Across-arc variations in Mo isotopes and implications for subducted oceanic crust in the source of back-arc basin volcanic rocks

Geology ◽  
2021 ◽  
Author(s):  
Xiaohui Li ◽  
Quanshu Yan ◽  
Zhigang Zeng ◽  
Jingjing Fan ◽  
Sanzhong Li ◽  
...  

Molybdenum (Mo) isotope ratios provide a potential means of tracing material recycling involved in subduction zone processes. However, the geochemical behavior of Mo in subducted oceanic crust remains enigmatic. We analyzed Mo isotope ratios of arc and back-arc basin lavas from the Mariana subduction zone (western Pacific Ocean), combining newly obtained element and Sr-Nd-Pb-Li isotope data to investigate subduction zone geochemical processes involving Mo. The Mo isotope ratios (δ98/95MoNIST3134; U.S. National Institute of Standards and Technology [NIST] Mo standard) of the volcanic rocks showed clear across-arc variations, decreasing with increasing depth to the Wadati-Benioff zone. The high δ98/95Mo values in the Mariana Islands (–0.18‰ to +0.38‰) correspond to high 87Sr/86Sr, low 143Nd/144Nd, and radiogenic Pb isotope ratios, suggesting that altered upper oceanic crust played an important role in the magma source. The low δ98/95Mo values in the Central Mariana Trough (–0.65‰ to –0.17‰) with mantle-like Sr-Nd-Pb but slightly low δ7Li values provide direct evidence for the contribution of deep recycled oceanic crust to the magma source of the back-arc basin lavas. The isotopically light Mo magmas originated by partial melting of a residual subducted slab (eclogite) after high degrees of dehydration and then penetrated into the back-arc mantle. This interpretation provides a new perspective with which to investigate the deep recycling of subducted oceanic lithosphere and associated magma petrogenesis.

2021 ◽  
Vol 57 ◽  
pp. 239-273
Author(s):  
Allan Ludman ◽  
Christopher McFarlane ◽  
Amber T.H. Whittaker

Volcanic rocks in the Miramichi inlier in Maine occur in two areas separated by the Bottle Lake plutonic complex: the Danforth segment (Stetson Mountain Formation) north of the complex and Greenfield segment to the south (Olamon Stream Formation). Both suites are dominantly pyroclastic, with abundant andesite, dacite, and rhyolite tuffs and subordinate lavas, breccias, and agglomerates. Rare basaltic tuffs and a small area of basaltic tuffs, agglomerates, and lavas are restricted to the Greenfield segment. U–Pb zircon geochronology dates Greenfield segment volcanism at ca. 469 Ma, the Floian–Dapingian boundary between the Lower and Middle Ordovician. Chemical analyses reveal a calc-alkaline suite erupted in a continental volcanic arc, either the Meductic or earliest Balmoral phase of Popelogan arc activity. The Maine Miramichi volcanic rocks are most likely correlative with the Meductic Group volcanic suite in west-central New Brunswick. Orogen-parallel lithologic and chemical variations from New Brunswick to east-central Maine may result from eruptions at different volcanic centers. The bimodal Poplar Mountain volcanic suite at the Maine–New Brunswick border is 10–20 myr younger than the Miramichi volcanic rocks and more likely an early phase of back-arc basin rifting than a late-stage Meductic phase event. Coeval calc-alkaline arc volcanism in the Miramichi, Weeksboro–Lunksoos Lake, and Munsungun Cambrian–Ordovician inliers in Maine is not consistent with tectonic models involving northwestward migration of arc volcanism. This >150 km span cannot be explained by a single east-facing subduction zone, suggesting more than one subduction zone/arc complex in the region.


There are well established differences in the chemical and isotopic characteristics of the calc-alkaline basalt—andesite-dacite-rhyolite association of the northern (n.v.z.), central (c.v.z.) and southern volcanic zones (s.v.z.) of the South American Andes. Volcanic rocks of the alkaline basalt-trachyte association occur within and to the east of these active volcanic zones. The chemical and isotopic characteristics of the n.v.z. basaltic andesites and andesites and the s.v.z. basalts, basaltic andesites and andesites are consistent with derivation by fractional crystallization of basaltic parent magmas formed by partial melting of the asthenospheric mantle wedge containing components from subducted oceanic lithosphere. Conversely, the alkaline lavas are derived from basaltic parent magmas formed from mantle of ‘within-plate’ character. Recent basaltic andesites from the Cerro Galan volcanic centre to the SE of the c.v.z. are derived from mantle containing both subduction zone and within-plate components, and have experienced assimilation and fractional crystallization (a.f.c.) during uprise through the continental crust. The c.v.z. basaltic andesites are derived from mantle containing subduction-zone components, probably accompanied by a.f.c. within the continental crust. Some c.v.z. lavas and pyroclastic rocks show petrological and geochemical evidence for magma mixing. The petrogenesis of the c.v.z. lavas is therefore a complex process in which magmas derived from heterogeneous mantle experience assimilation, fractional crystallization, and magma mixing during uprise through the continental crust.


