To the theory of radiation chemistry. IV. The calculation of radiation-chemical yields in the radiolysis of methane, ethane, propane and methanol in the gas phase

1967 ◽  
Vol 32 (9) ◽  
pp. 3105-3132 ◽  
Author(s):  
Z. Prášil
1970 ◽  
Vol 44 (2) ◽  
pp. 296 ◽  
Author(s):  
James W. Buchanan ◽  
Robert J. Hanrahan

1976 ◽  
Vol 80 (14) ◽  
pp. 1532-1539 ◽  
Author(s):  
Arthur J. Frank ◽  
Robert J. Hanrahan

1967 ◽  
Vol 45 (8) ◽  
pp. 779-783
Author(s):  
D. R. Smith ◽  
J. C. Tole

The techniques and some preliminary results of an indirect method of studying vapor phase radiolysis by electron spin resonance (e.s.r.) spectroscopy are reported. After traversing a beam of 40 keV Ar+ ions, a stream of vapor is condensed on a cold finger at 77 °K. Free radicals which are formed by ion bombardment in the vapor phase become trapped in the solid deposit and are detected by e.s.r. Various vapors such as cyclopentane, cyclohexane, benzene, and ethanol have been bombarded at room temperature. The results correlate with conventional radiation chemical data. For example, benzene forms [Formula: see text] (and probably [Formula: see text]) radicals. These may be the intermediates which lead to polymer formation when benzene vapor is irradiated. The potential value of the experiment to vapor phase radiation chemistry is discussed.


1970 ◽  
Vol 42 (2) ◽  
pp. 244 ◽  
Author(s):  
James W. Buchanan ◽  
Robert J. Hanrahan

1978 ◽  
Vol 12 (5-6) ◽  
pp. 153-160 ◽  
Author(s):  
Tacheng Hsieh ◽  
Robert J Hanrahan

1978 ◽  
Vol 12 (1-2) ◽  
pp. 51-58 ◽  
Author(s):  
Tacheng Hsieh ◽  
Robert J. Hanrahan

Sign in / Sign up

Export Citation Format

Share Document