scholarly journals Carbon dots in zeolites: A new class of thermally activated delayed fluorescence materials with ultralong lifetimes

2017 ◽  
Vol 3 (5) ◽  
pp. e1603171 ◽  
Author(s):  
Jiancong Liu ◽  
Ning Wang ◽  
Yue Yu ◽  
Yan Yan ◽  
Hongyue Zhang ◽  
...  
2021 ◽  
Author(s):  
Cathay Chai Au-Yeung ◽  
Lok-Kwan Li ◽  
Man-Chung Tang ◽  
Shiu-Lun Lai ◽  
Wai-Lung Cheung ◽  
...  

We report the design of a new class of fused heterocyclic alkynyl ligand-containing gold(iii) complexes, which shows tunable emission colors spanning yellow to red region and exhibits thermally activated delayed fluorescence (TADF) properties.


2020 ◽  
Vol 4 (5) ◽  
pp. 1404-1410 ◽  
Author(s):  
Hongyue Zhang ◽  
Jiancong Liu ◽  
Bolun Wang ◽  
Kaikai Liu ◽  
Guangrui Chen ◽  
...  

CD@zeolite composites with tunable TADF emission via an energy transfer process between confined CDs.


2020 ◽  
Author(s):  
BAHADUR SK ◽  
Samarth Sharma ◽  
Anto James ◽  
Subhankar Kundu ◽  
Abhijit Patra

<p></p><p>Control of nonradiative deactivation of triplet states and tuning the singlet-triplet energy gap (ΔE<sub>ST</sub>) are the major challenges to develop materials exhibiting thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP). Herein, we propose a new class of multichromophoric tridonor-acceptor (D<sub>3</sub>-A) compounds with rigid and flexible π-spacer having N-rich pyridoquinoxaline (PQ) and pyridopyrazine (PZ) acceptor core, respectively. The molecule with carbazole (Cz) donors at <i>meta</i> to quinoxaline (QX) nitrogen of rigid PQ core exhibits TADF. Whereas, the variation of the linkage position of Cz to PQ as well as twisted and flexible PZ core show predominantly RTP due to relatively higher singlet-triplet energy gap (ΔE<sub>ST</sub>). Increasing the donor strength with phenoxazine (PO) in PZ system leads to simultaneous TADF and RTP. Further, we demonstrate the promising scope of all-organic triplet harvesting materials in solid-state security encryption.</p><br><p></p>


2020 ◽  
Author(s):  
BAHADUR SK ◽  
Samarth Sharma ◽  
Anto James ◽  
Subhankar Kundu ◽  
Abhijit Patra

<p></p><p>Control of nonradiative deactivation of triplet states and tuning the singlet-triplet energy gap (ΔE<sub>ST</sub>) are the major challenges to develop materials exhibiting thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP). Herein, we propose a new class of multichromophoric tridonor-acceptor (D<sub>3</sub>-A) compounds with rigid and flexible π-spacer having N-rich pyridoquinoxaline (PQ) and pyridopyrazine (PZ) acceptor core, respectively. The molecule with carbazole (Cz) donors at <i>meta</i> to quinoxaline (QX) nitrogen of rigid PQ core exhibits TADF. Whereas, the variation of the linkage position of Cz to PQ as well as twisted and flexible PZ core show predominantly RTP due to relatively higher singlet-triplet energy gap (ΔE<sub>ST</sub>). Increasing the donor strength with phenoxazine (PO) in PZ system leads to simultaneous TADF and RTP. Further, we demonstrate the promising scope of all-organic triplet harvesting materials in solid-state security encryption.</p><br><p></p>


2015 ◽  
Vol 51 (100) ◽  
pp. 17768-17771 ◽  
Author(s):  
Juan Hou ◽  
Long Wang ◽  
Ping Zhang ◽  
Yuan Xu ◽  
Lan Ding

A rapid preparative method for carbon dots in an immiscible system was proposed. CDs possess high quantum yield, excitation-independent emission and thermally activated delayed fluorescence.


2021 ◽  
Author(s):  
Lok-Kwan Li ◽  
Wing-Kei Kwok ◽  
Man-Chung Tang ◽  
Wai-Lung Cheung ◽  
Shiu-Lun Lai ◽  
...  

A new class of carbazolylgold(iii) C^C^N dendrimers with thermally activated delayed fluorescence properties has been designed and synthesized for the realzaqtion of operationally stable solution-processed organic light-emitting devices.


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