2004 ◽  
Vol 175 (5) ◽  
pp. 443-460 ◽  
Author(s):  
Rodolfo A. Tamayo* ◽  
René C. Maury* ◽  
Graciano P. Yumul ◽  
Mireille Polvé ◽  
Joseph Cotten ◽  
...  

Abstract The basement complexes of the Philippine archipelago include at least 20 ophiolites and ophiolitic complexes. These complexes are characterised by volcanic sequences displaying geochemical compositions similar to those observed in MORB, transitional MORB-island arc tholeiites and arc volcanic rocks originating from modern Pacific-type oceans, back-arc basins and island arcs. Ocean island basalt-like rocks are rarely encountered in the volcanic sequences. The gabbros from the ophiolites contain clinopyroxenes and plagioclases showing a wide range of XMg and An values, respectively. Some of these gabbros exhibit mineral chemistries suggesting their derivation from basaltic liquids formed from mantle sources that underwent either high degrees of partial melting or several partial melting episodes. Moreover, some of the gabbros display a crystallization sequence where orthopyroxene and clinopyroxene appeared before plagioclase. The major element compositions of coexisting orthopyroxenes and olivines from the mantle peridotites are consistent with low to high degrees of partial melting. Accessory spinels in these peridotites display a wide range of XCr values as well with some of them above the empirical upper limit of 0.6 often observed in most modern mid-oceanic ridge (MOR) mantle rocks. Co-existing olivines and spinels from the peridotites also exhibit compositions suggesting that they lastly equilibrated under oxidizing mantle conditions. The juxtaposition of volcanic rocks showing affinities with modern MOR and island arc environments suggests that most of the volcanic sequences in Philippine ophiolites formed in subduction-related geodynamic settings. Similarly, their associated gabbros and peridotites display mineralogical characteristics and mineral chemistries consistent with their derivation from modern supra-subduction zone-like environments. Alternatively, these rocks could have, in part, evolved in a supra-subduction zone even though they originated from a MOR-like setting. A simplified scenario regarding the early geodynamic evolution of the Philippines is proposed on the basis of the geochemical signatures of the ophiolites, their ages of formation and the ages and origins of the oceanic basins actually bounding the archipelago, including basins presumed to be now totally consumed. This scenario envisages the early development of the archipelago to be largely dominated by the opening and closing of oceanic basins. Fragments of these basins provided the substratum on top of which the Cretaceous to Recent volcanic arcs of the Philippines were emplaced.


Geology ◽  
2021 ◽  
Author(s):  
Yu-Ming Lai ◽  
Sun-Lin Chung ◽  
Azman A. Ghani ◽  
Sayed Murtadha ◽  
Hao-Yang Lee ◽  
...  

The migration of arc magmatism that is a fundamental aspect of plate tectonics may reflect the complex interaction between subduction zone processes and regional tectonics. Here we report new observations on volcanic migration from northwestern Sumatra, in the westernmost Sunda arc, characterized by an oblique convergent boundary between the Indo-Australian and Eurasian plates. Our study indicates that in northwestern Sumatra, volcanism ceased at 15–10 Ma on the southern coast and reignited to form a suite of active volcanoes that erupt exclusively to the north of the trench-parallel Sumatran fault. Younger volcanic rocks from the north are markedly more enriched in K2O and other highly incompatible elements, delineating a geochemical variation over space and time similar to that in Java and reflecting an increase in the Benioff zone depth. We relate this mid-Miocene volcanic migration in northwestern Sumatra to the far-field effect of propagating extrusion tectonics driven by the India-Eurasia collision. The extrusion caused regional deformation southward through Myanmar to northwestern Sumatra and thus transformed the oblique subduction into a dextral motion–governed plate boundary. This tectonic transformation, associated with opening of the Andaman Sea, is suggested to be responsible for the volcanic migration in northwestern Sumatra.


2008 ◽  
Vol 45 (1) ◽  
pp. 15-29 ◽  
Author(s):  
Alan D’hulst ◽  
Georges Beaudoin ◽  
Michel Malo ◽  
Marc Constantin ◽  
Pierre Pilote

