Physical aspects of the effect of chain transfer agents on the properties of poly(methyl methacrylate)

2008 ◽  
Vol 50 (7) ◽  
pp. 792-797 ◽  
Author(s):  
S. A. Bulgakova ◽  
Yu. D. Semchikov ◽  
K. V. Kir’yanov ◽  
T. A. Gracheva ◽  
K. S. Klychkov
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Poly Methyl Methacrylate ◽  
Transfer Agents

Monodisperse poly(methyl methacrylate) microspheres with tunable carboxyl groups on the surface obtained by photoinitiated RAFT dispersion polymerization

2019 ◽  
Vol 55 (54) ◽  
pp. 7848-7851 ◽  
Author(s):  
Liangliang Yu ◽  
Yuxuan Zhang ◽  
Xiaocong Dai ◽  
Li Zhang ◽  
Jianbo Tan
Keyword(s):  
Methyl Methacrylate ◽  
Binary Mixtures ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Carboxyl Groups ◽  
Polymeric Microspheres ◽  
Poly Methyl Methacrylate ◽  
Macromolecular Chain ◽  
Transfer Agents

Monodisperse polymeric microspheres with tunable carboxy groups on the surface are prepared by photoinitiated RAFT dispersion polymerization using binary mixtures of two macromolecular chain transfer agents (macro-CTAs).

Synthesis of Poly(Methyl Methacrylate)-Based Polyrotaxane via Reversible Addition–Fragmentation Chain Transfer Polymerization

2020 ◽  
Vol 9 (12) ◽  
pp. 1853-1857
Author(s):  
Yu-Cheng Wang ◽  
Rina Maeda ◽  
Gergely Kali ◽  
Hideaki Yokoyama ◽  
Gerhard Wenz ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Poly Methyl Methacrylate ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

scholarly journals Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2

2021 ◽  
Author(s):  
Ana A. C. Pacheco ◽  
Arnaldo F. da Silva Filho ◽  
Kristoffer Kortsen ◽  
Magnus W. D. Hanson-Heine ◽  
Vincenzo Taresco ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Good Control ◽  
Chain Transfer Agent ◽  
Methylpropionic Acid ◽  
Transfer Agents

RAFT dispersion polymerisation of methyl methacrylate is performed in scCO2 with 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT) present as chain transfer agent (CTA) and surprisingly shows good control over PMMA molecular weight.

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