-cyclohexanediaminetetraacetate Complexes

1970 ◽  
Vol 91 (3) ◽  
pp. 236-240
Author(s):  
Tatuo TAKAHASHI ◽  
Takefumi KOISO ◽  
Nobuyuki TANAKA
Keyword(s):  
Substitution Reaction ◽  
Kinetics Of
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