The Lower Devonian Sainte-Marguerite volcanic rocks are part of a Silurian–Devonian volcanic sequence deposited between the Taconian and Acadian orogenies in the Gaspé Peninsula, Quebec, Canada. The Sainte-Marguerite unit includes basaltic and dacitic lava flows with calc-alkaline and volcanic-arc affinities. Such affinities are also recorded by the trace-element signature in Lower Silurian and most Lower Devonian volcanic units of the Gaspé Peninsula. However, most of the other Silurian–Devonian volcanic rocks occurring in the Gaspé Peninsula have been previously interpreted to have erupted in an intracontinental setting. A back-arc setting for the Gaspé Peninsula between the Taconian and Acadian orogenies could account for these subduction volcanic-arc signatures, though a metasomatized lithospheric mantle magma source, unrelated to subduction, cannot be excluded. Lower Silurian and Lower Devonian volcanic rocks in the central part of the Gaspé Peninsula show an arc affinity, whereas Upper Silurian and Lower to Middle Devonian volcanic rocks, located in the south and north of the Gaspé Peninsula, respectively, show a within-plate affinity. The Lower Devonian Archibald Settlement and Boutet volcanic rocks of the southern and northern Gaspé Peninsula, respectively, show a trend toward a within-plate affinity. This suggests that within-plate volcanism migrated from south to north through time in an evolving back-arc environment and that the subduction signature of Lower Silurian and Lower Devonian rocks results from a source that melted only under the central part of the Gaspé Peninsula.


1998 ◽  
Vol 135 (2) ◽  
pp. 171-181 ◽  
Author(s):  
J. D. KEPPIE ◽  
J. DOSTAL

Central Cape Breton Island in Nova Scotia, Canada, is host to ∼700–630 Ma felsic and associated mafic volcanic rocks that are relatively rare in other parts of the Avalon Composite Terrane, occurring elsewhere only in the Stirling Block of southern Cape Breton Island and in parts of eastern Newfoundland. The mafic rocks of central Cape Breton Island are typically intraplate tholeiitic basalts generated by melting of a garnet-bearing mantle source. They lack a continental trace element and εNd imprint although they were emplaced on continental crust; they resemble oceanic island basalts. Contemporaneous volcanism in the Stirling Block is calc-alkaline and formed in a volcanic arc setting. In the absence of evidence for an intervening trench complex or suture, it may be inferred that the central Cape Breton tholeiites formed in a back-arc setting relative to the Stirling Block. This rifting may represent the initial stages of separation of an Avalonian arc from western Gondwana. The arc rifted further between ∼630–610 Ma when the younger Antigonish-Cobequid back-arc basin formed. Subsequently, the extensional arc became convergent, telescoping the back-arc basin. Northwestward migration of calc-alkaline arc magmatism may be related to shallowing of the associated Benioff zone through time.


Ophiolite belts are found in Tibet along the Zangbo, Banggong and Jinsha River Sutures and in the Anyemaqen mountains, the eastern extension of the Kunlun mountains. Where studied, the Zangbo Suture ophiolites are characterized by: apparently thin crustal sequences (3-3.5 k m ); an abundance of sills and dykes throughout the crustal and uppermost mantle sequences; common intraoceanic melanges and unconformities; and an N-MORB petrological and geochemical composition. The ophiolites probably formed within the main neo-Tethyan ocean and the unusual features may be due to proximity to ridge-transform intersections, rather than to genesis at very slow -spreading ridges as the current consensus suggests. The Banggong Suture ophiolites have a supra-subduction zone petrological and geochemical composition — although at least one locality in the Ado Massif shows MORB characteristics. However, it is also apparent that the dykes and lavas show a regional chemical zonation, from boninites and primitive island arc tholeiites in the south of the ophiolite belt, through normal island arc tholeiites in the central belt to island arc tholeiites transitional to N-MORB in the north. The ophiolites could represent fragments of a fore-arc, island arc, back-arc complex developed above a Jurassic, northward-dipping subduction zone and emplaced in several stages during convergence of the Lhasa and Qiangtang terranes. The ophiolites of the Jinsha River Suture have a N-MORB composition where analysed, but more information is needed for a proper characterization. The Anyemaqen ophiolites, where studied, have a within-plate tholeiite composition and may have originated at a passive margin: it is not, however, certain whether true oceanic lithosphere, as opposed to strongly attenuated continental lithosphere, existed in this region.


Geological and geochemical evidence suggest that the Oman ophiolite is a fragment of a submarine arc-basin complex formed above a short-lived subduction zone in the mid-Cretaceous. Detailed studies of the lava stratigraphy and the intrusive relationships of dykes, sills and high-level plutons provide further evidence for the magmatic and tectonic development of the complex in question. Four consecutive events can be recognized to have taken place before emplacement: (1) eruption of basalts of island arc affinity onto pre-existing (Triassic) oceanic crust; (2) creation of new oceanic crust by backarc spreading; (3) intrusion of magma into this back-arc oceanic crust accompanied by eruption of basalts and andesites from discrete volcanic centres; (4) further intrusion of magma accompanied by uplift and eruption of basalts and rhyolites in submarine graben. A combined structural and geochemical analysis of the dyke swarm indicates that extension took place in approximately a N-S (ridge) and an ESE-WNW (leaky transform) direction relative to an inferred direction of subduction to the NE, and that a small but significant proportion of the sheeted dykes were injected during the ‘arc’ rather than the earlier ‘back-arc spreading’ episode. These various observations can be explained in terms of the progressive response of a non-isotropic lithosphere to the stresses induced during subduction.


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