scholarly journals Identifying time scales for violation/preservation of Stokes-Einstein relation in supercooled water

2017 ◽  
Vol 3 (8) ◽  
pp. e1700399 ◽  
Author(s):  
Takeshi Kawasaki ◽  
Kang Kim
Keyword(s):  
Time Scales ◽  
Supercooled Water ◽  
Einstein Relation

scholarly journals Exploring the validity of the Stokes-Einstein relation in supercooled water using nanomolecular probes

2021 ◽  
Author(s):  
Sharon Berkowicz ◽  
Fivos Perakis
Keyword(s):  
Liquid Water ◽  
Supercooled Water ◽  
Einstein Relation ◽  
The Many

The breakdown of Stokes-Einstein relation in liquid water is one of the many anomalies that take place upon cooling and indicates the decoupling of diffusion and viscosity. It is hypothesized...

scholarly journals The violation of the Stokes-Einstein relation in supercooled water

2006 ◽  
Vol 103 (35) ◽  
pp. 12974-12978 ◽  
Author(s):  
S.-H. Chen ◽  
F. Mallamace ◽  
C.-Y. Mou ◽  
M. Broccio ◽  
C. Corsaro ◽  
...  
Keyword(s):  
Supercooled Water ◽  
Einstein Relation

scholarly journals Time scales of supercooled water and implications for reversible polyamorphism

2015 ◽  
Vol 113 (17-18) ◽  
pp. 2799-2804 ◽  
Author(s):  
David T. Limmer ◽  
David Chandler
Keyword(s):  
Time Scales ◽  
Supercooled Water

scholarly journals Experimental observation of the liquid-liquid transition in bulk supercooled water under pressure

Science ◽  
2020 ◽  
Vol 370 (6519) ◽  
pp. 978-982 ◽  
Author(s):  
Kyung Hwan Kim ◽  
Katrin Amann-Winkel ◽  
Nicolas Giovambattista ◽  
Alexander Späh ◽  
Fivos Perakis ◽  
...  
Keyword(s):  
Time Scales ◽  
Supercooled Water ◽  
Supercooled Liquid ◽  
Laser Pulses ◽  
High Density ◽  
Liquid Transition ◽  
Probe Delay ◽  
Sample Density ◽  
Order Of Magnitude ◽  
Isochoric Heating

We prepared bulk samples of supercooled liquid water under pressure by isochoric heating of high-density amorphous ice to temperatures of 205 ± 10 kelvin, using an infrared femtosecond laser. Because the sample density is preserved during the ultrafast heating, we could estimate an initial internal pressure of 2.5 to 3.5 kilobar in the high-density liquid phase. After heating, the sample expanded rapidly, and we captured the resulting decompression process with femtosecond x-ray laser pulses at different pump-probe delay times. A discontinuous structural change occurred in which low-density liquid domains appeared and grew on time scales between 20 nanoseconds to 3 microseconds, whereas crystallization occurs on time scales of 3 to 50 microseconds. The dynamics of the two processes being separated by more than one order of magnitude provides support for a liquid-liquid transition in bulk supercooled water.

Understanding the Origin of the Breakdown of the Stokes–Einstein Relation in Supercooled Water at Different Temperature–Pressure Conditions

2019 ◽  
Vol 123 (47) ◽  
pp. 10089-10099 ◽  
Author(s):  
Vikas Dubey ◽  
Shakkira Erimban ◽  
Sandipa Indra ◽  
Snehasis Daschakraborty
Keyword(s):  
Supercooled Water ◽  
Einstein Relation

scholarly journals Relation between the Widom line and the breakdown of the Stokes-Einstein relation in supercooled water

2007 ◽  
Vol 104 (23) ◽  
pp. 9575-9579 ◽  
Author(s):  
P. Kumar ◽  
S. V. Buldyrev ◽  
S. R. Becker ◽  
P. H. Poole ◽  
F. W. Starr ◽  
...  
Keyword(s):  
Supercooled Water ◽  
Einstein Relation ◽  
Widom Line

Breakdown of the Stokes–Einstein relation in supercooled water: the jump-diffusion perspective

2021 ◽  
Vol 23 (36) ◽  
pp. 19964-19986
Author(s):  
Vikas Dubey ◽  
Shivam Dueby ◽  
Snehasis Daschakraborty
Keyword(s):  
Supercooled Water ◽  
Jump Diffusion ◽  
Einstein Relation

The breakdown of the Stokes–Einstein relation in supercooled water can be quantitatively explained using the translational jump-diffusion approach.

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