Monodisperse poly(methyl methacrylate) microspheres with tunable carboxyl groups on the surface obtained by photoinitiated RAFT dispersion polymerization

2019 ◽  
Vol 55 (54) ◽  
pp. 7848-7851 ◽  
Author(s):  
Liangliang Yu ◽  
Yuxuan Zhang ◽  
Xiaocong Dai ◽  
Li Zhang ◽  
Jianbo Tan
Keyword(s):  
Methyl Methacrylate ◽  
Binary Mixtures ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Carboxyl Groups ◽  
Polymeric Microspheres ◽  
Poly Methyl Methacrylate ◽  
Macromolecular Chain ◽  
Transfer Agents

Monodisperse polymeric microspheres with tunable carboxy groups on the surface are prepared by photoinitiated RAFT dispersion polymerization using binary mixtures of two macromolecular chain transfer agents (macro-CTAs).

Physical aspects of the effect of chain transfer agents on the properties of poly(methyl methacrylate)

2008 ◽  
Vol 50 (7) ◽  
pp. 792-797 ◽  
Author(s):  
S. A. Bulgakova ◽  
Yu. D. Semchikov ◽  
K. V. Kir’yanov ◽  
T. A. Gracheva ◽  
K. S. Klychkov
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Poly Methyl Methacrylate ◽  
Transfer Agents

Polymerization-induced self-assembly: ethanolic RAFT dispersion polymerization of 2-phenylethyl methacrylate

2014 ◽  
Vol 5 (7) ◽  
pp. 2342-2351 ◽  
Author(s):  
Yiwen Pei ◽  
Andrew B. Lowe
Keyword(s):  
Self Assembly ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Degree Of Polymerization ◽  
Average Degree ◽  
Macromolecular Chain ◽  
Ethyl Methacrylate ◽  
Reversible Addition ◽  
Transfer Agents

Reversible addition-fragmentation chain transfer (RAFT) radical dispersion polymerization (RAFTDP) has been employed to polymerize 2-phenylethyl methacrylate (PEMA) using poly[2-(dimethylamino)ethyl methacrylate] (PDMAEMA) macromolecular chain transfer agents (macro-CTAs) of varying average degree of polymerization (X̄n).

scholarly journals Rationally designed anionic diblock copolymer worm gels are useful model systems for calcite occlusion studies

2019 ◽  
Vol 10 (37) ◽  
pp. 5131-5141 ◽  
Author(s):  
Lee A. Fielding ◽  
Coit T. Hendley IV ◽  
Emily Asenath-Smith ◽  
Lara A. Estroff ◽  
Steven P. Armes
Keyword(s):  
Binary Mixtures ◽  
Diblock Copolymer ◽  
Chain Transfer ◽  
Model Systems ◽  
Macromolecular Chain ◽  
Carboxylate Groups ◽  
Transfer Agents

Binary mixtures of RAFT macromolecular chain transfer agents are utilized to rationally design anionic diblock copolymer nanoparticles via PISA. The role of carboxylate groups in directing calcite growth within copolymer worm gels is investigated.

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