Canonical Quantization of the Schrödinger Equation

1964 ◽  
Vol 32 (8) ◽  
pp. 609-611 ◽  
Author(s):  
L. J. Tassie
2021 ◽  
Vol 81 (12) ◽  
Author(s):  
Theodoros Pailas ◽  
Nikolaos Dimakis ◽  
Petros A. Terzis ◽  
Theodosios Christodoulakis

AbstractThe system under study is the $$\Lambda $$ Λ -Kantowski–Sachs universe. Its canonical quantization is provided based on a recently developed method: the singular minisuperspace Lagrangian describing the system, is reduced to a regular (by inserting into the dynamical equations the lapse dictated by the quadratic constraint) possessing an explicit (though arbitrary) time dependence; thus a time-covariant Schrödinger equation arises. Additionally, an invariant (under transformations $$t=f({\tilde{t}})$$ t = f ( t ~ ) ) decay probability is defined and thus “observers” which correspond to different gauge choices obtain, by default, the same results. The time of decay for a Gaussian wave packet localized around the point $$a=0$$ a = 0 (where a the radial scale factor) is calculated to be of the order $$\sim 10^{-42}{-}10^{-41}~\text {s}$$ ∼ 10 - 42 - 10 - 41 s . The acquired value is near the end of the Planck era (when comparing to a FLRW universe), during which the quantum effects are most prominent. Some of the results are compared to those obtained by following the well known canonical quantization of cosmological systems, i.e. the solutions of the Wheeler–DeWitt equation.


2020 ◽  
Vol 2 (3) ◽  
pp. 414-441
Author(s):  
Theodoros Pailas

A “time”-covariant Schrödinger equation is defined for the minisuperspace model of the Reissner–Nordström (RN) black hole, as a “hybrid” between the “intrinsic time” Schrödinger and Wheeler–DeWitt (WDW) equations. To do so, a reduced, regular, and “time(r)”-dependent Hamiltonian density was constructed, without “breaking” the re-parametrization covariance r→f(r˜). As a result, the evolution of states with respect to the parameter r and the probabilistic interpretation of the resulting quantum description is possible, while quantum schemes for different gauge choices are equivalent by construction. The solutions are found for Dirac’s delta and Gaussian initial states. A geometrical interpretation of the wavefunctions is presented via Bohm analysis. Alongside this, a criterion is presented to adjudicate which, between two singular spacetimes, is “more” or “less” singular. Two ways to adjudicate the existence of singularities are compared (vanishing of the probability density at the classical singularity and semi-classical spacetime singularity). Finally, an equivalence of the reduced equations with those of a 3D electromagnetic pp-wave spacetime is revealed.


2019 ◽  
Vol 34 (14) ◽  
pp. 1950108 ◽  
Author(s):  
S. Sargolzaeipor ◽  
H. Hassanabadi ◽  
W. S. Chung

In this paper, we investigate the behavior of the energy eigenvalues of the Schrödinger equation by using the canonical quantization method. We obtain the Hamiltonian of the Schrödinger equation by the Lagrangian in terms of the new coordinates. Then we calculate the partition function by the eigenvalues and the thermodynamic properties of the system in the superstatistics formalism for the modified Dirac delta and the Gamma distributions. All results in the limiting cases satisfy that of the harmonic oscillator. Furthermore, the effects of the all parameters in the problem of energy eigenvalues and thermodynamic properties are calculated and shown graphically.


Symmetry ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 943
Author(s):  
Philip Broadbridge ◽  
Kathryn Deutscher

For a scalar field in an exponentially expanding universe, constituent modes of elementary excitation become unstable consecutively at shorter wavelength. After canonical quantization, a Bogoliubov transformation reduces the minimally coupled scalar field to independent 1D modes of two inequivalent types, leading eventually to a cosmological partitioning of energy. Due to accelerated expansion of the coupled space-time, each underlying mode transits from an attractive oscillator with discrete energy spectrum to a repulsive unit with continuous unbounded energy spectrum. The underlying non-autonomous Schrödinger equation is solved here as the wave function evolves through the attraction-repulsion transition and ceases to oscillate.


2018 ◽  
Vol 2 (2) ◽  
pp. 43-47
Author(s):  
A. Suparmi, C. Cari, Ina Nurhidayati

Abstrak – Persamaan Schrödinger adalah salah satu topik penelitian yang yang paling sering diteliti dalam mekanika kuantum. Pada jurnal ini persamaan Schrödinger berbasis panjang minimal diaplikasikan untuk potensial Coulomb Termodifikasi. Fungsi gelombang dan spektrum energi yang dihasilkan menunjukkan kharakteristik atau tingkah laku dari partikel sub atom. Dengan menggunakan metode pendekatan hipergeometri, diperoleh solusi analitis untuk bagian radial persamaan Schrödinger berbasis panjang minimal diaplikasikan untuk potensial Coulomb Termodifikasi. Hasil yang diperoleh menunjukkan terjadi peningkatan energi yang sebanding dengan meningkatnya parameter panjang minimal dan parameter potensial Coulomb Termodifikasi. Kata kunci: persamaan Schrödinger, panjang minimal, fungsi gelombang, energi, potensial Coulomb Termodifikasi Abstract – The Schrödinger equation is the most popular topic research at quantum mechanics. The  Schrödinger equation based on the concept of minimal length formalism has been obtained for modified Coulomb potential. The wave function and energy spectra were used to describe the characteristic of sub-atomic particle. By using hypergeometry method, we obtained the approximate analytical solutions of the radial Schrödinger equation based on the concept of minimal length formalism for the modified Coulomb potential. The wave function and energy spectra was solved. The result showed that the value of energy increased by the increasing both of minimal length parameter and the potential parameter. Key words: Schrödinger equation, minimal length formalism (MLF), wave function, energy spectra, Modified Coulomb potential


Author(s):  
Niels Engholm Henriksen ◽  
Flemming Yssing Hansen

This introductory chapter considers first the relation between molecular reaction dynamics and the major branches of physical chemistry. The concept of elementary chemical reactions at the quantized state-to-state level is discussed. The theoretical description of these reactions based on the time-dependent Schrödinger equation and the Born–Oppenheimer approximation is introduced and the resulting time-dependent Schrödinger equation describing the nuclear dynamics is discussed. The chapter concludes with a brief discussion of matter at thermal equilibrium, focusing at the Boltzmann distribution. Thus, the Boltzmann distribution for vibrational, rotational, and translational degrees of freedom is discussed and illustrated.


Author(s):  
Frank S. Levin

Chapter 7 illustrates the results obtained by applying the Schrödinger equation to a simple pedagogical quantum system, the particle in a one-dimensional box. The wave functions are seen to be sine waves; their wavelengths are evaluated and used to calculate the quantized energies via the de Broglie relation. An energy-level diagram of some of the energies is constructed; on it are illustrations of the corresponding wave functions and probability distributions. The wave functions are seen to be either symmetric or antisymmetric about the midpoint of the line representing the box, thereby providing a lead-in to the later exploration of certain symmetry properties of multi-electron atoms. It is next pointed out that the Schrödinger equation for this system is identical to Newton’s equation describing the vibrations of a stretched musical string. The different meaning of the two solutions is discussed, as is the concept and structure of linear superpositions of them.


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